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\(n_{Fe_xO_y}=\dfrac{32}{56x+16y}\left(mol\right)\)
PTHH: FexOy + yH2 --to--> xFe + yH2O
\(\dfrac{32}{56x+16y}\)----------->\(\dfrac{32x}{56x+16y}\)
=> \(\dfrac{32x}{56x+16y}=\dfrac{22,4}{56}=0,4\)
=> \(\dfrac{x}{y}=\dfrac{2}{3}\)
=> CTHH: Fe2O3
\(n_{Fe}=\dfrac{22,4}{56}=0,4mol\)
\(Fe_xO_y+yH_2\rightarrow xFe+yH_2O\)
\(\dfrac{0,4}{x}\) 0,4
\(\Rightarrow M=\dfrac{32}{\dfrac{0,4}{x}}=80x\)
Mà \(M_{Fe_xO_y}=56x+16y=80x\Rightarrow16y=24x\Rightarrow\dfrac{x}{y}=\dfrac{16}{24}=\dfrac{2}{3}\)
\(\Rightarrow\left\{{}\begin{matrix}x=2\\y=3\end{matrix}\right.\Rightarrow Fe_2O_3\)
Ta có: \(n_{H_2}=\dfrac{7,392}{22,4}=0,33\left(mol\right)\)
Gọi: nH2 (pư) = a (mol) ⇒ nH2 (dư) = 10%a (mol)
⇒ a + 10%a = 0,33
⇒ a = 0,3 (mol)
Có: \(H_2+O_{\left(trongoxit\right)}\rightarrow H_2O\)
⇒ nO (trong oxit) = 0,3 (mol)
\(\Rightarrow n_{Fe}=\dfrac{16-m_{O\left(trongoxit\right)}}{56}=0,2\left(mol\right)\)
\(\Rightarrow\dfrac{x}{y}=\dfrac{0,2}{0,3}=\dfrac{2}{3}\)
Vậy: CTHH cần tìm là Fe2O3.
nH2= 0,448/22,4= 0,02(mol)
PTHH :
CuO + H2 -tdo--> Cu + H20
FexOy + yH2 -tdo-> xFe + yH20
Cu + HCl --> k pu
Fe + 2HCl ---> FeCl2 + H2
0,02 -- 0,04---> 0,02 --- 0,02 (mol)
mFe = 0,02 .56= 1,12(g)
=> mCu = 1,76 - 1,12= 0,64(g)
n Cu = 0,64 /64 =0,01(mol)
PTHH :
CuO + H2 -tdo-> Cu + H20
0,,01 --0,01 ----> 0,01(mol)
mCuO= 0,01 . 80 = 0,8(g)
=> mFexOy = 2,4-0,8= 1,6(g)
PTHH :
FexOy + yH2 ---> xFe + yH20
56x+ 16y ---------> 56x
1,6 (g) -------------> 1,12(g)
<=> 1,6 .56x = 1,12( 56x + 16y)
<=> 89,6x = 62,72 x + 17,92y
<=> 89,6x - 62,72x = 17,92y
<=> 26,88 x = 17,92y
=> x/y= 17,92 / 26,88 =2/3
Vậy công thức đúng là Fe203.
\(n_{H_2}=\dfrac{0,672}{22,4}=0,03\left(mol\right)\) \(\Rightarrow y=0,03\left(mol\right)\)
\(Fe_xO_y+yH_2\rightarrow\left(t^o\right)xFe+yH_2O\)
\(n_{H_2}=\dfrac{0,448}{22,4}=0,02mol\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,02 0,02 ( mol )
\(\Rightarrow x=0,02\left(mol\right)\)
\(\Rightarrow\dfrac{x}{y}=\dfrac{0,02}{0,03}=\dfrac{2}{3}\)
\(\Rightarrow CTHH:Fe_2O_3\)
\(n_{H_2\left(thu\right)}=\dfrac{V}{22,4}=\dfrac{0,448}{22,4}=0,02\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
1 : 1 (mol)
0,02 : 0,02 (mol)
\(n_{H_2\left(dùng\right)}=\dfrac{V}{22,4}=\dfrac{0,672}{22,4}=0,03\left(mol\right)\)
\(yH_2+Fe_xO_y\rightarrow^{t^0}xFe+yH_2O\)
y : x (mol)
0,03 : 0,02 (mol)
\(\Rightarrow\dfrac{0,03}{y}=\dfrac{0,02}{x}\)
\(\Rightarrow\dfrac{x}{y}=\dfrac{0,02}{0,03}=\dfrac{2}{3}\Rightarrow x=2;y=3\)
-Vậy CTHH của oxit sắt là Fe2O3.
