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\(n_{CuO}=\dfrac{1.6}{80}=0.02\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{100\cdot20\%}{98}=\dfrac{10}{49}\left(mol\right)\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
\(TC:\dfrac{0.02}{1}< \dfrac{10}{49}\Rightarrow H_2SO_4dư\)
\(m_{dd}=1.6+100=101.6\left(g\right)\)
\(C\%_{CuSO_4}=\dfrac{0.02\cdot160}{101.6}\cdot100\%=3.15\%\)
\(C\%_{H_2SO_4\left(dư\right)}=\dfrac{\left(\dfrac{10}{49}-0.02\right)\cdot98}{101.6}\cdot100\%=17.7\%\)
\(n_{FeCl_3}=\dfrac{48,75}{162,5}=0,3(mol)\\ 3NaOH+FeCl_3\to Fe(OH)_3\downarrow+3NaCl\\ \Rightarrow n_{Fe(OH)_3}=0,3(mol);n_{NaOH}=n_{NaCl}=0,9(mol)\\ a,m_{Fe(OH)_3}=0,3.107=32,1(g)\\ b,m_{dd_{NaOH}}=\dfrac{0,9.40}{10\%}=360(g)\\ c,C\%_{NaCl}=\dfrac{0,9.58,5}{360+48,75-32,1}.100\%=13,98\%\\ \)
\(d,2Fe(OH)_3+3H_2SO_4\to Fe_2(SO_4)_3+6H_2O\\ \Rightarrow n_{H_2SO_4}=0,45(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,45.98}{20\%}=220,5(g)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{220,5}{1,14}=193,42(ml)\)
\(n_{CuO}=\dfrac{1,6}{80}=0,02\left(mol\right)\)
\(m_{H_2SO_4}=100.20\%=20\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{20}{98}=\dfrac{10}{49}\left(mol\right)\)
PTHH: CuO + H2SO4 → CuSO4 + H2O
Mol: 0,02 0,02 0,02
Ta có: \(\dfrac{0,02}{1}< \dfrac{\dfrac{10}{49}}{1}\) ⇒ CuO hết, H2SO4 dư
mdd sau pứ = 1,6 + 100 = 101,6 (g)
\(C\%_{ddCuSO_4}=\dfrac{0,02.160.100\%}{101,6}=3,15\%\)
\(C\%_{ddH_2SO_4}=\dfrac{\left(\dfrac{10}{49}-0,02\right).98.100\%}{101,6}=17,76\%\)
a) PTHH: CuO + H2SO4 ---> CuSO4 + H2O
b)
n Cu = 1,6 / 80 = 0,02 mol
m H2SO4 = 20 . 100 / 100 = 20 g
=> n H2SO4 = 20 / 98 = 0,204 mol
TPT:
1 mol : 1 mol
0,02 mol : 0,204 mol
=> Tỉ lệ: 0,02/1 < 0,204/1
=> H2SO4 dư, tính toán theo CuO
m dd sau p/ư = m dd H2SO4 + m CuO = 100 + 1,6 = 101,6 g
TPT: n CuSO4 = n CuO = 0,02 mol
=> m CuSO4 = 0,02 . 160 = 3,2 g
=> C% CuSO4 = 3,2 / 101,6 . 100% = 3,15%
n H2SO4 dư = 0,204 - 0,02 = 0,182 mol
=> m H2SO4 dư = 0,182 . 98 =17,836 g
=> C% H2SO4 = 17,836 / 101,6 . 100% = 17,83%
\(n_{CuO}=\dfrac{3,2}{80}=0,04\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{100.20\%}{98}=0,204\left(mol\right)\)
PTHH:
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
0,04 0,04 0,04
\(\dfrac{0,04}{1}< \dfrac{0,204}{1}\) --> H2SO4 dư
\(C\%_{CuSO_4}=\dfrac{0,04.160}{3,2+100}.100\%=6,2\%\)
\(C\%_{H_2SO_4\left(dư\right)}=\dfrac{0,2.98}{3,2+100}.100\%=19\%\)
\(n_{Fe_2O_3}=\dfrac{20}{160}=0,125\left(mol\right)\)
PTHH:
\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
0,125 0,375 0,125 0,375
\(m_{ddH_2SO_4}=\dfrac{0,375.98.100}{25}=147\left(g\right)\)
\(C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0,125.406}{20+147}\approx30,39\%\)
\(n_{H_2SO_4}=1.0,2=0,2(mol)\\ H_2SO_4+BaCl_2\to BaSO_4\downarrow+2HCl\\ \Rightarrow n_{BaSO_4}=n_{BaCl_2}=0,2(mol)\\ a,m_{BaSO_4}=0,2.233=46,6(g)\\ b,V_{dd_{BaCl_2}}=\dfrac{0,2}{1,5}\approx 0,13(l)\\ c,n_{HCl}=0,4(mol)\\ \Rightarrow C_{M_{HCl}}=\dfrac{0,4}{0,2+0,13}\approx 1,21M\)
\(d,\) Dd sau p/ứ là HCl nên làm quỳ tím hóa đỏ
\(n_{H_2SO_4}=0,2.1=0,2\left(mol\right)\\ H_2SO_4+BaCl_2\rightarrow BaSO_4+2HCl\\ n_{BaCl_2}=n_{BaSO_4}=n_{H_2SO_4}=0,2\left(mol\right)\\ n_{HCl}=2.0,2=0,4\left(mol\right)\\ a,m_{\downarrow}=m_{BaSO_4}=0,2.233=46,6\left(g\right)\\ b,V_{\text{dd}BaCl_2}=\dfrac{0,2}{1,5}=\dfrac{2}{15}\left(l\right)\\ c,C_{M\text{dd}HCl}=\dfrac{0,4}{\dfrac{2}{15}+0,2}=1,2\left(M\right)\\ d,V\text{ì}.c\text{ó}.\text{dd}.HCl\Rightarrow Qu\text{ỳ}.ho\text{á}.\text{đ}\text{ỏ}\)
CuO+H2SO4->CuSO4+H2O
0,02----------------0,02 mol
n CuO=1,6\80=0,02 mol
=>m CuSO4=0,02.160=3,2g
=>thiếu dữ kiện
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