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Gọi x, y lần lượt là sô mol của Fe và Mg
Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH:
Fe + H2SO4 ---> FeSO4 + H2 (1)
Mg + H2SO4 ---> MgSO4 + H2 (2)
a. Theo PT(1): \(n_{H_2}=n_{Fe}=x\left(mol\right)\)
Theo PT(2): \(n_{H_2}=n_{Mg}=y\left(mol\right)\)
\(\Rightarrow x+y=0,3\) (*)
Theo đề, ta có: 56x + 24y = 10.4 (**)
Từ (*) và (**), ta có HPT:
\(\left\{{}\begin{matrix}x+y=0,3\\56x+24y=10,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)
\(\Rightarrow m_{Fe}=0,1.56=5,6\left(g\right);m_{Mg}=0,2.24=4,8\left(g\right)\)
b. Ta có: \(n_{hh}=0,1+0,2=0,3\left(mol\right)\)
Theo PT(1,2): \(n_{H_2SO_4}=n_{hh}=0,3\left(mol\right)\)
Đổi 200ml = 0,2 lít
\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,3}{0,2}=1,5M\)
B1:
Ba(OH)2 + 2HCl -> BaCl2 + 2H2O
Theo bài ra ta có:
nBa(OH)2 bđ = 0,2 . 1 = 0,2 mol
nHCl bđ = 0,3 . 2 = 0,6 mol
Theo pthh ta có:
nBa(OH)2 pt= 1 mol
nHCl pt = 2 mol
Ta có tỉ lệ:
\(\dfrac{nBa\left(OH\right)_2bđ}{nBa\left(OH\right)_2pt}\)=\(\dfrac{0,2}{1}\)= 0,2 < \(\dfrac{nHCl_{bđ}}{nHCl_{pt}}\)= \(\dfrac{0,6}{2}\)= 0,3
=> Sau pư Ba(OH)2 tgpư hết ; HCl còn dư
dd thu đc sau pư: BaCl2 và HCl dư
Theo pthh và bài ta có:
nBaCl2 = nBa(OH)2 = 0,2 mol
V dd sau pư = 0,2 + 0,3 = 0,5 l
=>CM dd BaCl2 = 0,2/0,5 = 0,4 M
nHCl tgpư = nBa(OH)2 = 0,2 mol
=> nHCl dư = 0,6 - 0,2 = 0,4 mol
Vdd HCl dư = 0,4 / 0,5 = 0,8M
Vậy...
a) 2Al (0,2) + 3H2SO4 (0,3) -----> Al2(SO4)3 + 3H2 (0,3)
b) - nH2 = 0,3 mol
- Theo PTHH: nAl = 0,2 mol
=> mAl = 5,4 gam
=> mCu = 4,6 gam
==>mhh=5,4+4,6=10 g
b Theo PTHH: nH2SO4 = 0,3 mol
=> mH2SO4 = 29,4 gam
=> mdd H2SO4 = 29,4.100\20=147gam
\(2Al+3H_2SO_4-->Al_2\left(SO_4\right)_3+3H_2\left(1\right)\)
0,2______0,3_____________0,1________0,3
\(n_{H_2}=\frac{6,72}{22,4}=0,3\left(mol\right)\)
a) => \(m=0,2.27+10=15,4\left(g\right)\)
b) \(m_{d^2H_2SO_4}=\frac{0,3.98.100}{20}=147\left(g\right)\)
c) \(Ba+2H_2O-->Ba\left(OH\right)_2+H_2\left(2\right)\)
0.35__________________0,35
\(n_{Ba}=\frac{47,95}{137}=0,35\left(mol\right)\)
\(3Ba\left(OH\right)_2+Al_2\left(SO_4\right)_3-->3BaSO_4\downarrow+2Al\left(OH\right)_3\downarrow\)
0,3___________0,1_______________0,3 _______0,2
\(2Al\left(OH\right)_3+Ba\left(OH\right)_2-->Ba\left(AlO_2\right)_2+4H_2O\left(3\right)\)
0,1__________0,05__________0,05
\(m_{d^2sau}=0,2.27+147-0,3.2+47,95-0,3.233-0,2.78=137,55\left(g\right)\)
\(C\%_{Ba\left(AlO_2\right)_2}=\frac{0,05.255}{137,55}.100=9,27\%\)
a, Gọi \(\left\{{}\begin{matrix}n_{C_2H_5OH}=a\left(mol\right)\\n_{CH_3COOH}=b\left(mol\right)\end{matrix}\right.\)
\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH:
2C2H5OH + 2Na ---> 2C2H5ONa + H2
a---------------------------------------->0,5a
2CH3COOH + 2Na ---> 2CH3COONa + H2
b------------------------------------------------>0,5b
