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Bài 7 :
200ml = 0,2l
\(n_{CuCl2}=2.0,2=0,4\left(mol\right)\)
Pt : \(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl|\)
1 2 1 2
0,4 0,8 0,4 0,8
\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O|\)
1 1 1
0,4 0,4
a) \(n_{CuO}=\dfrac{0,4.1}{1}=0,4\left(mol\right)\)
⇒ \(m_{CuO}=0,4.40=32\left(g\right)\)
b) \(n_{NaCl}=\dfrac{0,4.2}{1}=0,8\left(mol\right)\)
⇒ \(m_{NaCl}=0,8.58,5=46,8\left(g\right)\)
\(m_{ddCuCl2}=1,35.200=270\left(g\right)\)
\(m_{ddspu}=270+100=370\left(g\right)\)
\(C_{NaCl}=\dfrac{46,8.100}{370}=12,65\)0/0
Chúc bạn học tốt
\(n_{NaOH}=\dfrac{200.15\%}{40}=0,75\left(mol\right)\)
\(\left\{{}\begin{matrix}n_{H_2SO_4}=0,0001V\left(mol\right)\\n_{Fe_2\left(SO_4\right)_3}=0,00005V\left(mol\right)\end{matrix}\right.\)
PTHH: 2NaOH + H2SO4 --> Na2SO4 + 2H2O
0,0002V<-0,0001V
6NaOH + Fe2(SO4)3 --> 3Na2SO4 + 2Fe(OH)3
0,0003V<-0,00005V---------------->0,0001V
=> 0,0002V + 0,0003V = 0,75
=> V = 1500 (ml)
nFe(OH)3 = 0,15 (mol)
=> m1 = 0,15.107 = 16,05 (g)
PTHH: 2Fe(OH)3 --to--> Fe2O3 + 3H2O
0,15--------->0,075
=> mFe2O3 = 0,075.160 = 12 (g)
\(n_{AlCl_3}=0.2\cdot1=0.2\left(mol\right)\)
\(n_{NaOH}=0.5V\left(mol\right)\)
\(n_{Al_2O_3}=\dfrac{5.1}{102}=0.05\left(mol\right)\)
\(2Al\left(OH\right)_3\underrightarrow{^{^{t^0}}}Al_2O_3+3H_2O\)
\(0.1...............0.05\)
TH1 : Al(OH)3 không bị hòa tan.
\(AlCl_3+3NaOH\rightarrow Al\left(OH\right)_3+3NaCl\)
\(0.1...........0.3................0.1\)
\(\Leftrightarrow V=\dfrac{0.3}{0.5}=0.6\left(l\right)\)
TH2 : Al(OH)3 bị hòa tan một phần
\(AlCl_3+3NaOH\rightarrow Al\left(OH\right)_3+3NaCl\)
\(0.2...........0.6................0.2\)
\(NaOH+Al\left(OH\right)_3\rightarrow NaAlO_2+2H_2O\)
\(0.5V-0.6...0.5V-0.6\)
\(n_{Al\left(OH\right)_3}=0.2+0.5V-0.6=0.1\left(mol\right)\)
\(\Rightarrow V=1\left(l\right)\)
chất rắn A này là NaCl hay Fe(OH)2
mình nghĩ là Fe(OH)2 nhưng lại đem đun thì ko đúng
\(a,PTHH:3NaOH+FeCl_3\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\\ 2Fe\left(OH\right)_3\rightarrow^{t^o}Fe_2O_3+3H_2O\uparrow\\ b,n_{FeCl_3}=1,5\cdot0,2=0,3\left(mol\right)\\ \Rightarrow n_{NaOH}=3n_{FeCl_3}=0,9\left(mol\right)\\ \Rightarrow V_{dd_{NaOH}}=\dfrac{0,9}{2}=0,45\left(l\right)\)
Theo đề: \(\left\{{}\begin{matrix}X:Fe\left(OH\right)_3\\A:NaCl\\Y:Fe_2O_3\end{matrix}\right.\)
Theo PT: \(n_{NaCl}=3n_{FeCl_3}=0,9\left(mol\right)\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,9}{0,45+0,2}\approx1,4M\)
\(c,\) Theo PT: \(n_{Fe\left(OH\right)_3}=n_{FeCl_3}=0,3\left(mol\right);n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_X=m_{Fe\left(OH\right)_3}=0,3\cdot107=32,1\left(g\right)\\m_Y=m_{Fe_2O_3}=0,15\cdot160=24\left(g\right)\end{matrix}\right.\)
\(n_{CuCl_2}=\dfrac{2,7}{135}=0,02\left(mol\right)\\ a,CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\\ b,n_{Cu\left(OH\right)_2}=n_{CuCl_2}=0,02\left(mol\right)\\ n_{NaCl}=n_{NaOH}=2.0,02=0,04\left(mol\right)\\ b,m_D=m_{Cu\left(OH\right)_2}=98.0,02=1,96\left(g\right)\\ Cu\left(OH\right)_2\rightarrow\left(t^o\right)CuO+H_2O\\ n_{CuO}=n_{Cu\left(OH\right)_2}=0,02\left(mol\right)\\ \Rightarrow m_E=m_{CuO}=0,02.80=1,6\left(g\right)\)
FeCl3+3NaOH-->Fe(OH)3+3NaCl
nFe(OH)3=10,7\107=0,1 mol
2Fe(OH)3-to->Fe2O3+3H2O
0,1-------------------0,05 mol
=>mFe2O3=0,05.160=8 g