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\(n_{CO_2}=\dfrac{4,48}{22,4}=0,2mol\)
\(MgCO_3+2HCl\rightarrow MgCl_2+CO_2+H_2O\)
\(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
\(\Rightarrow\left\{{}\begin{matrix}84\cdot n_{MgCO_3}+100\cdot n_{CaCO_3}=18,4\\n_{MgCO_3}+n_{CaCO_3}=n_{CO_2}=0,2\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}n_{MgCO_3}=0,1mol\\n_{CaCO_3}=0,1mol\end{matrix}\right.\)
\(\%m_{CaCO_3}=\dfrac{0,1\cdot100}{18,4}\cdot100\%=54,35\%\)
\(\%m_{MgCO_3}=100\%-54,35\%=45,65\%\)
\(n_{H2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Pt : \(Fe+2HCl\rightarrow FeCl_2+H_2|\)
1 2 1 1
0,2 0,4 0,2 0,2
\(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O|\)
1 6 2 3
0,2 1,2 0,4
\(n_{Fe}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
⇒ \(m_{Fe}=0,2.56=11,2\left(g\right)\)
\(m_{Fe2O3}=27,2-11,2=16\left(g\right)\)
0/0Fe = \(\dfrac{11,2.100}{27,2}=41,18\)0/0
0/0Fe2O3 = \(\dfrac{16.100}{27,2}=58,82\)0/0
b) Có : \(m_{Fe2O3}=16\left(g\right)\)
\(n_{Fe2O3}=\dfrac{16}{160}=0,1\left(mol\right)\)
\(n_{HCl\left(tổng\right)}=0,4+1,2=1,6\left(mol\right)\)
\(V_{HCl}=\dfrac{1,6}{2}=0,8\left(l\right)\)
c) \(n_{FeCl2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
\(n_{FeCl3}=\dfrac{1,2.2}{6}=0,4\left(mol\right)\)
\(C_{M_{FeCl2}}=\dfrac{0,2}{0,8}=0,25\left(M\right)\)
\(C_{M_{FeCl3}}=\dfrac{0,4}{0,8}=0,5\left(M\right)\)
Chúc bạn học tốt
m dd sau pư = mFe + m dd HCl - mH2 thôi em nhé, Cu không phản ứng nên không cộng thêm vào.
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
a) Theo Pt : \(n_{H2}=n_{Fe}=n_{FeCl2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(\%m_{Fe}=\dfrac{0,1.56}{10}.100\%=56\%\)
\(\%m_{Cu}=100\%-56\%=44\%\)
b) Theo Pt : \(n_{H2}=2n_{HCl}=2.0,1=0,2\left(mol\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{0,2.36,5}{7,3\%}.100\%=100\left(g\right)\)
c) \(m_{ddspu}=10+100-0,1.2=109,8\left(g\right)\)
\(C\%_{FeCl2}=\dfrac{0,1.127}{109,8}.100\%=11,57\%\)
a)
$Fe + 2HCl \to FeCl_2 + H_2$
$FeO + 2HCl \to FeCl_2 + H_2O$
b)
Theo PTHH : $n_{Fe} = n_{H_2} = \dfrac{3,36}{22,4} = 0,15(mol)$
$m_{Fe} = 0,15.56 = 8,4(gam)$
$m_{FeO} = 12 - 8,4 = 3,6(gam)$
$n_{FeO} =0,05(mol)$
Theo PTHH : $n_{HCl} = 2n_{Fe} + 2n_{FeO} = 0,4(mol)$
$V_{dd\ HCl} = \dfrac{0,4}{2} = 0,2(lít)$
c) $Fe + CuSO_4 \to FeSO_4 + Cu$
$n_{Cu} = n_{Fe} = 0,15(mol) \Rightarrow m_{chất\ rắn} = m_{FeO} + m_{Cu}$
$= 3,6 + 0,15.64 = 13,2(gam)$
Vì Cu không tác dụng với HCl, nên chỉ có phản ứng của Fe.
PTHH: Fe+2HCl\(\rightarrow\)FeCl2+H2
a) nH2=0,15(mol)
Theo pt: nFe=nH2=0,15 (mol)
\(\Rightarrow\)mFe=8,4(g)
b) mCu=10-8,4=1,6(g)
c) Theo pt: nHCl=nH2=0,15(mol)
\(\Rightarrow\)VHCl=0,3(l)
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\) (1)
\(MgO+2HCl\rightarrow MgCl_2+H_2O\) (2)
a) Ta có: \(n_{H_2}=\dfrac{22,4}{22,4}=1\left(mol\right)=n_{Mg}\) \(\Rightarrow m_{Mg}=1\cdot24=24\left(g\right)\)
\(\Rightarrow\%m_{Mg}=\dfrac{24}{32}\cdot100\%=75\%\) \(\Rightarrow\%m_{MgO}=25\%\)
b) Theo 2 PTHH: \(\left\{{}\begin{matrix}n_{HCl\left(1\right)}=2n_{Mg}=2mol\\n_{HCl\left(2\right)}=2n_{MgO}=2\cdot\dfrac{32-24}{40}=0,4mol\end{matrix}\right.\)
\(\Rightarrow\Sigma n_{HCl}=2,4mol\) \(\Rightarrow m_{ddHCl}=\dfrac{2,4\cdot36,5}{7,3\%}=1200\left(g\right)\)
c) Theo PTHH: \(\Sigma n_{MgCl_2}=\dfrac{1}{2}\Sigma n_{HCl}=1,2mol\)
\(\Rightarrow\Sigma m_{MgCl_2}=1,2\cdot95=114\left(g\right)\)
Mặt khác: \(m_{H_2}=1\cdot2=2\left(g\right)\)
\(\Rightarrow m_{dd}=m_{hh}+m_{ddHCl}-m_{H_2}=1230\left(g\right)\)
\(\Rightarrow C\%_{MgCl_2}=\dfrac{114}{1230}\cdot100\%\approx9,27\%\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
a 2a a a
\(FeS+2HCl\rightarrow FeCl_2+H_2S\uparrow\)
b 2b b b
\(n_{HCl}=\dfrac{400\times7.3}{100\times36.5}=0.8mol\)
\(n_X=\dfrac{4.48}{22.4}=0.2mol\)
\(M_X=2\times9=18\Leftrightarrow\dfrac{2a+34b}{a+b}=18\)
Ta có: \(\left\{{}\begin{matrix}a+b=0.2\\\dfrac{2a+34b}{a+b}=18\end{matrix}\right.\)\(\Leftrightarrow\left\{{}\begin{matrix}a+b=0.2\\2a+34b=3.6\end{matrix}\right.\)\(\Leftrightarrow\left\{{}\begin{matrix}a=0.1\\b=0.1\end{matrix}\right.\)
a. \(\%V_{H_2}=\dfrac{0.1\times22.4\times100}{4.48}=50\%\)
\(\%V_{H_2S}=100-50=50\%\)
b. \(a=0.1\times56+0.1\times88=14.4g\)
\(\%m_{Fe}=\dfrac{0.1\times56}{14.4}\times100=38.8\%\)
\(\%m_{FeS}=100-38.8=61.2\%\)
c. m dung dịch sau phản ứng\(=14.4+400-0.1\times2-0.1\times34=410.8g\)
nHCl phản ứng\(=2\times0.1+2\times0.1=0.4mol\)
nHCl dư = 0.8 - 0.4 = 0.4 mol
\(C\%_{HCldu}=\dfrac{0.4\times36.5\times100}{410.8}=3.55\%\)
\(C\%_{FeCl_2}=\dfrac{0.2\times127\times100}{410.8}=6.18\%\)