=> hệ pt \(\left\{{}\begin{matrix}46a+60b=48,8\\0,5a+0,5b=0,5\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,8\left(mol\right)\\b=0,2\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{C_2H_5OH}=0,8.46=36,8\left(g\right)\\m_{CH_3COOH}=0,2.60=12\left(g\right)\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}\%m_{C_2H_5OH}=\dfrac{36,8}{48,8}.100\%=75,41\%\\\%m_{CH_3COOH}=100\%-75,41\%=24,59\%\end{matrix}\right.\)
b, PTHH:
\(C_2H_5OH+CH_3COOH\xrightarrow[t^o]{H_2SO_4đặc}CH_3COOC_2H_5+H_2O\)
LTL: 0,8 > 0,2 => Rượu dư
\(n_{CH_3COOC_2H_5\left(tt\right)}=0,2.85\%=0,17\left(mol\right)\\ m_{este}=0,17.88=14,96\left(g\right)\)
a.Gọi \(\left\{{}\begin{matrix}n_{C_2H_5OH}=x\\n_{CH_3COOH}=y\end{matrix}\right.\)
\(n_{H_2}=\dfrac{11,2}{22,4}=0,5mol\)
\(2C_2H_5OH+2Na\rightarrow2C_2H_5ONa+H_2\)
x 1/2 x ( mol )
\(2CH_3COOH+Na\rightarrow2CH_3COONa+H_2\)
y 1/2 y ( mol )
Ta có:
\(\left\{{}\begin{matrix}46x+60y=48,8\\\dfrac{1}{2}x+\dfrac{1}{2}y=0,5\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,8\\y=0,2\end{matrix}\right.\)
\(\rightarrow m_{C_2H_5OH}=0,8.46=36,8g\)
\(\rightarrow\left\{{}\begin{matrix}\%m_{C_2H_5OH}=\dfrac{36,8}{48,8}.100=75,4\%\\\%m_{CH_3COOH}=100\%-75,4\%=24,6\%\end{matrix}\right.\)
b.\(C_2H_5OH+CH_3COOH\rightarrow\left(H_2SO_4\left(đ\right),t^o\right)CH_3COOC_2H_5+H_2O\)
0,8 < 0,2 ( mol )
0,2 0,2 ( mol )
\(m_{CH_3COOC_2H_5}=0,2.88.85\%=14,96g\)
PTHH: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
a_______a_______a_____a (mol)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
2b______3b__________b_____3b (mol)
Ta lập HPT: \(\left\{{}\begin{matrix}56a+27\cdot2b=11\\a+3b=0,2\cdot2=0,4\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,1\cdot56}{11}\cdot100\%\approx50,91\%\\\%m_{Al}=49,09\%\end{matrix}\right.\)
Theo các PTHH: \(\left\{{}\begin{matrix}n_{H_2}=0,4\left(mol\right)\\n_{FeSO_4}=0,1\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,4\cdot22,4=8,96\left(l\right)\\C_{M_{FeSO_4}}=\dfrac{0,1}{0,2}=0,5\left(M\right)\\C_{M_{Al_2\left(SO_4\right)_3}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\end{matrix}\right.\)
a) nH2SO4=0,4(mol)
Đặt: nFe=x(mol); nAl=y(mol) (x,y>0)
PTHH: Fe + H2SO4 -> FeSO4 + H2
x________x______x______x(mol)
2Al + 3 H2SO4 -> Al2(SO4)3 + 3 H2
y____1,5y_______0,5y_______1,5y(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}56x+27y=11\\x+1,5y=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)
=> mFe=0,1.56=5,6(g)
=>%mFe=(5,6/11).100=50,909%
=>%mAl= 49,091%
b) V(H2,đktc)=0,4.22,4=8,96(l)
c) nAl2(SO4)3= 0,5y=0,5.0,2=0,1(mol)
nFeSO4=x=0,1(mol)
Vddsau=VddH2SO4=0,2(l)
=>CMddAl2(SO4)3= 0,1/0,2=0,5(M)
CMddFeSO4=0,1/0,2=0,5(M)
nH2 = \(\frac{1,68}{22,4}\) = 0,075 (mol)
Mg + 2HCl \(\rightarrow\) MgCl2 + H2\(\uparrow\) (1)
0,075 <--------0,075 <--0,075 (mol)
MgO + 2HCl \(\rightarrow\) MgCl2 + H2O (2)
%mMg= \(\frac{0,075.24}{5,8}\) . 100% = 31,03 %
%m MgO = 68,97%
nMgO = \(\frac{5,8-0,075.24}{40}\) = 0,1 (mol)
Theo pt(2) nMgCl2 = nMgO= 0,1 (mol)
mdd sau pư = 5,8 + 194,35 - 0,075.2 = 200 (g)
C%(MgCl2) = \(\frac{95\left(0,075+0,1\right)}{200}\) . 100% = 8,3125%