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\(a,n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\)
PTHH: Zn + 2HCl ---> ZnCl2 + H2
0,125->0,25----->0,125->0,125
\(\Rightarrow\left\{{}\begin{matrix}a,V_{ddHCl}=\dfrac{0,25}{0,5}=0,5\left(l\right)\\b,V_{H_2}=0,125.22,4=2,8\left(l\right)\\c,C_{M\left(ZnCl_2\right)}=\dfrac{0,125}{0,5}=0,25M\end{matrix}\right.\)
\(n_{Zn}=\dfrac{26}{65}=0,4\left(mol\right)\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,4 0,8 0,4 0,4
\(a,V_{H_2}=0,4.22,4=8,96\left(l\right)\\ b,C\%_{HCl}=\dfrac{0,8.36,5}{150}.100\%=19,5\%\\ c,m_{\text{dd}}=26+150-\left(0,4.2\right)=175,2\left(g\right)\\ C\%_{ZnCl_2}=\dfrac{0,4.136}{175,2}.100\%=31\%\)
a) Zn + 2HCl → ZnCl2 + H2
b) n H2 = n Zn = 1,95/65 = 0,03(mol)
V H2 = 0,03.22,4 = 0,672(lít)
c) n ZnCl2 = n Zn = 0,03(mol)
=> m dd sau pư = 1,95 + 120 - 0,03.2 = 121,89(gam)
C% ZnCl2 = 0,03.136/121,89 .100% = 3,35%
a) nZn=0,03(mol)
PTHH: Zn + 2 HCl -> ZnCl2 + H2
nH2=nZnCl2=nZn=0,03(mol)
b) V(H2,đktc)=0,03.22,4=0,672(l)
c) mZnCl2=136.0,03=4,08(g)
mddA=mddZnCl2=1,95+ 120 - 0,03.2= 121,89(g)
=> C%ddZnCl2=(4,08/121,89).100=3,347%
\(n_{Fe}=\dfrac{36,4}{56}=0,65\left(mol\right)\)
PTHH: Fe + 2HCl ---> FeCl2 + H2
0,65->1,3----->0,65--->0,65
=> \(\left\{{}\begin{matrix}a,V_{ddHCl}=\dfrac{1,3}{0,5}=2,6\left(l\right)\\b,V_{H_2}=0,65.22,4=14,56\left(l\right)\end{matrix}\right.\)
c, \(C_{M\left(FeCl_2\right)}=\dfrac{0,65}{2,6}=0,25M\)
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
\(m_{HCl}=100.14,6\%=14,6\left(g\right)\Rightarrow n_{HCl}=\dfrac{14,6}{36,5}=0,4\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,4}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{HCl\left(pư\right)}=2n_{Zn}=0,2\left(mol\right)\\n_{ZnCl_2}=n_{Zn}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl\left(dư\right)}=0,4-0,2=0,2\left(mol\right)\)
Ta có: m dd sau pư = 6,5 + 100 - 0,1.2 = 106,3 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,1.136}{106,3}.100\%\approx12,79\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,2.36,5}{106,3}.100\%\approx6,87\%\end{matrix}\right.\)
a)
$Fe + 2HCl \to FeCl_2 + H_2$
n H2 = n Fe = 11,2/56 = 0,2(mol)
V H2 = 0,2.22,4 = 4,48(lít)
b)
n HCl = 2n Fe = 0,2.2 = 0,4(mol)
=> CM HCl = 0,4/0,4 = 1M
c)
$CuO + H_2 \xrightarrow{t^o} Cu + H_2O$
Ta thấy :
n CuO = 64/80 = 0,8 > n H2 = 0,2 nên CuO dư
Theo PTHH :
n CuO pư = n Cu = n H2 = 0,2(mol)
n Cu dư = 0,8 - 0,2 = 0,6(mol)
Vậy :
%m Cu = 0,2.64/(0,2.64 + 0,6.80) .100% = 21,05%
%m CuO = 100% -21,05% = 78,95%
