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4 ý cuối :
1)
Cu + 2H2SO4→ CuSO4+ SO2+2H2O
Cu0 →Cu+2 +2e║ x1
S+6+2e →S+4 ║ x1
2)
2Al+ 4H2SO4→ Al2(SO4)3+ S+ 4H2O
2Al0→2Al+3 +6e║x1
S+6 +6e→S0 ║x1
3)
4Zn +5H2SO4→ 4ZnSO4+ H2S+ 4H2O
Zn0\(\rightarrow\) Zn+2 +2e ║x4
S+6 +8e →S−2 ║x1
4)
8Fe+ 15H2SO4→ 4Fe2(SO4)3+3H2S+ 12H2O
2Fe0→ 2Fe+3+6e║x4
S+6 +8e →S−2 ║x3
6 ý đầu
1.\(\overset{-3}{4NH_2}+\overset{0}{5O_2}\rightarrow\overset{+2+6}{4NO}+\overset{-2}{6H_2O}\)
4 X \(||\) N-3 + 5e → N+2
5 X \(||\) 2O0 + 4e → 2O-2
2.\(\overset{-3}{4NH3}+\overset{0}{3O_2}\rightarrow\overset{0}{2N_2}+\overset{-2}{6H_2O}\)
2 X \(||\) 2N-3 + 6e → 2N0
3 X \(||\) 2O0 + 4e → 2O-2
3.\(\overset{0}{3Mg}+\overset{+5}{8NO_3}\rightarrow\overset{+2}{3Mg\left(NO_3\right)_2}+\overset{+2}{2NO}+\overset{ }{4H_2O}\)
3 X \(||\) Mg0 → Mg+2 + 2e
2 X \(||\) N+5 + 3e → N+2
4.\(\overset{0}{Al}+\overset{+5}{6NO_3}\rightarrow\overset{+3}{Al\left(NO_3\right)_3}+\overset{+4}{3NO_2}+\overset{ }{3H_2O}\)
1 X \(||\) Al0 → Al+3 + 3e
3 X \(||\) N+5 + 1e → N+4
5.\(\overset{0}{Zn}+\overset{+5}{4HNO_3}\rightarrow\overset{+3}{Fe\left(NO_3\right)_3}+\overset{+2}{NO}+\overset{ }{2H_2O}\)
1 X \(||\) Zn0 → Mg+2 + 2e
2 X \(||\) N+5 + 3e → N+4
6.\(\overset{0}{Fe}+\overset{+5}{4HNO_3}\rightarrow\overset{+3}{Fe\left(NO_3\right)_3}+\overset{+2}{NO}+\overset{ }{2H_2O}\)
1 X \(||\) Fe0 → Fe+3 + 3e
1 X \(||\) N+5 + 3e → N+2
1) 3Mg + 8HNO3 → 3Mg(NO3)2 + 2NO + 4H2O
2) 2Fe + 6H2SO4 → Fe2(SO4)3 + 3SO2 + 6H2O
3) 4Mg + 5H2SO4 → 4MgSO4 + H2S + 4H2O
4) 8Al + 30HNO3 → 8Al(NO3)3 + 3NH4NO3 + 9H2O
5) 2FeCO3 + 4H2SO4 → Fe2(SO4)3 + SO2 + 2CO2 + 4H2O
6) 8Fe3O4 + 74HNO3 → 24Fe(NO3)3 + N2O + 37H2O
7) 8Al + 30HNO3 → 8Al(NO3)3 + 3N2O + 15H2O
8) 10FeSO4 + 8H2SO4 + 2KMnO4 → 5Fe2(SO4)3 + 2MnSO4 + K2SO4 + 8H2O
9) 2KMnO4 + 16HCl → 2KCl + 2MnCl2 + 5Cl2 + 8H2O
10) K2Cr2O7 + 14HCl → 2KCl + 2CrCl3 + 3Cl2 + 7H2O
mình ghi số cân bằng thôi nhaa, 3Mg +8HNO3 -> 3(Mg(NO3)2+2NO+4H2O
