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\(a) m_{O_2} = 28,05 - 21,65 = 6,4(gam)\\ n_{O_2} = \dfrac{6,4}{32} = 0,2(mol)\\ V_{O_2} = 0,2.22,4 = 4,48(lít)\\ b) n_{KClO_3} =a ; n_{KMnO_4} = b(mol)\\ \Rightarrow 122,5a + 158b = 28,05(1)\\ 2KClO_3 \xrightarrow{t^o} 2KCl + 3O_2\\ 2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2\\ n_{O_2} = 1,5a + 0,5b = 0,2(2) (1)(2)\Rightarrow a = b = 0,1\)
\(m_{KClO_3} = 0,1.122,5 = 12,25(gam)\\ m_{KMnO_4} = 0,1.158 = 15,8(gam)\\ n_{K_2MnO_4} = n_{MnO_2} = 0,5b = 0,05(mol)\\ m_{K_2MnO_4} = 0,05.197 = 9,85(gam)\\ m_{MnO_2} = 0,05.87 = 4,35(gam)\\ n_{KCl} = n_{KClO_3} = 0,1(mol)\\ m_{KCl} = 0,1.74,5 = 7,45(gam)\)
PT: \(2KClO_3\xrightarrow[MnO_2]{t^o}2KCl+3O_2\)
\(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
a, Phần này phải là thể tích O2 chứ nhỉ?
Theo ĐLBT KL, có: mKClO3 + mKMnO4 = m chất rắn + mO2
⇒ mO2 = 28,05 - 21,65 = 6,4 (g)
\(\Rightarrow n_{O_2}=\dfrac{6,4}{32}=0,2\left(mol\right)\Rightarrow V_{O_2}=0,2.22,4=4,48\left(l\right)\)
b, Giả sử: \(\left\{{}\begin{matrix}n_{KClO_3}=x\left(mol\right)\\n_{KMnO_4}=y\left(mol\right)\end{matrix}\right.\)
⇒ 122,5x + 158y = 28,05 (1)
Theo PT: \(n_{O_2}=\dfrac{3}{2}x+\dfrac{1}{2}y\left(mol\right)\)
\(\Rightarrow\dfrac{3}{2}x+\dfrac{1}{2}y=0,2\left(2\right)\)
Từ (1) và (2) ⇒ x = y = 0,1 (mol)
⇒ mKClO3 = 122,5.0,1 = 12,25 (g)
mKMnO4 = 0,1.158 = 15,8 (g)
Theo PT: \(\left\{{}\begin{matrix}n_{KCl}=n_{KClO_3}=0,1\left(mol\right)\\n_{K_2MnO_4}=n_{MnO_2}=\dfrac{1}{2}n_{KMnO_4}=0,05\left(mol\right)\end{matrix}\right.\)
⇒ mKCl = 0,1.74,5 = 7,45 (g)
mK2MnO4 = 0,05.197 = 9,85 (g)
mMnO2 = 0,05.87 = 4,35 (g)
Bạn tham khảo nhé!
\(a)n_{KMnO_4} = a; n_{KClO_3} = b\Rightarrow 158a + 122,5b = 99,95(1)\\ 2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2\\ 2KClO_3 \xrightarrow{t^o} 2KCl + 3O_2\\ n_{O_2} = 0,5a +1,5b = \dfrac{14,56}{22,4}=0,65(2)\\ (1)(2)\Rightarrow a = 0,4 ; b = 0,3\\ \%m_{KMnO_4} = \dfrac{0,4.158}{99,95}.100\% = 63,23\%\\ \%m_{KClO_3} = 100\%-63,23\% = 36,77\%\)
\(n_{K_2MnO_4} = n_{MnO_2} = 0,5a = 0,2(mol)\\ n_{KClO_3} = b = 0,3(mol)\\ m_{hh\ sau\ pư} = 99,95 - 0,65.32 = 79,15(gam)\\ \%m_{K_2MnO_4} = \dfrac{0,2.197}{79,15}.100\% = 49,78\%\\ \%m_{MnO_2} = \dfrac{0,2.87}{79,15},100\% = 21,98\%\\ \%m_{KCl} = 28,24\%\)
ko khó lém bn ơi có câu nèo easy hơm ko
Gọi n KMnO4 = a
n KClO3 = b ( mol )
--> 158a + 122,5 b = 43,3
PTHH :
\(2KClO_3\underrightarrow{t^o}2KCl+3O_2\uparrow\)
0,9b 1,35b
\(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
0,9a 0,45a
\(\%Mn=\dfrac{55a}{43,3-32\left(0,45a+1,35b\right)}=24,103\%\)
\(\rightarrow a=0,15\)
\(b=0,16\)
\(m_{KMnO_4}=0,15.158=23,7\left(g\right)\)
\(m_{KClO_3}=0,16.122,5=19,6\left(g\right)\)
\(n_{Al}=\dfrac{1,728}{27}=0,064\left(mol\right)\)
PTHH: 4Al + 3O2 --to--> 2Al2O3
____0,064->0,048
=> mO2 = 0,048.32 = 1,536 (g)
\(m_B=\dfrac{0,894.100}{8,127}=11\left(g\right)\)
Theo ĐLBTKL: mA = mB + mO2
=> mA = 11 + 1,536 = 12,536 (g)
\(n_{KMnO_4}=\dfrac{31,6}{158}=0,2mol\)
\(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
