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a)
\(b)n_{Fe_3O_4} = \dfrac{6,96}{232} = 0,03(mol)\\ 3Fe + 2O_2 \xrightarrow{t^o}Fe_3O_4\\ n_{Fe} = 3n_{Fe_3O_4} = 0,09(mol)\\ m_{Fe} = 0,09.56 = 5,04(gam)\\ c) n_{O_2} = 2n_{Fe_3O_4} = 0,06(mol)\\ V_{O_2} = 0,06.22,4 = 1,344(lít)\\ d) 2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2\\ n_{KMnO_4} = 2n_{O_2} = 0,12(mol)\\ m_{KMnO_4} = 0,12.158 = 18,96(gam)\)
\(n_{Fe_3O_4}=\dfrac{6.96}{232}=0.03\left(mol\right)\)
\(3Fe+2O_2\underrightarrow{t^0}Fe_2O_3\)
\(0.09.....0.06.......0.03\)
\(m_{Fe}=0.09\cdot56=5.04\left(g\right)\)
\(V_{O_2}=0.06\cdot22.4=1.344\left(l\right)\)
\(2KMnO_4\underrightarrow{t^0}K_2MnO_4+MnO_2+O_2\)
\(0.12...............................................0.06\)
\(m_{KMnO_4}=0.12\cdot158=18.96\left(g\right)\)
n Fe3O4=\(\dfrac{13,92}{232}\)=0,06 mol
3Fe + 2O2 -to--> Fe3O4
0,18------0,12-------0,06
=>m Fe=0,18.56=10,08g
=>VO2=0,12.22,4=2,688l
2KMnO4-to>K2MnO4+MnO2+O2
0,24-------------------------------------0,12
=>m KMnO4=0,24.158=37,92g
nFe3O4 = 13,92 : 160= 0,087 (mol)
pthh : 3Fe + 2O2 -t--> Fe3O4
0,087->0,058-->0,029 (mol)
=> mFe = 0,029 . 56 = 1,624 (g)
=> VO2 = 0,058 . 22,4 = 1,2992 (L)
pthh : 2KMnO4 -t--> K2MnO4 + MnO2 + O2
0,116<------------------------------0,058 (mol)
=> mKMnO4 = 0,116 . 158 = 18,328 (g)
a)
\(n_{P_2O_5} = \dfrac{42,6}{142} = 0,3(mol)\\ \)
4P + 5O2 \(\xrightarrow{t^o}\) 2P2O5
0,6.............0,75.................0,3..........(mol)
mP = 0,6.31 = 18,6(gam)
b)
2KClO3 \(\xrightarrow{t^o}\) 2KCl + 3O2
0,5....................................0,75.....(mol)
\(m_{KClO_3} = 0,5.122,5 = 61,25(gam)\)
c)
\(3Fe + 2O_2 \xrightarrow{t^o} Fe_3O_4\)
\(n_{Fe} = \dfrac{16,8}{56} = 0,3(mol)\\ \dfrac{n_{Fe}}{3} = 0,1 < \dfrac{n_{O_2}}{2} = 0,375\)
nên hiệu suất tính theo số mol Fe.