\(CT:Fe_xO_y\)
\(Fe_xO_y+yH_2\underrightarrow{^{t^o}}xFe+yH_2O\left(1\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\left(2\right)\)
\(n_{Fe}=n_{H_2\left(2\right)}=\dfrac{4.032}{22.4}=0.18\left(mol\right)\)
\(n_{H_2\left(1\right)}=\dfrac{y}{x}\cdot n_{Fe}=\dfrac{5.376}{22.4}=0.24\left(mol\right)\)
\(\Leftrightarrow\dfrac{y}{x}\cdot0.18=0.24\)
\(\Leftrightarrow\dfrac{x}{y}=\dfrac{3}{4}\)
\(CT:Fe_3O_4\)
\(m_{Fe_3O_4}=\dfrac{0.18}{3}\cdot232=13.92\left(g\right)\)
Sửa: \(32g\) oxit sắt
\(n_{H_2}=\dfrac{13,44}{22,4}=0,6(mol)\\ PTHH:Fe_xO_y+yH_2\to xFe+yH_2O\\ \Rightarrow y.n_{Fe_xO_y}=n_{H_2}=0,6(mol)\\ \Rightarrow \dfrac{32y}{56x+16y}=0,6\\ \Rightarrow 32y=33,6x+9,6y\\ \Rightarrow 33,6x=22,4y\\ \Rightarrow \dfrac{x}{y}=\dfrac{22,4}{33,6}=\dfrac{2}{3}\\ \Rightarrow x=2;y=3\)
Vậy CTHH là \(Fe_2O_3\)
\(Fe_3O_4+4H_2\underrightarrow{t^o}3Fe+4H_2O\)
\(Fe_xO_y+yH_2\underrightarrow{t^o}xFe+yH_2O\)
Ta có: \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
Theo PT: \(n_{H_2O}=n_{H_2}=0,5\left(mol\right)\)
Theo ĐLBT KL, có: mFe3O4 + mFexOy + mH2 = mFe + mH2O
⇒ a = mFe3O4 = 19,6 + 0,5.18 - 0,5.2 - 16 = 11,6 (g)
\(\Rightarrow n_{Fe_3O_4}=\dfrac{11,6}{232}=0,05\left(mol\right)\)
Có: \(n_{Fe}=\dfrac{19,6}{56}=0,35\left(mol\right)\)
Theo PT: \(n_{Fe}=3n_{Fe_3O_4}+x.n_{Fe_xO_y}\Leftrightarrow0,35=3.0,05+x.n_{Fe_xO_y}\Rightarrow n_{Fe_xO_y}=\dfrac{0,2}{x}\left(mol\right)\)
\(\Rightarrow M_{Fe_xO_y}=\dfrac{16}{\dfrac{0,2}{x}}=80x\left(g/mol\right)\)
Mà: \(M_{Fe_xO_y}=56x+16y\left(g/mol\right)\)
\(\Rightarrow56x+16y=80x\Rightarrow\dfrac{x}{y}=\dfrac{2}{3}\)
Vậy: CTHH cần tìm là Fe2O3
\(n_{H_2\left(đktc\right)}=\dfrac{V}{22,4}=\dfrac{17,92}{22,4}=0,8\left(mol\right)\)
\(yH_2+Fe_xO_y\rightarrow^{t^0}yH_2O+xFe\)
y : 1 (mol)
0,8 : \(\dfrac{0,8}{y}\) (mol)
\(\Rightarrow M_{Fe_xO_y}=\dfrac{m}{n}=\dfrac{46,4}{\dfrac{0,8}{y}}=58y\) (g/mol)
\(\Rightarrow56x+16y=58y\)
\(\Rightarrow56x=42y\)
\(\Rightarrow\dfrac{x}{y}=\dfrac{42}{56}=\dfrac{3}{4}\Rightarrow x=3;y=4\)
-CTHH của oxit sắt là Fe3O4
mình ghi sai đề thật camon ban nhiềuuu