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Gọi \(\left\{{}\begin{matrix}n_{H_2}=a\left(mol\right)\\n_{CO}=b\left(mol\right)\end{matrix}\right.\)⇒ 2a + 28b = 6,8(1)
\(2H_2 + O_2 \xrightarrow{t^o} 2H_2O\\ 2CO + O_2 \xrightarrow{t^o} 2CO_2\)
Theo PTHH :
\(n_{O_2} = 0,5a + 0,5b = \dfrac{8,96}{22,4} = 0,4(2)\)
Từ (1)(2) suy ra: a = 0,6 ; b = 0,2
Vậy :
\(\%m_{H_2} = \dfrac{0,6.2}{6,8}.100\% = 17,65\%\\ \%m_{CO} = 100\% - 17,65\% = 82,35\%\)
Cho em hỏi tại sao no2=0.5a+0.5b=0.4
tại sao viết 0.5 mà ko là 1 ạ
\(m_{CH_4} = 8.30\% = 2,4(gam)\\ m_{C_2H_4} = 8 - 2,4 = 5,6(gam)\\ CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_4 + 3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O\\\)
Theo PTHH :
\(n_{CO_2} = n_{CH_4} + 2n_{C_2H_4} = \dfrac{2,4}{16} + \dfrac{5,6}{28}.2 = 0,55(mol)\\ \Rightarrow m_{CO_2} = 0,55.44 = 24,2(gam)\)
\(m_{CH_4}=0.3\cdot8=2.4\left(g\right)\)
\(n_{CH_4}=\dfrac{2.4}{16}=0.15\left(mol\right)\)
\(m_{C_2H_4}=8-2.4=5.6\left(g\right)\)
\(n_{C_2H_4}=\dfrac{5.6}{28}=0.2\left(mol\right)\)
\(CH_4+2O_2\underrightarrow{t^0}CO_2+2H_2O\)
\(C_2H_4+3O_2\underrightarrow{t^0}2CO_2+2H_2O\)
\(n_{CO_2}=2\cdot0.15+0.2=0.5\left(mol\right)\)
\(m_{CO_2}=0.5\cdot44=22\left(g\right)\)
Giả sử các khí được đo ở điều kiện sao cho 1 mol khí chiếm thể tích 1 lít
Gọi số mol CH4, C2H6 là a, b (mol)
=> \(a+b=\dfrac{25}{1}=25\left(mol\right)\) (1)
\(n_{O_2}=\dfrac{95}{1}=95\left(mol\right)\)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
a---->2a---------->a
2C2H6 + 7O2 --to--> 4CO2 + 6H2O
b------>3,5b-------->2b
=> \(\left\{{}\begin{matrix}n_{O_2\left(dư\right)}=95-2a-3,5b\left(mol\right)\\n_{CO_2}=a+2b\left(mol\right)\end{matrix}\right.\)
=> \(95-a-1,5b=\dfrac{60}{1}=60\)
=> a + 1,5b = 35 (2)
(1)(2) => a = 5; b = 20
=> \(\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{5}{25}.100\%=20\%\\\%V_{C_2H_6}=\dfrac{20}{25}.100\%=80\%\end{matrix}\right.\)
\(\overline{M}_A=\dfrac{5.16+20.30}{5+20}=27,2\left(g/mol\right)\)
\(\overline{M}_B=20,5.2=41\left(g/mol\right)\)
=> \(d_{A/B}=\dfrac{27,2}{41}\approx0,663\)
\(n_X=\dfrac{0,896}{22,4}=0,08\left(mol\right)\)
\(M_X=21.2=42\left(g\text{/}mol\right)\\ \rightarrow m_X=0,08.42=3,36\left(g\right)\)
PTHH:
\(C_3H_4+4O_2\xrightarrow[]{t^o}3CO_2+H_2O\\ 2C_3H_6+9O_2\xrightarrow[]{t^o}6CO_2+6H_2O\\ C_3H_8+5O_2\xrightarrow[]{t^o}3CO_2+4H_2O\)
Theo PTHH: \(n_C=n_{CO_2}=3n_X=3.0,08=0,24\left(mol\right)\)
\(\rightarrow V_{CO_2}=0,24.22,4=5,376\left(l\right)\)
BTNT:
\(m_H=m_X=m_C=3,36-0,24.12=0,48\left(g\right)\\ \rightarrow n_H=\dfrac{0,48}{1}=0,48\left(mol\right)\)
Theo PTHH: \(n_{H_2O}=\dfrac{1}{2}n_H=\dfrac{1}{2}.0,48=0,24\left(mol\right)\)
\(\rightarrow m_{H_2O}=0,24.18=3,42\left(g\right)\)