0,2 0,1 0,1 0,1
a)\(V_{O_2}=0,1\cdot22,4=2,24l\)
b)\(m_{CRắn}=m_{K_2MnO_4}+m_{MnO_2}=0,1\cdot197+0,1\cdot87=28,4g\)
c)\(n_{CH_4}=\dfrac{11,2}{22,4}=0,5mol\)
\(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
0,5 0,1 0 0
0,05 0,1 0,05 0,1
0,45 0 0,05 0,1
\(V_{CO_2}=0,05\cdot22,4=1,12l\)
\(m_{H_2O}=0,1\cdot18=1,8g\)
PTHH: 2KMnO4--to-> K2MnO4+MnO2+O2
0,2----------------0,1---------0,1-----0,1
b, nKMnO4= \(\dfrac{31,6}{158}\)=0,2 mol
Theo pt: nO2=\(\dfrac{1}{2}\).0,2=0,1 mol
=> VO2= 0,1.22,4= 2,24 l
=>m cr=0,1.197+0,1.87=28,4g
CH4+2O2-to>CO2+2H2O
0,5-----0,25-----0,5
n CH4=\(\dfrac{11,2}{22,4}\)=0,5 mol
=>Oxi du
=>V CO2=0,25.22,4=5,6l
=>m H2O=0,5.18=9g
1)
Gọi số mol KMnO4, KClO3 là a, b (mol)
=> 158a + 122,5b = 308,2 (1)
PTHH: 2KMnO4 --to--> K2MnO4 + MnO2 + O2
a-------------------------------->0,5a
2KClO3 --to--> 2KCl + 3O2
b------------------>1,5b
=> mO2 = (0,5a + 1,5b).32 = 16a + 48b (g)
mD = 308,2 - 16a - 48b(g)
\(m_{Mn}=\dfrac{\left(308,2-16a-48b\right).10,69}{100}=32,94658-1,7104a-5,1312b\left(g\right)\)
=> \(n_{Mn}=\dfrac{32,94658-1,7104a-5,1312b}{55}=0,6-\dfrac{1069}{34375}a-\dfrac{3207}{34375}\left(mol\right)\)
Mà \(n_{Mn}=n_{KMnO_4}=a\left(mol\right)\)
=> \(\dfrac{35444}{34375}a+\dfrac{3207}{34375}b=0,6\) (2)
(1)(2) => a = 0,4 (mol); b = 2 (mol)
=> \(\left\{{}\begin{matrix}\%m_{KMnO_4}=\dfrac{0,4.158}{308,2}.100\%=20,506\%\\\%m_{KClO_3}=\dfrac{2.122,5}{308,2}.100\%=79,494\%\end{matrix}\right.\)
2)
Giả sử nung 100 (g) đá vôi
=> \(m_{CaCO_3\left(bđ\right)}=\dfrac{80.100}{100}=80\left(g\right)\)
\(m_{rắn.sau.pư}=\dfrac{100.73,6}{100}=73,6\left(g\right)\)
=> mCO2 = 100 - 73,6 = 26,4 (g)
\(n_{CO_2}=\dfrac{26,4}{44}=0,6\left(mol\right)\)
PTHH: CaCO3 --to--> CaO + CO2
0,6<----------------0,6
=> mCaCO3(pư) = 0,6.100 = 60 (g)
\(H\%=\dfrac{60}{80}.100\%=75\%\)
`#3107.101107`
1.
a.
Ta có:
\(\text{n}_{\text{KClO}_3}=\dfrac{\text{m}_{\text{KClO}_3}}{\text{M}_{\text{KClO}_3}}=\dfrac{122,5}{122,5}=1\text{ (mol)}\)
PTPỨ: \(\text{2KClO}_3\text{ }\)\(\underrightarrow{\text{ }t^0}\) \(\text{2KCl}+3\text{O}_2\)
Ta có: `2` mol \(\text{KClO}_3\) thu được `3` mol \(\text{O}_2\)
`=>` `1` mol \(\text{KClO}_3\) thu được `1,5` mol \(\text{O}_2\)
b.
\(\text{V}_{\text{O}_2}=\text{n}_{\text{O}_2}\cdot24,79=1,5\cdot24,79=37,185\left(l\right)\)
TTĐ:
\(m_{KClO_3}=122,5\left(g\right)\)
______________
a) PTHH?
b) \(V_{O_2}=?\left(l\right)\)
Giải
\(n_{KClO_3}=\dfrac{m}{M}=\dfrac{122,5}{122,5}=1\left(mol\right)\)
\(2KClO_3\underrightarrow{t^o}2KCl+3O_2\uparrow\)
1-> 1 : 1,5(mol)
\(V_{O_2}=n.22,4=1,5.22,4=33,6\left(l\right)\)
$n_{Kali} = \dfrac{21,65.36,03\%}{39} = 0,2(mol)$
Gọi $n_{KMnO_4} = a ; n_{KClO_3} = b$
$2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2$
$2KClO_3 \xrightarrow{t^o} 2KCl + 3O_2$
Bảo toàn Kali : $a + b = 0,2$
$n_{O_2} = 0,5a + 1,5b(mol)$
Bảo toàn khối lượng : $158a + 122,5b = 21,65 + (0,5a + 1,5b).32$
Suy ra: a = b = 0,1
$n_{O_2} = 0,5a + 1,5b = 0,2(mol)$
$V_{O_2} = 0,2.22,4 = 4,48(lít)$
anh ơi anh giải thích giúp em chỗ a+b=0,2 được không ạ