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a,\(n_{FeCl_2}=0,25.0,2=0,05\left(mol\right);n_{NaOH}=0,25.0,5=0,125\left(mol\right)\)
PTHH: FeCl2 + 2NaOH → Fe(OH)2 + 2NaCl
Mol: 0,05 0,05 0,1
Tỉ lệ:\(\dfrac{0,05}{1}< \dfrac{0.125}{2}\) ⇒ FeCl2 pứ hết;NaOH dư
PTHH: \(Fe\left(OH\right)_2\underrightarrow{t^o}FeO+H_2O\)
Mol: 0,1 0,1
⇒ m=mFeO = 0,1.72 = 7,2 (g)
b,\(C_{MNaOHdư}=\dfrac{0,125-0,1}{0,5}=0,05M\)
\(C_{MNaCl}=\dfrac{0,1}{0,5}=0,2M\)
a)
$MgCl_2 + 2NaOH \to Mg(OH)_2 + 2NaCl$
$Mg(OH)_2 \xrightarrow{t^o} MgO + H_2O$
b)
$n_{Mg(OH)_2} = n_{MgCl_2} = \dfrac{38}{95} = 0,4(mol)$
$m_{Mg(OH)_2} = 0,4.58 = 23,2(gam)$
c)
$n_{MgO} = n_{MgCl_2} = 0,4(mol)$
$m_{MgO} = 0,4.40 = 16(gam)$
\(a,PTHH:3NaOH+FeCl_3\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\\ 2Fe\left(OH\right)_3\rightarrow^{t^o}Fe_2O_3+3H_2O\uparrow\\ b,n_{FeCl_3}=1,5\cdot0,2=0,3\left(mol\right)\\ \Rightarrow n_{NaOH}=3n_{FeCl_3}=0,9\left(mol\right)\\ \Rightarrow V_{dd_{NaOH}}=\dfrac{0,9}{2}=0,45\left(l\right)\)
Theo đề: \(\left\{{}\begin{matrix}X:Fe\left(OH\right)_3\\A:NaCl\\Y:Fe_2O_3\end{matrix}\right.\)
Theo PT: \(n_{NaCl}=3n_{FeCl_3}=0,9\left(mol\right)\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,9}{0,45+0,2}\approx1,4M\)
\(c,\) Theo PT: \(n_{Fe\left(OH\right)_3}=n_{FeCl_3}=0,3\left(mol\right);n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_X=m_{Fe\left(OH\right)_3}=0,3\cdot107=32,1\left(g\right)\\m_Y=m_{Fe_2O_3}=0,15\cdot160=24\left(g\right)\end{matrix}\right.\)
a, PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_{2\downarrow}\)
\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)
b, Ta có: \(n_{Mg}=\dfrac{9,6}{24}=0,4\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Mg}=0,8\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,8}{0,2}=4\left(M\right)\)
c, Theo PT: \(n_{MgO}=n_{Mg}=0,4\left(mol\right)\)
\(\Rightarrow m_{MgO}=0,4.40=16\left(g\right)\)
câu 1
cho 2dd trên td vs NaOH dư
có tủa => CuSO4
CuSO4 + 2NaOH => Na2SO4 + Cu(OH)2
ko hiện tượng => Na2SO4
MgCl2 + 2NaOH -> 2NaCl + Mg(OH)2 (1)
Mg(OH)2 -> MgO + H2O (2)
nMgCl2=0,2.0,15=0,03(mol)
nNaOH=0,2.0,2=0,04(mol)
Vì \(\dfrac{0,04}{2}< 0,03\) nên MgCl2 dư 0,1 mol
Theo PTHH 1 ta có:
nMg(OH)2=\(\dfrac{1}{2}\)nNaOH=0,02(mol)
nNaCl=nNaOH=0,04(mol)
Theo PTHH 2 ta có:
nMgO=nMg(OH)2=0,02(mol)
mMgO=40.0,02=0,8(g)
CM dd MgCl2=\(\dfrac{0,01}{0,4}=0,025M\)
CM dd NaCl=\(\dfrac{0,04}{0,4}=0,01M\)
nNaOH=8/40=0,2mol
pt : 2NaOH + MgCl2 ------> Mg(OH)2 + 2NaCl
npứ:0,2------->0,1------------->0,1
pt : Mg(OH)2 ---to--> MgO + H2O
npứ:0,1----------------->0,1
mMgO = 0,1.40=4g
CM (MgCl2)=0,1/0,2=0,5M