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a, \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=0,2\left(mol\right)\Rightarrow V_{O_2}=0,2.22,4=4,48\left(l\right)\)
\(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,1\left(mol\right)\Rightarrow m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)
c, \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,3}{1}\), ta được H2 dư.
Theo PT: \(n_{Cu}=n_{CuO}=0,2\left(mol\right)\Rightarrow m_{Cu}=0,2.64=12,8\left(g\right)\)
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_{\text{4}}\)
0,15 0,1 0,05
\(m_{Fe_2O_4}=0,05.232=11,6\left(g\right)\\
V_{O_2}=0,1.11,4=2,24\left(l\right)\\
pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
0,2 0,1
\(m_{KMnO_4}=0,2.158=31,6\left(g\right)\)
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
0,15 0,1 0,05
\(m_{Fe_3O_{\text{ 4}}}=0,05.232=11,6\left(g\right)\\ V_{O_2}=0,1.22,4=2,24\left(l\right)\\ pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
0,1 0,05
\(m_{KMnO_4}=0,1.158=15,8\left(g\right)\)
gọi số mol Fe là x
pthh : 3Fe + 2O2 --t---> Fe3O4
x---->\(\dfrac{2}{3}\)x----------> \(\dfrac{x}{3}\)
=> mFe3O4= \(\dfrac{x}{3}\) . 232 = \(\dfrac{232x}{3}\) (G)
=> VO2 = \(\dfrac{2x}{3}\) . 22,4 = \(\dfrac{224x}{15}\) (L)
a. \(n_{Fe_3O_4}=\dfrac{6,96}{232}=0,03\left(mol\right)\)
PTHH : 3Fe + 2O2 -to-> Fe3O4
0,09 0,06 0,03
\(m_{Fe}=0,09.56=5,04\left(g\right)\)
\(V_{O_2}=0,06.22,4=1,344\left(l\right)\)
b. PTHH : 2KCl + 3O2 -> 2KClO3
0,06 0,04
\(m_{KClO_3}=0,04.122,5=4,9\left(g\right)\)
a) \(n_{Fe}=\dfrac{3,36}{56}=0,06\left(mol\right)\)
PTHH: 3Fe + 2O2 --to--> Fe3O4
0,06->0,04------->0,02
=> mFe3O4 = 0,02.232 = 4,64 (g)
b) VO2 = 0,04.22,4 = 0,896 (l)
Bài 3 :
PTHH : \(6Fe+4O_2\left(t^o\right)->2Fe_3O_4\) (1)
\(n_{Fe_3O_4}=\dfrac{m}{M}=\dfrac{2,32}{56.3+16.4}=0,01\left(mol\right)\)
Từ (1) => \(3n_{Fe_3O_4}=n_{Fe}=0,03\left(mol\right)\)
=> \(m_{Fe}=n.M=1,68\left(g\right)\)
Từ (1) => \(2n_{Fe_3O_4}=n_{O_2}=0,02\left(mol\right)\)
=> \(V_{O_2\left(đktc\right)}=n.22,4=0,448\left(l\right)\)
Bài 4 :
PTHH : \(4P+5O_2\left(t^o\right)->2P_2O_5\) (1)
\(n_P=\dfrac{m}{M}=\dfrac{6,2}{31}=0,2\left(mol\right)\)
\(n_{O_2}=\dfrac{V}{22,4}=\dfrac{6,72}{32}=0,21\left(mol\right)\)
Có : \(n_P< n_{O_2}\left(0,2< 0,21\right)\)
-> P hết ; O2 dư
Từ (1) -> \(\dfrac{1}{2}n_P=n_{P_2O_5}=0,1\left(mol\right)\)
=> \(m_{P_2O_5}=n.M=14,2\left(g\right)\)
Bài 3:
\(n_{Fe_3O_4}=\dfrac{2,32}{232}=0,01\left(mol\right)\)
PTHH: 3Fe + 2O2 ---to→ Fe3O4
Mol: 0,03 0,02 0,01
\(m_{Fe}=0,03.56=1,68\left(g\right);V_{O_2}=0,02.22,4=0,448\left(l\right)\)
Sửa đề: "672 ml khí hidro"
PTHH: \(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
\(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Ta có: \(n_{H_2}=\dfrac{0,672}{22,4}=0,03\left(mol\right)\) \(\Rightarrow n_{Fe}=0,02mol\)
\(\Rightarrow n_{O_2}=\dfrac{1}{75}\left(mol\right)\) \(\Rightarrow V_{O_2}=\dfrac{1}{75}\cdot22,4\approx0,3\left(l\right)\)