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\(a)CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ b)n_{CuO}=\dfrac{4}{80}=0,05mol\\ n_{H_2SO_4}=\dfrac{100.20}{100.98}=\dfrac{10}{49}mol\\ \Rightarrow\dfrac{0,05}{1}< \dfrac{10:49}{1}\rightarrow H_2SO_4.dư\\ n_{CuSO_4}=n_{H_2SO_4}=n_{CuO}=0,05mol\\ C_{\%CuSO_4}=\dfrac{0,05.160}{100+4}\cdot100=7,69\%\\ C_{\%H_2SO_4}=\dfrac{\left(10:49-0,05\right)98}{100+4}\cdot100=14,52\%\)
Ta có: \(n_{H_2SO_4}=\dfrac{200.19,6\%}{98}=0,4\left(mol\right)\)
\(n_{Cu\left(OH\right)_2}=\dfrac{29,4}{98}=0,3\left(mol\right)\)
PT: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
Dung dịch A gồm: CuSO4 và H2SO4 dư
\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)
\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
Đề có cho dữ kiện gì liên quan đến dd NaOH không bạn nhỉ?
\(n_{H_2SO_4}=\dfrac{200.19,6}{100.98}=0,4mol\\ CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4\left(A\right)}=n_{CuO}=n_{H_2SO_4}=0,4mol\\ n_{Cu\left(OH\right)_2}=\dfrac{29,4}{98}=0,3mol\\ CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\\\Rightarrow\dfrac{0,4}{1}>\dfrac{0,3}{1}\Rightarrow CuSO_4.pư.không.hết\)
\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
0,3mol 0,6mol 0,3mol
\(m_{ddB}=0,4.80+200+0,6.40-29,4=226,6g\\ C_{\%Na_2SO_4\left(B\right)}=\dfrac{0,3.142}{226,6}\cdot100=18,8\%\)
\(n_{Fe_2O_3}=\dfrac{20}{160}=0,125\left(mol\right)\)
PTHH:
\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
0,125 0,375 0,125 0,375
\(m_{ddH_2SO_4}=\dfrac{0,375.98.100}{25}=147\left(g\right)\)
\(C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0,125.406}{20+147}\approx30,39\%\)
\(n_{Al}=\dfrac{10,8}{27}=0,4(mol)\\ a,2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ \Rightarrow n_{H_2}=n_{H_2SO_4}=0,6(mol);n_{Al_2(SO_4)_3}=0,2(mol)\\ b,V_{H_2}=0,6.22,4=13,44(l)\\ c,m_{dd_{H_2SO_4}}=\dfrac{0,6.98}{9,8\%}=600(g)\\ \Rightarrow C\%_{Al_2(SO_4)_3}=\dfrac{0,2.342}{10,8+600-0,6.2}.100\%=11,22\%\)
Ta có: \(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
\(m_{H_2SO_4}=200.19,6\%=39,2\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{39,2}{98}=0,4\left(mol\right)\)
a, PT: \(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
b, Xét tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,4}{3}\), ta được H2SO4 dư.
Theo PT: \(\left\{{}\begin{matrix}n_{Fe_2\left(SO_4\right)_3}=n_{Fe_2O_3}=0,1\left(mol\right)\\n_{H_2SO_4\left(pư\right)}=3n_{Fe_2O_3}=0,3\left(mol\right)\end{matrix}\right.\)
⇒ nH2SO4 (dư) = 0,4 - 0,3 = 0,1 (mol)
Ta có: m dd sau pư = mFe2O3 + m dd H2SO4 = 16 + 200 = 216 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0,1.400}{216}.100\%\approx18,52\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{0,1.98}{216}.100\%\approx4,54\%\end{matrix}\right.\)
Bạn tham khảo nhé!
