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a)\(Fe2O3+3H2SO4-->Fe2\left(SO4\right)3+3H2O\)
\(n_{Fe2O3}=\frac{16}{160}=0,1\left(mol\right)\)
\(n_{H2SO4}=3n_{Fe2O3}=0,3\left(mol\right)\)
\(m_{H2SO4}=0,3.98=29,4\left(g\right)\)
\(n_{Fe2\left(SO4\right)3}=n_{Fe2O3}=0,1\left(mol\right)\)
\(m_{Fe2\left(SO4\right)3}=0,1.400=40\left(g\right)\)
b) \(Fe2O3+3H2SO4-->Fe2\left(SO4\right)3+3H2O\)
\(n_{Fe2O3}=\frac{32}{160}=0,2\left(mol\right)\)
\(n_{H2SO4}=\frac{29,4}{98}=0,3\left(mol\right)\)
\(n_{Fe2O3}\left(\frac{0,2}{1}\right)>nH2SO4\left(\frac{0,3}{3}\right)\)
\(\Rightarrow FE2O3dư\)
\(n_{Fe2O3}=\frac{1}{3}n_{H2SO4}=0,1\left(mol\right)\)
\(n_{Fe2O3}dư=0,2-0,1=0,1\left(mol\right)\)
\(m_{Fe2O3}dư=0,1.160=16\left(g\right)\)
\(n_{Fe2\left(SO4\right)3}=\frac{1}{3}n_{H2SO4}=0,1\left(mol\right)\)
\(m_{Fe2\left(SO4\right)3}=0,1.400=40\left(g\right)\)
pt:2Fe+3H2SO4\(\rightarrow\)Fe2SO4+H2
a)nFe=\(\frac{m}{M}\)=\(\frac{22,4}{56}\) =0,4(mol)
nFe2(SO4)3=\(\frac{m}{M}\)=\(\frac{24,5}{340}\)=0,07(mol)
Theo pt ta có tỉ lệ :
\(\frac{0,4}{2}>\frac{0,07}{1}\)
=>nFe dư , nFe2(SO4)3
nên ta tính theo nFe2(SO4)3
=> nFe dư = nFe đề bài - nFe phản ứng
= 2-0,2=1,8(mol)
=>mFe = n x M = 1,8 x 56 = 100,8(g)
b) Theo pt: nH2 = nFe = 1,8 (mol)
VH2 = n x 22,4 = 1,8 x 22,4 = 40,32 (l)
Bài 1)
a \(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
\(n_{Fe_2O_3}=\frac{4,8}{216}\approx\text{0,02 (mol)}\)
\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
0,02 0,06
\(m_{H_2SO_4}=98\cdot0,06=5,88\left(g\right)\)
b) \(m_{Fe_2\left(SO_4\right)_3}=0,02\cdot400=\text{290.24}\left(g\right)\)
Câu 2 mai làm
Câu 2
a)\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+H_2\)
\(n_{Al}=\frac{5,4}{2,7}=0,2\left(mol\right)\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+H_2\)
0,4 mol 0,6 mol 0,2 mol
\(V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\)
b) \(m_{H_2SO_4}=0,6\cdot98=58,8\left(g\right)\)
\(Fe_2O_3\left(0,075\right)+3H_2\left(0,225\right)\rightarrow2Fe\left(0,15\right)+3H_2O\)
\(CuO\left(0,1\right)+H_2\left(0,1\right)\rightarrow Cu\left(0,1\right)+H_2O\)
\(m_{Fe_2O_3}=20.60\%=12\left(g\right)\)
\(\Rightarrow n_{Fe_2O_3}=\frac{12}{160}=0,075\left(mol\right)\)
\(\Rightarrow m_{Fe}=0,15.56=8,4\left(g\right)\)
\(m_{CuO}=20.40\%=8\left(g\right)\)
\(\Rightarrow n_{CuO}=\frac{8}{80}=0,1\left(mol\right)\)
\(\Rightarrow m_{Cu}=0,1.64=6,4\left(g\right)\)
\(\Rightarrow n_{H_2}=0,225+0,1=0,325\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,325.22,4=7,28\left(l\right)\)
a) Fe2O3+3H2--->2Fe+3H2O
n Fe=79/56=1,4(mol)
Theo pthh
n Fe2O3=1/2n Fe=0,7(mol)
m Fe2O3=0,7.160=112(g)
b) n H2O=3/2n Fe=0,933(mol)
m H2O=0,933.18=16,794(g)
c) n H2=3/2n Fe=0,933(mol)
V H2=0,933.22,4=20,8992(l)
a)
\(n_{Fe}=\frac{79}{56}\left(mol\right)\)
\(Fe_2O_3+3H_2\rightarrow2Fe+3H_2O\)
79/112_237/112 __79/56__237/112
\(m_{Fe2O3}=\frac{160.79}{112}=112,86\left(g\right)\)
b)
\(m_{H2O}=\frac{237}{112.18}=38,09\left(g\right)\)
c)
\(\rightarrow V_{H2}=\frac{237}{112}.22,4=47,4\left(l\right)\)
Bạn tham khảo câu này ha nếu k cân bằng dc PTHH thì ns với mk nhé https://hoc24.vn/hoi-dap/question/679693.html?pos=1869014
Coi hỗn hợp ban đầu chỉ gồm Fe và O
nFe2(SO4)3= 32/400= 0,08 mol
\(\rightarrow\)nFe= 2nFe2(SO4)3= 0,16 mol
nSO2=\(\frac{0,448}{22,4}\)= 0,02 mol
Fe\(\rightarrow\) Fe+3 +3e
\(\rightarrow\) n e nhường= 0,48 mol
O+ 2e\(\rightarrow\) O-2
S+6 +2e -> S+4 (1)
(1) có nSO2= 0,02 mol \(\rightarrow\)> S+6 nhận 0,04 mol
\(\rightarrow\) O nhận 0,44 mol e \(\rightarrow\) nO= 0,22 mol
\(\rightarrow\) mO= 0,22.16= 3,52g
nFe= 0,16 mol\(\rightarrow\) mFe= 0,16.56= 8,96g
Vậy khối lượng oxit ban đầu là:
m= mFe+ mO= 12,48g
\(n_{H_2\left(2\right)}=\dfrac{2,8}{22,4}=0,125\left(mol\right)\\ PTHH:Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\left(1\right)\\ Fe+H_2SO_4\rightarrow FeSO_4+H_2\left(2\right)\\ n_{Fe}=n_{H_2\left(2\right)}=0,125\left(mol\right)\\ n_{Fe_2O_3}=\dfrac{0,125}{2}=0,0625\left(mol\right)\\ \Rightarrow a=m_{Fe_2O_3}=160.0,0625=10\left(g\right)\\ b=m_{Fe}=0,125.56=7\left(g\right)\)
a pop cs đg onl hem ta