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a) $2NaOH + H_2SO_4 \to Na_2SO_4 + 2H_2O$
b)
n H2SO4 = 0,03.1 = 0,03(mol)
n NaOH = 2n H2SO4 = 0,06(mol)
=> CM NaOH = 0,06/0,05 = 1,2M
c) $H_2SO_4 + 2KOH \to K_2SO_4 + 2H_2O$
n KOH = 2n H2SO4 = 0,06(mol)
=> m KOH = 0,06.56 = 3,36 gam
=> m dd KOH = 3,36/5,6% = 60(gam)
=> V dd KOH = m/D = 60/1,045 = 57,42(ml)
1.
Al2O3 + 2NaOH -> 2NaAlO2 + H2O (1)
nNaAlO2=0,225(mol)
Từ 1:
nNaOH=nNaAlO2=0,225(mol)
nal2O3=\(\dfrac{1}{2}\)nNaAlO2=0,1125(mol)
V dd NaOH=0,225:5=0,045(lít)
mAl2O3=0,1125.102=11,475(g)
mquặng=11,475.110%=12,6225(g)
\(n_{MgCO_3}=\dfrac{16,8}{84}=0,2mol\\ a.MgCO_3+H_2SO_4->MgSO_4+H_2O+CO_2\\ 2NaOH+H_2SO_{\text{4 }}->Na_2SO_4+2H_2O\\ b.n_{H_2SO_4dư}=\dfrac{1}{2}n_{NaOH}=\dfrac{1}{2}.80.0,1:40=0,1mol\\ n_{H_2SO_4\left(MgCO_3\right)}=0,2mol\\ c.C\%=\dfrac{98.0,3}{200}.100\%=14,7\%\\ V=0,2.22,4=4,48L\\ d.m_{ddsau}=200+16,8-44.0,2+80=288g\\ C\%_{Na_2SO_4}=\dfrac{40.0,1}{288}.100\%=1,39\%\\ C\%_{MgSO_4}=\dfrac{120.0,2}{288}.100\%=8,33\%\)
\(n_{MgCO_3}=\dfrac{16,8}{84}=0,2\left(mol\right)\)
\(n_{NaOH}=\dfrac{80}{40}=2\left(mol\right)\)
PTHH :
\(MgCO_3+H_2SO_4\rightarrow MgSO_4+H_2O+CO_2\uparrow\)
0,2 0,2 0,2
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
2 1 1
Vậy có 0,2 mol H2SO4 phản ứng với MgCO3
có 1 mol H2SO4 phản ứng với NaOH
\(m_{H_2SO_4}=1,2.98=117,6\left(g\right)\)
\(c,C\%_{H_2SO_4}=\dfrac{117,6}{200}.100\%=58,8\%\)
\(V_{CO_2}=0,2.22,4=4,48\left(l\right)\)
\(d,m_{Na_2SO_4}=1.142=142\left(g\right)\)
\(m_{ddNaOH}=\dfrac{80.100}{10}=800\left(g\right)\)
\(m_{ddH_2SO_4dư}=1.98:58,8\%\approx166,67\left(g\right)\)
\(m_{ddNa_2SO_4}=800+166,67=966,67\left(g\right)\)
\(C\%_{Na_2SO_4}=\dfrac{142}{966,67}.100\%\approx14,69\%\)
a) H2SO4 + 2NaOH --> Na2SO4 + 2H2O
b) \(n_{H_2SO_4}=0,2.1=0,2\left(mol\right)\)
PTHH: H2SO4 + 2NaOH --> Na2SO4 + 2H2O
0,2---->0,4
=> mNaOH = 0,4.40 = 16 (g)
=> \(m_{dd.NaOH}=\dfrac{16.100}{20}=80\left(g\right)\)
c)
PTHH: H2SO4 + 2KOH --> K2SO4 + 2H2O
0,2---->0,4
=> mKOH = 0,4.56 = 22,4 (g)
=> \(m_{dd.KOH}=\dfrac{22,4.100}{5,6}=400\left(g\right)\)
=> \(V_{dd.KOH}=\dfrac{400}{1,045}=382,775\left(ml\right)\)
\(n_{H_2SO_4}=0,2.1=0,2\left(mol\right)\\ pthh:H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)
0,2 0,4
\(m_{\text{ }NaOH}=0,4.40=16g\\ m_{\text{dd}NaOH}=\dfrac{16.100}{20}=80g\)
\(pthh:H_2SO_4+2KOH\rightarrow K_2SO_4+2H_2O\)
0,2 0,4
\(m_{KOH}=0,4.56=22,4g\\
m_{\text{dd}KOH}=\dfrac{22,4.100}{5,6}=400g\\
V_{\text{dd}}=\dfrac{400}{1,045}=382,7ml\)
\(V_{dd}=\dfrac{22,4}{1,045}=21,4354ml\)
BaCl2 + H2SO4 ➜ BaSO4↓ + 2HCl
\(n_{BaCl_2}=0,3\times1=0,3\left(mol\right)\)
\(n_{H_2SO_4}=0,5\times1,5=0,75\left(mol\right)\)
Theo PT: \(n_{BaCl_2}=n_{H_2SO_4}\)
Theo bài: \(n_{BaCl_2}=\dfrac{2}{5}n_{H_2SO_4}\)
Vì \(\dfrac{2}{5}< 1\) ⇒ dd BaCl2 hết, dd H2SO4 dư
a) Theo PT: \(n_{BaSO_4}=n_{BaCl_2}=0,3\left(mol\right)\)
\(\Rightarrow m_{BaSO_4}=0,3\times233=69,9\left(g\right)\)
b) Dung dịch thu được gồm: H2SO4 dư và HCl
Theo PT: \(n_{H_2SO_4}pư=n_{BaCl_2}=0,3\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4}dư=0,75-0,3=0,45\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{BaCl_2}=2\times0,3=0,6\left(mol\right)\)
\(\Sigma m_{dd}=0,3+0,5=0,8\left(l\right)\)
\(C_{M_{H_2SO_4}}dư=\dfrac{0,45}{0,8}=0,5625\left(M\right)\)
\(C_{M_{HCl}}=\dfrac{0,6}{0,8}=0,75\left(M\right)\)
nHCl=0,6 mol
FeO+2HCl-->FeCl2+ H2O
x mol x mol
Fe2O3+6HCl-->2FeCl3+3H2O
x mol 2x mol
72x+160x=11,6 =>x=0,05 mol
A/ CFeCl2=0,05/0,3=1/6 M
CFeCl3=0,1/0,3=1/3 M
CHCl du=(0,6-0,4)/0,3=2/3 M
B/
NaOH+ HCl-->NaCl+H2O
0,2 0,2
2NaOH+FeCl2-->2NaCl+Fe(OH)2
0,1 0,05
3NaOH+FeCl3-->3NaCl+Fe(OH)3
0,3 0,1
nNaOH=0,6
CNaOH=0,6/1,5=0,4M
\(n_{H_2SO_4}=0.3\cdot1=0.3\left(mol\right)\)
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\)
\(0.6...............0.3...............0.3\)
\(V_{dd_{NaOH}}=\dfrac{0.6}{1}=0.6\left(l\right)=600\left(ml\right)\)
\(C_{M_{Na_2SO_4}}=\dfrac{0.3}{0.3+0.6}=0.33\left(M\right)\)