b, Fe+6H2SO4 -> Fe2(SO4)3+3SO2 + 6H2O
c, 4Mg + 5H2SO4 -> 4MgSO4 + H2S + 4H2O
d, 8Al +30 HNO3 -> 8Al(NO3)3 + 3NH4NO3 + 9H2O
e, 6FeCO3 + 10H2SO4 -> 3Fe2(SO4)3 +S+ 6CO2 +10H2O
f, 8Fe3O4 +74HNO3 -> 24Fe(NO3)3 + N2O + 37H2O
g, 8Al +30HNO3 -> 8Al(NO3)3 + 3N2O + 15H2O
h,10FeSO4 + 8H2SO4 +2KMnO4 -> 5Fe2(SO4)3 + 2MnSO4 + K2SO4 +8H2O
i,2KMnO4 +16 HCl ->2 KCl + 2MnCl2 + 5Cl2 + 8H2O
j,K2Cr2O7 +14HCl -> 2KCl + 2CrCl3 + 3Cl2 + 7H2O
\(\overset{+2}{Fe}\overset{-2}{S}+H\overset{+5}{N}O_3+H_2O\rightarrow\overset{+3}{Fe}\left(NO_3\right)_3+\overset{+3}{Fe}_2\left(\overset{+6}{S}O_4\right)_3+\overset{-3}{N}H_4NO_3\) quá trình OXH : \(3\overset{+2}{Fe}+3\overset{-2}{S}\rightarrow3\overset{+3}{Fe}+3\overset{+6}{S}+27e|\times8\)
quá trình khử : \(\overset{+5}{N}+8e\rightarrow\overset{-3}{N}|\times27\)
\(\Rightarrow\) \(24FeS+78HNO_3+15H_2O\rightarrow8Fe\left(NO_3\right)_3+8Fe_2\left(SO_4\right)_3+27NH_4NO_3\)
4.MnO2+4HCl\(\rightarrow\)MnCl2+Cl2+2H2O
Mn+4 +2e \(\rightarrow\)Mn+2
2Cl- \(\rightarrow\)Cl2+2e
5.2KMnO4+16HCl\(\rightarrow\)2KCl+2MnCl2+5Cl2+8H2O
Mn+7+5e\(\rightarrow\)Mn+2
2Cl-\(\rightarrow\)Cl2+2e
6.8FeO+26HNO3\(\rightarrow\)8Fe(NO3)3+N2O+13H2O
Fe+2\(\rightarrow\)Fe+3 +1e
2N+5+8e\(\rightarrow\)2N+1
7.2KMnO4+3K2SO3+H2O\(\rightarrow\)3K2SO4+2MnO2+2KOH
S+4\(\rightarrow\)S+6 +2e
Mn+7+3e\(\rightarrow\)Mn+4
8.\(\text{2KMnO4+10FeSO4+8H2SO4}\rightarrow\text{5Fe2(SO4)3+2MnSO4+K2SO4+8H2O}\)
Mn+7 +5e\(\rightarrow\)Mn+2
Fe+2 \(\rightarrow\)Fe+3+1e
2KMnO4\(\rightarrow\)K2MnO4+O2+MnO2
\(\overset{+2}{N}O+K_2\overset{+6}{Cr}_2O_7+H_2SO_4\rightarrow H\overset{+5}{N}O_3+K_2SO_4+\overset{+3}{Cr}_2\left(SO_4\right)_3+H_2O\)
quá trình OXH : \(\overset{+2}{N}\rightarrow\overset{+5}{N}+3e\) \(\times2\)
quá trình khử : \(\overset{+6}{2Cr}+2.3e\rightarrow\overset{+3}{2Cr}\) \(\times1\)
\(\Rightarrow\)\(2NO+K_2Cr_2O_7+4H_2SO_4\rightarrow2HNO_3+K_2SO_4+Cr_2\left(SO_4\right)_3+3H_2O\)