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a) n Fe = 28/56 = 0,5(mol)
$Fe + 2HCl \to FeCl_2 + H_2$
Theo PTHH :
n HCl = 2n Fe = 1(mol)
=> m dd HCl = 1.36,5/10% = 365(gam)
b)
n FeCl2 = n H2 = n Fe = 0,5(mol)
Suy ra :
V H2 = 0,5.22,4 = 11,2(lít)
m FeCl2 = 0,5.127 = 63,5(gam)
c)
Sau phản ứng:
mdd = m Fe + mdd HCl - m H2 = 28 + 365 - 0,5.2 = 392(gam)
=> C% FeCl2 = 63,5/392 .100% = 16,2%
\(n_{Al}=\dfrac{6,75}{27}=0,25\left(mol\right)\)
PTHH :
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
0,25 0,75 0,25 0,375
\(a,V_{H_2}=0,375.22,4=8,4\left(l\right)\)
\(b,m_{HCl}=0,75.36,5=27,375\left(g\right)\)
\(m_{ddHCl}=\dfrac{27,375.100}{10,95}=250\left(g\right)\)
\(c,m_{AlCl_3}=0,25.133,5=33,375\left(g\right)\)
\(m_{ddAlCl_3}=6,75+250-\left(0,375.2\right)=256\left(g\right)\)
\(C\%_{AlCl_3}=\dfrac{33,375}{256}.100\%\approx13,04\left(\%\right)\)
\(n\)Fe = \(\dfrac{8,4}{56}\)= 0,15 mol
Fe + 2HCl -----> FeCl\(2\)+H\(2\)
0,15->0,3 ->0,15 -> 0,15 (mol
V\(H2\) = 0,15 . 22,4 = 3,36 l
b, mct HCl = 0,3 . 36,5 = 10,95 (g)
mdd HCl = \(\dfrac{10,95}{10,95\%}\) = 100 (g)
c, mdd sau pu = 8,4 + 100 - 0,15.2 = 108,1 g
C% FeCl2 = \(\dfrac{0,15.127}{108,1}.100\%\)= 1,76%
nFe = 5.6/56 = 0.1 (mol)
nHCl = 0.2*2 = 0.4 (mol)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
LTL : 0.1/1 < 0.4/2 => HCl dư
mHCl dư = ( 0.4 - 0.2 ) * 36.5 = 7.3 (g)
VH2 = 0.2*22.4 = 4.48 (l)
CM FeCl2 = 0.1/0.2 = 0.5(M)
CM HCl dư = 0.2 / 0.2 = 1(M)
nFe = 2,8 : 56 = 0,05 ( mol )
PTHH : Fe + 2HCl -----> FeCl2 + H2
mol 0,05 0,1 0,05
VH2 = 0,05 x 22,4 = 1,12 ( l )
mHCl = 0,1 x 36,5 = 3,65 ( g)
=> mHCl (10%) = 3,65 x 100 : 10 = 36,5 (g)
PTHH
Fe + 2HCl \(\rightarrow\) Fe + H2O
gt 0,05 0,1 0,05 0,05
mFe = 2,8 g \(\Rightarrow\) nFe = \(\frac{m}{M}\)= \(\frac{2,8}{56}=0,05\left(mol\right)\)
Theo ptpư + gt ta có:
V\(H_2\) = n. 22,4 = 0,05 . 22,4 = 1,12 (lít)
mHCl = 0,1 . 36,5 = 3, 65 (g)
mdd HCl = \(\frac{3,65.100}{10}=36,5\left(g\right)\)
\(n_{Fe}=\dfrac{2,8}{56}=0,05\left(mol\right)\\ a,PTHH:Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{H_2}=n_{FeCl_2}=n_{Fe}=0,05\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,05.22,4=1,12\left(l\right)\\ V_{H_2\left(đkc\right)}=0,05.24,79=1,2395\left(l\right)\\ b,n_{HCl}=0,1.3=0,3\left(mol\right)\\ Vì:\dfrac{0,05}{1}< \dfrac{0,3}{2}\Rightarrow HCldư\\ n_{HCl\left(dư\right)}=0,3-0,05.2=0,2\left(mol\right)\\ n_{FeCl_2}=n_{Fe}=0,05\left(mol\right)\\ V_{ddsau}=V_{ddHCl}=0,1\left(l\right)\\ b,C_{MddFeCl_2}=\dfrac{0,05}{0,1}=0,5\left(M\right);C_{MddHCl\left(dư\right)}=\dfrac{0,2}{0,1}=2\left(M\right)\)
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\)
PTHH :
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
0,15 0,3 0,15 0,15
\(V_{H_2}=n.22,4=0,15.22,4=3,36\left(l\right)\)
Còn lại đề thiếu dữ kiện , bạn bổ sung và nếu cần thì đăng lại nha
\(n_{Fe}=\dfrac{8,4}{56}=0,15mol\)
a)\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,15 0,3 0,15 0,15
\(V_{H_2}=0,15\cdot22,4=3,36l\)
b)\(m_{H_2}=0,15\cdot2=0,3g\)
\(BTKL:m_{ddFeCl_2}=8,4+100-0,3=108,1g\)
\(m_{ctFeCl_2}=0,15\cdot127=19,05g\)
\(C\%=\dfrac{m_{ctFeCl_2}}{m_{ddFeCl_2}}\cdot100\%=\dfrac{19,05}{108,1}\cdot100\%=17,62\%\)
a) \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(Đặt:n_{Zn}=x\left(mol\right);n_{Fe}=y\left(mol\right)\)
\(n_{H_2}=0,4\left(mol\right)\)
Theo đề ta có hệ \(\left\{{}\begin{matrix}65x+56y=24,2\\x+y=0,4\end{matrix}\right.\)
=> x=0,2 ; y=0,2
\(\%m_{Zn}=\dfrac{0,2.65}{24,2}.100=53,72\%;\%m_{Fe}=46,28\%\)
b)Bảo toàn nguyên tố H: \(n_{HCl}=2n_{H_2}=0,8\left(mol\right)\)
=> \(V_{HCl}=\dfrac{0,8}{2,5}=0,32\left(l\right)\)
c) \(n_{FeCl_2}=0,2\left(mol\right);n_{ZnCl_2}=0,2\left(mol\right)\)
=> \(CM_{FeCl_2}=\dfrac{0,2}{0,32}=0,625\left(mol\right)\)
\(CM_{ZnCl_2}=\dfrac{0,2}{0,32}=0,625\left(mol\right)\)
`Fe + 2HCl -> FeCl_2 + H_2`
`0,05` `0,1` `0,05` `0,05` `(mol)`
`n_[Fe]=[2,8]/56=0,05(mol)`
`a)V_[H_2]=0,05.22,4=1,12(l)`
`b)m_[dd HCl]=[0,1.36,5]/10 . 100 = 36,5(g)`
`c)C%_[FeCl_2]=[0,05.127]/[2,8+36,5-0,05.2] . 100~~16,2%`