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a)
$2K + 2H_2O \to 2KOH + H_2$
$BaO + H_2O \to Ba(OH)_2$
Theo PTHH :
$n_K = 2n_{H_2} = 0,2(mol)$
$\%m_K = \dfrac{0,2.39}{23,1}.100\% = 33,77\%$
$\%m_{BaO} = 100\%- 33,77\% = 66,23\%$
b)
$n_{BaO} = \dfrac{23,1 - 0,2.39}{153} = 0,1(mol)$
$m_{dd} = 23,1 + 177,1 - 0,1.2 = 200(gam)$
$C\%_{KOH} = \dfrac{0,2.56}{200}.100\% = 5,6\%$
$C\%_{Ba(OH)_2} = \dfrac{0,1.171}{200}.100\% = 8,55\%$
c)
$KOH + HCl \to KCl + H_2O$
$Ba(OH)_2 + 2HCl \to BaCl_2 + 2H_2O$
$n_{HCl} = 2n_{Ba(OH)_2} + n_{KOH} = 0,4(mol)$
$V = \dfrac{0,4}{0,5} = 0,8(lít) = 800(ml)$
\(n_{Na}=\dfrac{2.3}{23}=0.1\left(mol\right)\)
\(n_{HCl}=0.4\cdot2=0.8\left(mol\right)\)
\(NaOH+HCl\rightarrow NaCl+H_2O\)
\(0.8..............0.8\)
\(2Na+2H_2O\rightarrow2NaOH+H_{_{ }2}\)
\(0.1........................0.1\)
\(n_{NaOH}=0.1< 0.8\)
Đề nhầm lãn !
nH2=\(\frac{6,72}{22,4}=0,3\)mol
PTHH
M+2HCl--> MCl2+H2
0,3mol<---------------0,3mol
=>MM=\(\frac{19,5}{0,3}=64\)
=> km loại là kẽm (Zn)
b) nNaOH=0,2.1=0,2 mol
PTHH
NaOH+HCl-->NaCl + H2O
0,2 mol--> 0,2 mol
---> thể tích HCl 1M đã dùng là V=\(\frac{0,2+0,3}{1}=0,5\)lít
=> CM(ZnCl2)=\(\frac{0,3}{0,5}=0,6M\)
1)
$n_{Na_2O} = \dfrac{6,2}{62} = 0,1(mol)$
$Na_2O + H_2O \to 2NaOH$
$n_{NaOH} = 2n_{Na_2O} = 0,2(mol)$
$m_{dd} = 6,2 + 193,8 = 200(gam) \Rightarrow C\%_{NaOH} = \dfrac{0,2.40}{200}.100\% = 4\%$
2)
$n_{K_2O} = \dfrac{23,5}{94} = 0,25(mol)$
$K_2O + H_2O \to 2KOH$
$n_{KOH} = 2n_{K_2O} = 0,5(mol) \Rightarrow C_{M_{KOH}} = \dfrac{0,5}{0,5} = 1M$
3) $n_{Na_2O} = \dfrac{12,4}{62} = 0,2(mol)$
$Na_2O + H_2O \to 2NaOH$
$n_{NaOH} = 2n_{Na_2O} = 0,4(mol)$
$C_{M_{NaOH}} = \dfrac{0,4}{0,5} =0,8M$
4)
$Na_2SO_3 + 2HCl \to 2NaCl +S O_2 + H_2O$
Theo PTHH :
$n_{SO_2} = n_{Na_2SO_3} = \dfrac{12,6}{126} = 0,1(mol)$
$V_{SO_2} = 0,1.22,4 = 2,24(lít)$
5) $n_{CaO} = \dfrac{5,6}{56} = 0,1(mol)$
$CaO + 2HCl \to CaCl_2 + H_2O$
Theo PTHH :
$n_{HCl} = 2n_{CaO} = 0,2(mol) \Rightarrow m_{dd\ HCl} = \dfrac{0,2.36,5}{14,6\%} = 50(gam)$
Ta có: \(n_{SO_3}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
\(a,PTHH:SO_3+H_2O--->H_2SO_4\left(1\right)\)
Ta lại có: \(m_{dd_A}=0,25.80+100=120\left(g\right)\)
Theo PT(1): \(n_{H_2SO_4}=n_{SO_3}=0,25\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=0,25.98=24,5\left(g\right)\)
\(\Rightarrow C_{\%_A}=\dfrac{24,5}{120}.100\%=20,42\%\)
\(b.PTHH:2KOH+H_2SO_4--->K_2SO_4+2H_2O\left(2\right)\)
Theo PT(2): \(n_{KOH}=2.n_{H_2SO_4}=2.0,25=0,5\left(mol\right)\)
\(\Rightarrow V_{dd_{KOH}}=\dfrac{0,5}{2}=0,25\left(lít\right)\)
tk
Ta có: nSO3=5,622,4=0,25(mol)nSO3=5,622,4=0,25(mol)
a,PTHH:SO3+H2O−−−>H2SO4(1)a,PTHH:SO3+H2O−−−>H2SO4(1)
Ta lại có: mddA=0,25.80+100=120(g)mddA=0,25.80+100=120(g)
Theo PT(1): nH2SO4=nSO3=0,25(mol)nH2SO4=nSO3=0,25(mol)
⇒mH2SO