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\(n_{H_2SO_4}=\dfrac{200.7,35\%}{98}=0,15\left(mol\right)\)
PTHH: 2NaOH + H2SO4 --> Na2SO4 + 2H2O
0,3<----0,15-------->0,15
=> mNaOH = 0,3.40 = 12 (g)
\(m_{dd.NaOH}=\dfrac{12.100}{8}=150\left(g\right)\)
mdd sau pư = 200 + 150 = 350 (g)
mNa2SO4 = 0,15.142 = 21,3 (g)
=> \(C\%_{dd.Na_2SO_4}=\dfrac{21,3}{350}.100\%=6,086\%\)
nCuSO4=0,01 mol
Fe+CuSO4=> FeSO4+Cu
0,01 mol =>0,01 mol
mCu=0,01.64=0,64gam
FeSO4+2NaOH=>Fe(OH)2 +Na2SO4
0,01 mol=>0,02 mol
Vdd NaOH=0,02/1=0,02 lit
a, \(Na_2O+H_2SO_4\rightarrow Na_2SO_4+H_2O\)
b, Số mol \(H_2SO_4\) là: \(n_1=V.C_M=0,5.0,5=0,25\) (mol)
Số mol \(Na_2SO_4\) là \(n_2=\dfrac{28,4}{142}=0,2\) (mol)
Do \(n_2< n_1\) nên \(H_2SO_4\) còn dư
Suy ra số mol \(Na_2O\) tham gia phản ứng là: \(n=n_2=0,2\) (mol)
Khối lượng là: \(m_{Na_2O}=0,2.62=12,4g\)
\(a) Fe + 2HCl \to FeCl_2 + H_2\\ n_{H_2} = n_{Fe} = \dfrac{16,8}{56} = 0,3(mol)\\ V_{H_2} = 0,3.22,4 = 6,72(lít)\\ b) n_{HCl} = 2n_{Fe} = 0,6(mol)\ \Rightarrow m_{HCl} = 0,6.36,5 = 21,9(gam)\)
(Thiếu C% của HCl nên không tìm được khối lượng dung dịch )
\(c) n_{FeCl_2} = n_{Fe} = 0,3(mol)\\ m_{FeCl_2} = 0,3.127 = 38,1(gam)\)
a) \(PT:CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\uparrow\)
\(HCl+NaOH\rightarrow NaOH+H_2O\)
b) \(m_{HCl}=\frac{200.10,95\%}{100\%}=21,9\left(g\right)\)
\(n_{HCl}=\frac{21,9}{36,5}=0,6\left(mol\right)\)
c) \(n_{NaOH}=2.0,05=0,1\left(mol\right)\Rightarrow n_{HCl\left(pưNaOH\right)}=0,1\left(mol\right)\)
\(\Rightarrow n_{HCl\left(pưCaCO_3\right)}=0,6-0,1=0,5\left(mol\right)\)
d) \(n_{CaCO_3}=\frac{1}{2}n_{HCl\left(pưCaCO_3\right)}=0,5.\frac{1}{2}=0,25\left(mol\right)\)
\(m_{CaCO_3}=0,25.100=25\left(g\right)\)
e) \(n_{CO_2}=n_{CaCO_3}=0,25\left(mol\right)\)
\(V_{CO_2}=0,25.22,4=5,6\left(l\right)\)
f) \(n_{CaCl_2}=n_{CaCO_3}=0,25\left(mol\right)\)
\(m_{ddA}=25+200-0,25.44=214\left(g\right)\)
\(C\%_{ddCaCl_2}=\frac{0,25.111}{214}.100\%=12,97\%\)
\(C\%_{ddHCldư}=\frac{0,1.36,5}{214}.100\%=1,71\%\)
\(n_{Na}=\dfrac{6,9}{23}=0,3\left(mol\right)\\ 2Na+2H_2O\rightarrow2NaOH+H_2\\ n_{H_2}=\dfrac{0,3}{2}=0,15\left(mol\right)\\ a,V_{H_2\left(đktc\right)}=0,15.22,4=3,36\left(l\right)\\ b,m_{ddsaup.ứ}=m_{Na}+m_{H_2O}-m_{H_2}=6,9+100-0,15.2=106,6\left(g\right)\)
Cu(OH)2 + H2SO4 \(\rightarrow\) CuSO4 + 2H2O
nCu(OH)2 = \(\dfrac{29,4}{98}=0,3mol\)
Theo pt: nH2SO4 = nCu(OH)2 = 0,3 mol
=> mH2SO4 = 0,3.98 = 29,4g
VH2SO4 = 0,3:1 = 0,3l
PTHH: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
Ta có: \(n_{CuO}=\dfrac{29,4}{80}=0,3675\left(mol\right)=n_{CuSO_4}=n_{H_2SO_4}\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CuSO_4}=0,3675\cdot160=58,8\left(g\right)\\m_{H_2SO_4}=0,3675\cdot98=36,015\left(g\right)\\V_{H_2SO_4}=\dfrac{0,3675}{1}=0,3675\left(l\right)=367,5\left(ml\right)\end{matrix}\right.\)
\(n_{H_2SO_4}=\dfrac{4,9}{98}=0,05\left(mol\right)\\ H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\\ a,n_{NaOH}=n_{H_2O}2.0,05=0,1\left(mol\right)\\ \Rightarrow m_{NaOH}=0,1.40=4\left(g\right)\\ b,C1:n_{Na_2SO_4}=n_{H_2SO_4}=0,05\left(mol\right)\\ m_{sp}=m_{Na_2SO_4}+m_{H_2O}=0,05.142+18.0,1=8,9\left(g\right)\\ C2:m_{sp}=m_{H_2SO_4}+m_{NaOH}=4,9+4=8,9\left(g\right)\)