nX=0,89622,4=0,08(mol)nX=0,89622,4=0,08(mol)
MX=21.2=42(g/mol)→mX=0,08.42=3,36(g)MX=21.2=42(g/mol)→mX=0,08.42=3,36(g)
PTHH:
C3H4+4O2to→3CO2+H2O2C3H6+9O2to→6CO2+6H2OC
a) PTHH: \(2CO+O_2\underrightarrow{t^o}2CO_2\) (1)
\(4H_2+O_2\underrightarrow{t^o}2H_2O\) (2)
b) Ta có: \(\left\{{}\begin{matrix}\Sigma n_{O_2}=\dfrac{9,6}{32}=0,3\left(mol\right)\\n_{CO_2}=\dfrac{8,8}{44}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{O_2\left(1\right)}=0,1mol\\n_{O_2\left(2\right)}=0,2mol\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CO}=0,1\cdot28=2,8\left(g\right)\\m_{H_2}=0,2\cdot2=0,4\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{CO}=\dfrac{2,8}{2,8+0,4}\cdot100\%=87,5\%\\\%m_{H_2}=12,5\%\end{matrix}\right.\)
c) PTHH: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
Theo PTHH: \(n_{KMnO_4}=2n_{O_2}=0,6mol\)
\(\Rightarrow m_{KMnO_4}=0,6\cdot158=94,8\left(g\right)\)
a) CH4 + 2O2 --to--> CO2 +2H2O
2C4H10 + 13O2 --to--> 8CO2 + 10H2O
b) \(\left\{{}\begin{matrix}n_{CH_4}+n_{C_4H_{10}}=\dfrac{6,72}{22,4}=0,3\\\dfrac{n_{CH_4}}{n_{C_4H_{10}}}=\dfrac{1}{2}\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}n_{CH_4}=0,1\\n_{C_4H_{10}}=0,2\end{matrix}\right.\)
PTHH: CH4 + 2O2 --to--> CO2 +2H2O
_____0,1--->0,2--------->0,1
2C4H10 + 13O2 --to--> 8CO2 + 10H2O
__0,2---->1,3------->0,8
=> VO2 = (0,2+1,3).22,4 = 33,6 (l)
=> Vkk = 33,6.5 = 168 (l)
VCO2 = (0,1+0,8).22,4 = 20,16 (l)
Bạn ơi cho mình hỏi là trong PTHH2 vì sao O2 lại là 1,3 mol vậy mình tính ra lại bằng 2,6 mol cơ
\(Đặt:n_{CH_4}=a\left(mol\right),n_{C_2H_4}=b\left(mol\right)\)
\(\Rightarrow a+b=0.15\left(1\right)\)
\(n_{CO_2}=\dfrac{4.48}{22.4}=0.2\left(mol\right)\)
\(CH_4+2O_2\underrightarrow{t^0}CO_2+2H_2O\)
\(C_2H_4+3O_2\underrightarrow{t^0}2CO_2+2H_2O\)
\(\Rightarrow a+2b=0.2\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.1,b=0.05\)
Vì : tỉ lệ thể tích tương ứng với tỉ lệ số mol :
\(\%n_{CH_4}=\dfrac{0.1}{0.15}\cdot100\%=66.67\%\)
\(\%n_{C_2H_4}=100-66.67=33.33\%\)
Chúc em học tốt !!
Đặt \(\left\{{}\begin{matrix}n_{CH_4}=x\left(mol\right)\\n_{C_2H_4}=y\left(mol\right)\end{matrix}\right.\)
\(\Sigma n_{hhkA}=\dfrac{3,36}{22,4}=0,15\\ \rightarrow x+y=0,15\left(1\right)\)
\(PTHH:CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
(mol)........x....->...2x.......x..............2x
\(PTHH:C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
(mol)........y......->...3y...........2y........2y
\(\Sigma n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ \rightarrow x+2y=0,2\)
Giải hpt (1) (2) ta được x=0,1 ; y=0,05
\(\%V_{CH_4}=\dfrac{0,1.22,4}{3,36}.100\%=66,67\%\\ \%V_{C_2H_4}=100\%-66,67\%=33,33\%\)
Đề bài là 8,96 lít hay 9,96 lít em hầy?
Chắc 8,96 chứ 9,96/22,4 = R