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BTKL : \(m_{CO_2}+m_{H_2O}=m_X+m_{O_2}=15,96\left(g\right)\)
=> \(m_{binhtang}=m_{CO_2}+m_{H_2O}=15,96\left(g\right)\)
\(n_P=\dfrac{12,4}{31}=0,4\left(mol\right)\\ a,PTHH:4P+5O_2\rightarrow\left(t^o\right)2P_2O_5\\ b,n_{O_2}=\dfrac{5}{4}.0,4=0,5\left(mol\right)\\ V_{O_2\left(đktc\right)}=0,5.22,4=11,2\left(l\right)\\ c,n_{P_2O_5}=\dfrac{2}{4}.0,4=0,2\left(mol\right)\\ m_{P_2O_5}=142.0,2=28,4\left(g\right)\)
\(n_{CaCO_3}=\dfrac{7,5}{100}=0,075\left(mol\right)\)
=> nC = 0,075 (mol)
Có \(n_{CO_2}=n_C=0,075\left(mol\right)\)
=> \(n_{H_2O}=\dfrac{4,2-0,075.44}{18}=0,05\left(mol\right)\)
=> nH = 0,1 (mol)
\(n_{O_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Bảo toàn O: \(n_{O\left(A\right)}=0,075.2+0,05-0,1.2=0\left(mol\right)\)
=> A chứa C, H
mA = mC + mH = 0,075.12 + 0,1.1 = 1 (g)
\(m_{tăng}=m_{H_2O}+m_{CO_2}=4,2\left(g\right)\\ n_{CaCO_3}=\dfrac{7,5}{100}=0,075\left(mol\right)\)
PTHH: Ca(OH)2 + CO2 ---> CaCO3 + H2O
0,075 0,075
\(\rightarrow m_{CO_2}=0,075.44=3,3\left(g\right)\\ \rightarrow m_{H_2O}=4,2-3,3=0,9\left(g\right)\\ \rightarrow n_{H_2O}=\dfrac{0,9}{18}=0,05\left(mol\right)\\ \rightarrow n_{O\left(sau.pư\right)}=0,05+0,075.2=0,1\left(mol\right)\\ n_{O\left(trong.O_2\right)}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ \rightarrow\left\{{}\begin{matrix}n_C=0,075\left(mol\right)\\n_H=0,05.2=0,1\left(mol\right)\\n_O=0,1-0,1=0\left(mol\right)\end{matrix}\right.\)
=> mA = 0,075.12 + 0,1.1 + 0 = 1 (g)
a. \(n_P=\frac{6,2}{31}=0,2mol\)
\(V_{O_2}=V_{kk}.\frac{1}{5}=\frac{18,48}{5}=3,696l\)
\(n_{O_2}=\frac{3,696}{22,4}=0,165mol\)
PTHH: \(4P+5O_2\xrightarrow{t^o}2P_2O_5\)
Tỷ lệ \(\frac{0,2}{4}>\frac{0,165}{5}\)
Vậy P dư
\(n_{P\left(\text{phản ứng }\right)}=\frac{4}{5}n_{O_2}=0,132mol\)
\(n_{P\left(dư\right)}=0,2-0,132=0,068mol\)
\(\rightarrow m_{P\left(dư\right)}=0,068.31=2,108g\)
b. \(n_{P_2O_5}=\frac{2}{5}n_{O_2}=0,066mol\)
\(\rightarrow m_{P_2O_5}=0,066.142=9,372g\)
c. PTHH: \(2KClO_3\xrightarrow{t^o}2KCl+3O_2\)
\(n_{KClO_3}=\frac{2}{3}n_{O_2}=0,11mol\)
\(\rightarrow m_{KClO_3}=0,11.122,5=13,475g\)
\(n_C=\dfrac{14,4}{44}=\dfrac{18}{55}\left(mol\right)\\ C+O_2\rightarrow\left(t^o\right)CO_2\\ n_{O_2}=n_C=n_{CO_2}=\dfrac{18}{55}\left(mol\right)\\ a,V_{O_2\left(đktc\right)}=\dfrac{18}{55}.22,4=\dfrac{2016}{275}\left(lít\right)\\ b,V_{kk}=\dfrac{100}{21}.\dfrac{2016}{275}=\dfrac{381}{11}\left(lít\right)\\ c,2KClO_3\rightarrow\left(t^o\right)2KCl+3O_2\\ n_{KClO_3\left(LT\right)}=\dfrac{2}{3}.n_{O_2}=\dfrac{2}{3}.\dfrac{18}{55}=\dfrac{12}{55}\left(mol\right)\\ \Rightarrow n_{KClO_3\left(TT\right)}=120\%.\dfrac{12}{55}=\dfrac{72}{275}\left(mol\right)\\ \Rightarrow m_{KClO_3}=122,5.\dfrac{72}{275}=\dfrac{1764}{55}\left(g\right)\)
