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\(n_{KOH}=\dfrac{100.14}{100.56}=0,25(mol)\\ 2KOH+CuCl_2\to Cu(OH)_2\downarrow+2KCl\\ \Rightarrow n_{CuCl_2}=n_{Cu(OH)_2}=0,125(mol);n_{KCl}=0,25(mol)\\ a,m_{CuCl_2}=0,125.135=16,875(g)\\ b,m_{Cu(OH)_2}=0,125.98=12,25(g)\\ c,C\%_{KCl}=\dfrac{0,25.74,5}{100+16,875-12,25}.100\%=17,8\%\\ d,Cu(OH)_2\xrightarrow{t^o}CuO+H_2O\\ \Rightarrow n_{CuO}=0,125(mol)\\ \Rightarrow m_{CuO}=0,125.80=10(g)\)
PTHH: \(CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_2\downarrow\)
\(Cu\left(OH\right)_2\xrightarrow[]{t^o}CuO+H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{CuCl_2}=0,2\cdot2=0,4\left(mol\right)\\n_{NaOH}=0,2\cdot2=0,4\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,4}{1}>\dfrac{0,4}{2}\) \(\Rightarrow\) CuCl2 còn dư
\(\Rightarrow\left\{{}\begin{matrix}n_{NaCl}=0,4\left(mol\right)\\n_{Cu\left(OH\right)_2}=0,2\left(mol\right)=n_{CuO}=n_{CuCl_2\left(dư\right)}\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CuO}=0,2\cdot80=16\left(g\right)\\C_{M_{NaCl}}=\dfrac{0,4}{0,2+0,2}=1\left(M\right)\\C_{M_{CuCl_2}}=\dfrac{0,2}{0,4}=0,5\left(M\right)\\\end{matrix}\right.\)
Câu 1
a)CuSO4+2NaOH---->Cu(OH)2+Na2SO4
Ta có
n CuSO4=0,4.2=0,8(mol)
Theo pthh
n Cu(OH)2=n CuSO4=0,8(mol0
m Cu(OH)2=0,8.98=78,4(g)
b)Cu(OH)2---->CuO+H2O
Theopthh2
n CuO=n Cu(OH)2=0,8(MOL)
m=m CuO=0,8.80=64(g)
Bài 2
2A+Cl2--->2ACl
Ta có
n A=\(\frac{9,2}{A}\)
n ACl=\(\frac{23,4}{A+35,5}\)
Theo pthh
n A=n ACl---->\(\frac{9,2}{A}=\frac{23,4}{A+35,5}\)
-->23,4A=9,2A+326,6
---->14,2A=326,6
>A=23
Vậy A là Na
Câu 3
Mg+2HCl---.MgCl2+H2
Fe+2HCl---->FeCl2+H2
Zn+2HCl-->ZnCl2+H2
n H2=8,96/22,4=0,4(mol)
Theo pthh 1,2,3
n HCl=2n H2=0,8(mol)
m HCl=0,8.36,5=29,2(g)
Áp dụng ĐLBTKL ta có
m Muối=m KL+m HCl-m H2
=16,9+29,2-0,845,3(g)
câu 1
cho 2dd trên td vs NaOH dư
có tủa => CuSO4
CuSO4 + 2NaOH => Na2SO4 + Cu(OH)2
ko hiện tượng => Na2SO4
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,3\left(mol\right)\)
\(\Rightarrow m_{Zn}=0,3.65=19,5\left(g\right)\)
c, \(n_{HCl}=2n_{H_2}=0,6\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,6}{0,1}=6\left(M\right)\)
a)PTHH: ZnCl2+2KOH---->Zn(OH)2+2KCl
b)
mZnCl2=204.10100=20,4(g)ZnCl2=204.10100=20,4(g)
nZnCl2=20,4136=0,15(mol)ZnCl2=20,4136=0,15(mol)
nKOH=112.20%56=0,4(mol)KOH=112.20%56=0,4(mol)
=> 0,15/1 < 0,4/1=> KOH dư
Theo pthh, ta có :
nCu(OH)2=nZnCl2=0,15(mol)Cu(OH)2=nZnCl2=0,15(mol)
mCu(OH)2=0,15.98=14,7(g)Cu(OH)2=0,15.98=14,7(g)
c) m dd sau pư=204+112=316(g)
Theo pthh
nKOH=2nZnCl2=0,3(mol)KOH=2nZnCl2=0,3(mol)
C% KOH=0,3.56326.100%=5,32%0,3.56326.100%=5,32%
nKCl=2nZnCl2=0,3(mol)KCl=2nZnCl2=0,3(mol)
C% KCl=0,3.74,5316.100%=7,07%
a, \(CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_2\)
b, \(n_{NaOH}=\dfrac{10}{40}=0,25\left(mol\right)\)
Theo PT: \(n_{CuCl_2}=n_{Cu\left(OH\right)_2}=\dfrac{1}{2}n_{NaOH}=0,125\left(mol\right)\)
\(\Rightarrow m_{Cu\left(OH\right)_2}=0,125.98=12,25\left(g\right)\)
c, \(C_{M_{CuCl_2}}=\dfrac{0,125}{0,1}=1,25\left(M\right)\)
\(n_{NaOH}=\dfrac{10}{40}=0,25\left(mol\right)\)
PTHH:
\(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\)
0,125 0,25 0,125 0,25
\(m_{Cu\left(OH\right)_2}=0,125.98=12,25\left(g\right)\)
\(C_{M\left(CuCl_2\right)}=\dfrac{0,125}{0,1}=1,25\left(M\right)\)