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\(a/ CuO+2HCl \to CuCl_2+H_2O\\ b/\\ n_{CuO}=0,125(mol)\\ \to n_{HCl}=0,125.2=0,25(mol)\\ m_{HCl}=0,25.36,5=9,125(g)\\ c/\\ n_{CuO}=n_{CuCl_2}=0,125(mol)\\ CM_{CuCl_2}=\frac{0,125}{0,5}=0,25M\)
a) \(CuO+2HCl\rightarrow CuCl2+H2O\)
b) Ta có: \(n_{CuO}=\dfrac{10}{80}=0,8\left(mol\right)\)
Theo PT: \(n_{HCl}=2nCuO=1,6\left(mol\right)\)
\(\Rightarrow m_{HCl}=1,6.36,5=58,4\left(g\right)\)
c) \(n_{CuCl2}=n_{CuO}=0,8\left(mol\right)\)
\(V_{dd}=\)không đổi \(=500ml=0,5l\)
\(\Rightarrow C_{M\left(CuCl2\right)}=\dfrac{0,8}{0,5}=1,6\left(M\right)\)
nCaCO3=8,4:(40+12+16.3)=0,084 mol
nH2SO4= 0,5.1=0,5 mol
PTHH: H2SO4+ CaCO3 --> CaSO4↓ + CO2 +H2O
theo đề: 0,5 mol: 0,084 mol
=> H2SO4 de theo CaCO3
phản ứng : 0,084mol<----0,084 mol---> 0,084mol
=> CM=\(\frac{0,084}{0,5}=0,168M\)
PTHH: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)
Ta có: \(n_{CuO}=\dfrac{10}{80}=0,125\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,25\left(mol\right)\\n_{CuCl_2}=0,125\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{HCl}=0,25\cdot36,5=9,125\left(g\right)\\C_{M_{CuCl_2}}=\dfrac{0,125}{0,5}=0,25\left(M\right)\end{matrix}\right.\)
\(n_{SO_3}=\dfrac{8}{80}=0.1\left(mol\right)\)
\(SO_3+H_2O\rightarrow H_2SO_4\)
\(0.1......................0.1\)
\(C_{M_{H_2SO_4}}=\dfrac{0.1}{0.5}=0.2\left(M\right)\)
\(n_{CuO}=\dfrac{10}{80}=0.125\left(mol\right)\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
\(0.1...........0.1\)
\(m_{CuO\left(dư\right)}=\left(0.125-0.1\right)\cdot80=2\left(g\right)\)
Ta có: \(n_{MgO}=\dfrac{4}{40}=0,1\left(mol\right)\)
\(n_{HCl}=4.100:1000=0,4\left(mol\right)\)
a. PTHH: MgO + 2HCl ---> MgCl2 + H2O
Ta thấy: \(\dfrac{0,1}{1}< \dfrac{0,4}{2}\)
Vậy HCl dư.
=> \(n_{dư}=\dfrac{0,1.2}{0,4}=0,5\left(mol\right)\)
=> \(m_{dư}=0,5.36,5=18,2\left(g\right)\)
b. Ta có: \(V_{dd_{MgCl_2}}=V_{HCl}=\dfrac{100}{1000}=0,1\left(lít\right)\)
Theo PT: \(n_{MgCl_2}=n_{MgO}=0,1\left(mol\right)\)
=> \(C_{M_{MgCl_2}}=\dfrac{0,1}{0,1}=1M\)
\(a.n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\\ CuO+2HCl\rightarrow CuCl_2+H_2O\\ n_{CuCl_2}=n_{CuO}=0,1\left(mol\right)\\ n_{HCl}=2.0,1=0,2\left(mol\right)\\ m_{CuCl_2}=135.0,1=13,5\left(g\right)\\ b.m_{HCl}=0,2.36,5=7,3\left(g\right)\\ c.C_{MddHCl}=\dfrac{0,2}{0,2}=1\left(M\right)\)
Em chưa biết làm dạng này như nào em? Vì dạng này rất cơ bản em ạ!
a) Đề bài sai phải không? (CO3 ----> CO2 chứ)
CO2 + H2O -----> H2CO3
CM= 0,36 (M)
b) nCuO=\(\frac{10}{80}\) = 0,125 (mol)
nH2CO3= \(\frac{2}{11}\) (mol)
CuO + H2CO3 ------> CuCO3 + H2O
ban đầu 0,125 \(\frac{2}{11}\) }
pư 0,125 ---> 0,125 ---> 0,125 } (mol)
sau pư 0 \(\frac{5}{88}\) 0,125 }
CM(H2CO3)=\(\frac{\frac{5}{88}}{0,5}\)=0,11 (M)
CM(CuCO3)=\(\frac{0,125}{0,5}\)=0,25 (M)
\(n_{H_2SO_4}=0,05.2=0,1\left(mol\right)\\ n_{BaCl_2}=0,05.1=0,05\left(mol\right)\\ BaCl_2+H_2SO_4\rightarrow BaSO_4\downarrow+2HCl\\ Vì:\dfrac{0,05}{1}< \dfrac{0,1}{1}\\ \Rightarrow H_2SO_4dư\\ n_{H_2SO_4\left(p.ứ\right)}=n_{BaCl_2}=0,05\left(mol\right)\\ n_{H_2SO_4\left(dư\right)}=0,1-0,05=0,05\left(mol\right)\\ n_{NaCl}=2.0,05=0,1\left(mol\right)\\ V_{ddsau}=0,05+0,05=0,1\left(l\right)\\ C_{MddNaCl}=\dfrac{0,1}{0,1}=1\left(M\right)\\ C_{MddH_2SO_4\left(dư\right)}=\dfrac{0,05}{0,1}=0,5\left(M\right)\)
nCuO=0,125mol
nH2SO4=0,5 mol
CuO + 2H2SO4--> CuCl2 + H2O
0,125 0,5
0,125 0,25 0,125
CCuCl2=0,125/0,5=0,25 M
CHCl du=0,25/0,5=0,5 M
0 0,25 0,125
CCuCl2= 0,125/