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a,
Fe2O3+ 3H2SO4 \(\rightarrow\) Fe2(SO4)3+ 3H2O
Fe2(SO4)3+ 3BaCl2 \(\rightarrow\)3BaSO4+ 2FeCl3
b,
nBaSO4= \(\frac{34,95}{233}\)= 0,15 mol
\(\rightarrow\) nFe2O3= nFe2(SO4)3= \(\frac{0,15}{3}\)= 0,05 mol
nH2SO4= 0,05.3= 0,15 mol
mFe2O3= 0,05.160= 8g
m dd H2SO4=\(\frac{\text{0,15.98.100}}{19,6}\)= 75g
PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
a+b) Ta có: \(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)=n_{H_2SO_4}=n_{ZnSO_4}\)
\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,3}{0,2}=1,5\left(M\right)=C_{M_{ZnSO_4}}\)
c) Theo PTHH: \(n_{H_2}=n_{Zn}=0,3mol\) \(\Rightarrow V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\)
d) Theo PTHH: \(n_{Fe}=\dfrac{2}{3}n_{H_2}=0,2mol\)
\(\Rightarrow m_{Fe}=0,2\cdot56=11,2\left(g\right)\)
n\(_{CO}\)=6,72/22,4=0,3mol
PTPU
\(Fe_2O_3+3CO->2Fe+3CO_2\)
0,1.............0,3...........0,2............0,3(mol)
\(m_{Ca\left(OH\right)_2}=\dfrac{7,4.200}{100}=14,8g\)
\(n_{Ca\left(OH\right)_2}\)=14,8/74=0,2mol
n\(_{CO_2}\)=0,3mol
PTPU
\(Ca\left(OH\right)_2+CO_2->CaCO_3+H_2O\)
x.....................x....................x...............x(mol)
\(Ca\left(OH\right)_2+2CO_2->Ca\left(HCO_3\right)_2\)
y........................2y....................y(mol)
n\(_{Ca\left(OH\right)_2}\)=x+y=0,2mol
n\(_{CO_2}\)=x+2y=0,3mol
=>x=0,1mol;y=0,1mol
n\(_{CaCO_3}\)=0,1mol
m\(_{CaCO_3}\)=0,1.100=10g
n\(_{Ca\left(HCO_3\right)_2}\)=0,1mol
m\(_{Ca\left(HCO_3\right)_2}\)=0,1.162=16,2g
Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
\(PTHH:Fe+2HCl--->FeCl_2+H_2\)
a. Theo PT: \(n_{FeCl_2}=n_{Fe}=0,1\left(mol\right)\)
\(\Rightarrow m_{FeCl_2}=0,1.127=12,7\left(g\right)\)
b. Theo PT: \(n_{H_2}=n_{Fe}=0,1\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,1.22,4=2,24\left(lít\right)\)
\(m_{giảm}=m_{Ca\left(OH\right)_2}-m_{H_2O}=6,72\left(g\right)\\ \rightarrow n_{giảm}=\dfrac{6,72}{74-18}=0,12\left(mol\right)\)
PTHH: Ca(OH)2 + CO2 ---> CaCO3 + H2O
Theo pthh: \(n_{giảm}=n_{CO_2}=0,12\left(mol\right)\)
PTHH: FexOy + yCO --to--> xFe + yCO2
Bảo toàn O: \(n_{CO}=n_{CO_2}=n_{O\left(oxit\right)}=0,12\left(mol\right)\)
\(\rightarrow n_{Fe}=\dfrac{6,96-0,12.16}{56}=0,09\left(mol\right)\)
CTHH: FexOy
=> x : y = 0,09 : 0,12 = 3 : 4
=> Oxit đó là Fe3O4
\(\left\{{}\begin{matrix}n_{AgNO_3}=0,1.1,2=0,12\left(mol\right)\\n_{Cu\left(NO_3\right)_2}=0,1.0,6=0,06\left(mol\right)\end{matrix}\right.\)
PTHH:
Fe + 2AgNO3 ---> Fe(NO3)2 + 2Ag
0,06 0,12 0,12
Fe + Cu(NO3)2 ---> Fe(NO3)2 + Cu
0,03 0,03
\(m=0,12.108+0,03.64=14,88\left(g\right)\)
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