\(n_{Fe_2O_3}=\dfrac{16}{160}=0.1\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{200\cdot19.6\%}{98}=0.4\left(mol\right)\)
\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
\(LTL:\dfrac{0.1}{1}< \dfrac{0.4}{3}\Rightarrow H_2SO_4dư\)
\(m_{\text{dung dịch sau phản ứng}}=16+200=216\left(g\right)\)
\(C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0.1\cdot400}{216}\cdot100\%=18.51\%\)
\(C\%_{H_2SO_4}=\dfrac{\left(0.4-0.2\right)\cdot98}{216}\cdot100\%=9.1\%\)
Bài 4 :
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
a) Pt : \(Zn+2HCl\rightarrow ZnCl_2+H_2|\)
1 2 1 1
0,2 0,4 0,2 0,2
b) \(n_{H2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,2.22,4=4,48\left(l\right)\)
c) \(n_{HCl}=\dfrac{0,2.2}{1}=0,4\left(mol\right)\)
⇒ \(m_{HCl}=0,4.36,5=14,6\left(g\right)\)
\(C_{ddHCl}=\dfrac{14,6.100}{100}=14,6\)0/0
d) \(n_{ZnCl2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
⇒ \(m_{ZnCl2}=0,2.136=27,2\left(g\right)\)
\(m_{ddspu}=13+100-\left(0,2.2\right)=112,6\left(g\right)\)
\(C_{ZnCl2}=\dfrac{27,2.100}{112,6}=24,16\)0/0
Chúc bạn học tốt
Bài 3 :
\(n_{Mg}=\dfrac{12}{24}=0,5\left(mol\right)\)
a) Pt : \(Mg+H_2SO_4\rightarrow MgSO_4+H_2|\)
1 1 1 1
0,5 0,5 0,5 0,5
b) \(n_{H2}=\dfrac{0,5.1}{1}=0,5\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,5.22,4=11,2\left(l\right)\)
c) \(n_{H2SO4}=\dfrac{0,5.1}{1}=0,5\left(mol\right)\)
⇒ \(m_{H2SO4}=0,5.98=49\left(g\right)\)
\(C_{ddH2SO4}=\dfrac{49.100}{200}=24,5\)0/0
d) \(n_{MgSO4}=\dfrac{0,5.1}{1}=0,5\left(mol\right)\)
⇒ \(m_{MgSO4}=0,5.120=60\left(g\right)\)
\(m_{ddspu}=12+200-\left(0,5.2\right)=211\left(g\right)\)
\(C_{MgSO4}=\dfrac{60.100}{211}=28,44\)0/0
Chúc bạn học tốt
a) nFe2O3=1,6/160=0,01(mol)
mH2SO4=19,6%.200=39,2(g) -> nH2SO4=39,2/98=0,4(mol)
PTHH: Fe2O3 + 3 H2SO4 -> Fe2(SO4)3 + 3 H2O
Ta có: 0,4/3 > 0,01/1
=> Fe2O3 hết, H2SO4 dư, tính theo nFe2O3
b) nFe2(SO4)3=nFe3O4=0,01(mol) => mFe2(SO4)3=0,01.400=4(g)
nH2SO4(dư)= 0,4 - 0,01.3= 0,37(mol) =>mH2SO4(dư)=0,37.98=36,26(g)
mddsau=1,6+200=201,6(g)
=>C%ddFe2(SO4)3= (4/201,6).100= 1,984%
C%ddH2SO4(dư)= (36,26/201,6).100=17,986%
a,\(n_{Fe_2O_3}=\dfrac{1,6}{160}=0,01\left(mol\right)\)
\(m_{H_2SO_4}=19,6\%.200=39,2\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{39,2}{98}=0,4\left(mol\right)\)
\(PTHH:Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
Mol: 0,01 0,03 0,01
Tỉ lệ:\(\dfrac{0,01}{1}< \dfrac{0,4}{3}\)⇒Fe2O3 pứ hết,H2SO4 dư
b,mdd sau pứ = 200+1,6 = 201,6 (g)
\(C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0,01.400}{201,6}.100\%=1,98\%\)
\(C\%_{H_2SO_4dư}=\dfrac{\left(0,4-0,03\right).98}{201,6}.100\%=17,98\%\)