\(n_{Fe\ pư} = 0,3.90\% = 0,27(mol)\\ n_{Fe_3O_4} =\dfrac{1}{3}n_{Fe\ pư} = 0,09(mol)\\ \Rightarrow m_{Fe_3O_4} = 0,09.232 = 20,88(gam)\)
\(n_{Fe_3O_4}=\dfrac{m_{Fe_3O_4}}{M_{Fe_3O_4}}=\dfrac{23,2}{232}=0,1mol\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
0,3 0,2 0,1 ( mol )
\(m_{Fe}=n_{Fe}.M_{Fe}=0,3.56=16,8g\)
\(V_{O_2}=n_{O_2}.22,4=0,2.22,4=4,48l\)
\(V_{kk}=\dfrac{4,48.100}{20}=22,4l\)
\(2KMnO_4\rightarrow\left(t^o\right)K_2MnO_4+MnO_2+O_2\)
0,4 0,2 ( mol )
\(n_{KMnO_4}=\dfrac{0,4}{85\%}=\dfrac{8}{17}mol\)
\(m_{KMnO_4}=n_{KMnO_4}.M_{KMnO_4}=\dfrac{8}{17}.158=74,3529g\)
\(PTHH:3Fe+2O_2\xrightarrow{t^o}Fe_3O_4\\ BTKL:m_{O_2}=m_{Fe_3O_4}-m_{Fe}=23,2-16,8=6,4(g)\)
\(a,3Fe+2O_2\xrightarrow{t^o}Fe_3O_4\\ b,\text{Bảo toàn KL: }m_{Fe}+m_{O_2}=m_{Fe_3O_4}\\ c,m_{O_2}=m_{Fe_3O_4}-m_{Fe}=28,4-12,4=16(g)\)
a, PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
Theo PT: \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=\dfrac{1}{30}\left(mol\right)\Rightarrow m_{Fe_3O_4}=\dfrac{1}{30}.232\approx7,733\left(g\right)\)
c, Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=\dfrac{1}{15}\left(mol\right)\)
PT: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
\(n_{KMnO_4\left(LT\right)}=2n_{O_2}=\dfrac{2}{15}\left(mol\right)\)
\(\Rightarrow m_{KMnO_4\left(LT\right)}=\dfrac{2}{15}.158=\dfrac{316}{15}\left(g\right)\)
Mà: H% = 85%
\(\Rightarrow m_{KMnO_4\left(TT\right)}=\dfrac{\dfrac{316}{15}}{85\%}\approx24,78\left(g\right)\)
PTHH: \(2KMnO_4\xrightarrow[]{t^o}K_2MnO_4+MnO_2+O_2\)
\(n_{KMnO_4}=\dfrac{m_{KMnO_4}}{M_{KMnO_4}}=\dfrac{15,8}{158}=0,1\left(mol\right)\)
a. Theo PTHH: \(n_{O_2}=\dfrac{1}{2}n_{KMnO_4}=\dfrac{1}{2}0,1=0,05\left(mol\right)\)
\(\Rightarrow V_{O_2}=n_{O_2}.22,4=0,05.22,4=1,12\left(l\right)\)
b. PTHH: \(3Fe+2O_2\xrightarrow[]{t^o}Fe_3O_4\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
Ta có: \(\dfrac{1}{n_{O_2}}=\dfrac{1}{0,05}\)
\(\dfrac{1}{n_{Fe}}=\dfrac{1}{0,1}\)
\(\Rightarrow\dfrac{1}{n_{O_2}}>\dfrac{1}{n_{Fe}}\)
Vậy Fe dư
Theo PTHH: \(n_{Fe_3O_4}=\dfrac{0,1.1}{3}=\dfrac{1}{30}\left(mol\right)\)
\(\Rightarrow m_{Fe_3O_4}=n_{Fe_3O_4}.M_{Fe_3O_4}=\dfrac{1}{30}.232\approx7,73g\)
\(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
0,6 0,4 0,2
\(n_{Fe_3O_4}=\dfrac{46,4}{232}=0,2\left(mol\right)\)
\(a,m_{Fe}=0,6.56=33,6\left(g\right)\)
\(b,m_{O_2}=0,4.32=12,8\left(g\right)\)
a. \(\text{3Fe + 2O2}\rightarrow Fe3O4\)
b.
nFe = \(\frac{16,8}{56}\) = 0,3 mol
nO2 = \(\frac{6,4}{32}\) = 0,2 mol
nFe3O4 = \(\frac{20,88}{232}\)= 0,09 mol
PTHH: 3Fe + 2O2\(\rightarrow\) Fe3O4
Bđ:____0,3___0,2
Pư:___0,27 <-0,18 <------0,09
Hiệu suất phản ứng:
H% = = \(\frac{0,27}{0,3}\).100% = 90%
a) Fe + O2 ➞ Fe2O3
PTHH: 4Fe + 3O2 ➜ 2Fe2O3