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nFe = 16.8/56 = 0.3 (mol)
nO2 = 6.72/22.4 = 0.3 (mol)
2Fe + 3O2 -to-> Fe3O4
0.2___0.3________0.1
mFe dư = ( 0.3 - 0.2 ) * 56 = 5.6 (g)
mFe3O4 = 0.1*232 = 23.2 (g)
a)
3Fe+2O2→Fe3O4
b)
nFe=16,8/56=0,3mol
nO2=6,72/22,4=0,3mol
Ta có: 0,3/3<0,3/2=> O2 dư tính theo Fe
nFe3O4=0,3/3=0,1
mFe3O4=0,1.232=23,2g
nFe = 11.2/56=0.2 (mol)
3Fe + 2O2 -to-> Fe3O4
0.2____2/15____1/15
VO2 = 2/15 * 22.4 = 2.9867 (l)
mFe3O4 = 1/15 * 232 = 15.47 (g)
ta có pthh: 3Fe + 2O2 → Fe3O4
Ta có nFe=\(\dfrac{m}{M}\)=\(\dfrac{11,2}{56}\)=0,2(mol)
nO2=2nFe=2*\(\dfrac{0,2}{3}\)=\(\dfrac{2}{15}\)(mol)
VO2=n*M=16*\(\dfrac{2}{15}\)=2,13(l)
nFe3O4=\(\dfrac{0,2}{2}\)=0,1(mol)
mFe3O4=\(\dfrac{0,1}{168+64}\)=23,2(g)
PTHH: \(2KMnO_4\xrightarrow[]{t^o}K_2MnO_4+MnO_2+O_2\)
\(n_{KMnO_4}=\dfrac{m_{KMnO_4}}{M_{KMnO_4}}=\dfrac{15,8}{158}=0,1\left(mol\right)\)
a. Theo PTHH: \(n_{O_2}=\dfrac{1}{2}n_{KMnO_4}=\dfrac{1}{2}0,1=0,05\left(mol\right)\)
\(\Rightarrow V_{O_2}=n_{O_2}.22,4=0,05.22,4=1,12\left(l\right)\)
b. PTHH: \(3Fe+2O_2\xrightarrow[]{t^o}Fe_3O_4\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
Ta có: \(\dfrac{1}{n_{O_2}}=\dfrac{1}{0,05}\)
\(\dfrac{1}{n_{Fe}}=\dfrac{1}{0,1}\)
\(\Rightarrow\dfrac{1}{n_{O_2}}>\dfrac{1}{n_{Fe}}\)
Vậy Fe dư
Theo PTHH: \(n_{Fe_3O_4}=\dfrac{0,1.1}{3}=\dfrac{1}{30}\left(mol\right)\)
\(\Rightarrow m_{Fe_3O_4}=n_{Fe_3O_4}.M_{Fe_3O_4}=\dfrac{1}{30}.232\approx7,73g\)
\(n_{Fe}=\dfrac{16,8}{56}=0,3mol\)
\(n_{O_2}=\dfrac{5,6}{22,4}=0,25mol\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
\(\dfrac{0,3}{3}\) < \(\dfrac{0,25}{2}\) ( mol )
0,3 0,2 0,1 ( mol )
Chất dư là O2
\(m_{O_2\left(dư\right)}=\left(0,25-0,2\right).32=1,6g\)
\(m_{Fe_3O_4}=0,1.232=23,2g\)
\(n_{Cu}=\dfrac{4}{80}=0.05\left(mol\right)\)
\(n_{Fe_2O_3}=\dfrac{4}{160}=0.025\left(mol\right)\)
\(n_{SO_2}=\dfrac{2.24}{22.4}=0.1\left(mol\right)\)
\(m_O=m_A-m_{Cu}-m_{Fe}-m_O=9.2-0.05\cdot64-0.025\cdot2\cdot56-0.1\cdot32=0\)
\(CT:Cu_xFe_yS_z\)
\(x:y:z=0.05:0.05:0.1=1:1:2\)
\(CT:CuFeS_2\)
a) \(n_{Fe}=\dfrac{3,36}{56}=0,06\left(mol\right)\)
PTHH: 3Fe + 2O2 --to--> Fe3O4
0,06->0,04------->0,02
=> mFe3O4 = 0,02.232 = 4,64 (g)
b) VO2 = 0,04.22,4 = 0,896 (l)
a) 3Fe + 2O2 --to--> Fe3O4
Tỉ lệ Fe : O2 = 3:2
b) Áp dụng ĐLBTKL: mFe + mO2 = mFe3O4
c) mFe + mO2 = mFe3O4
=> mO2 = 23,2 - 16,8 = 6,4(g)
=> \(n_{O_2}=\dfrac{6,4}{32}=0,2\left(mol\right)=>V_{O_2}=0,2.22,4=4,48\left(l\right)\)
d) Do Fe : O2 = 3:2
=> Số phân tử O2 để đốt cháy hết 0,9.1023 nguyên tử Fe
= \(\dfrac{2}{3}.0,9.10^{23}=0,6.10^{23}\)
\(a)3Fe+2O_2\rightarrow Fe_3O_4\)
\(3mol\) \(2mol\) \(1mol\)
\(0,3mol\) \(0,2mol\) \(0,1mol\)
\(b)n_{Fe}=\dfrac{m}{M}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
\(n_{O_2}=\dfrac{V}{22,4}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
\(\text{Ta thấy }O_2\text{ dư,}Fe\text{ phản ứng hết}\)
\(c)m_{Fe_3O_4}=n.M=0,1.232=23,2\left(g\right)\)
\(3Fe+2O2-->Fe3O4\)
\(n_{Fe}=\frac{16,8}{56}=0,3\left(mol\right)\)
\(n_{O2}=\frac{11,2}{22,4}=0,5\left(mol\right)\)
\(\frac{0,3}{3}< \frac{0,5}{2}\Rightarrow O2dư\)
Sau phản ứng gồm O2 dư và Fe3O4
\(n_{O2}=\frac{2}{3}n_{Fe}=0,2\left(mol\right)\)
\(n_{O2}dư=0,5-0,2=0,3\left(mol\right)\)
\(\Rightarrow m_{O2}dư=0,3.32=9,6\left(g\right)\)
\(n_{Fe3O4}=\frac{1}{3}n_{Fe}=0,1\left(mol\right)\)
\(m_{Fe3O4}=0,1.232=23,2\left(g\right)\)