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Số electron trong CaCO3 : 20 + 6 + 8.3 = 50(electron)
Số electron trong CO2 : 6 + 8.2 = 22(electron)
Gọi \(n_{CaCO_3} = x(mol)\)
\(n_{CO_2} = n_{CaCO_3\ pư} = x.80\% = 0,8x(mol)\)
Ta có :
\(n_{e(trong\ CaCO_3)} = n_{e(trong\ X)} + n_{e(trong\ CO_2)}\\ \Leftrightarrow 50x = \dfrac{1,944.10^{29}}{6.10^{23}} + 22x\\ \Leftrightarrow x = 10 000\\ \Rightarrow a = 10 000.100 = 10^6(gam) = 1(tấn)\)
a) PTHH : \(FeO+H_2-t^o->Fe+H_2O\)
\(CuO+H_2-t^o->Cu+H_2O\)
Đặt \(\hept{\begin{cases}n_{FeO}=x\left(mol\right)\\n_{CuO}=y\left(mol\right)\end{cases}}\) => \(72x+80y=11,2\left(I\right)\)
Có : \(m_{O\left(lấy.đi\right)}=m_{giảm}=1,92\left(g\right)\)
=> \(n_{O\left(lấy.đi\right)}=\frac{1,92}{16}=0,12\left(mol\right)\) Vì H% = 80% => Thực tế : \(n_{O\left(hh\right)}=\frac{0,12}{80}\cdot100=0,15\left(mol\right)\)
BT Oxi : \(x+y=0,15\left(II\right)\)
Từ (I) và (II) suy ra : \(\hept{\begin{cases}x=0,1\\y=0,05\end{cases}}\)
=> \(\hept{\begin{cases}m_{FeO}=7,2\left(g\right)\\m_{CuO}=4\left(g\right)\end{cases}}\)
b) PTHH : \(Fe+H_2SO_4-->FeSO_4+H_2\)
BT Fe : \(n_{Fe}=n_{FeO}=0,1\left(mol\right)\)
Theo pthh : \(n_{H_2}=n_{Fe}=0,1\left(mol\right)\)
=> \(V_{H_2}=2,24\left(l\right)\)
BT Cu : \(n_{Cu}=n_{CuO}=0,05\left(mol\right)\)
=> \(m_{CR\left(ko.tan\right)}=0,05\cdot64=3,2\left(g\right)\)
1) \(m_{CO_2}=m_{rắn\left(trcpư\right)}-m_{rắn\left(saupư\right)}=100-64,8=35,2\left(g\right)\)
=> \(n_{CO_2}=\dfrac{35,2}{44}=0,8\left(mol\right)\)
=> \(V_{CO_2}=0,8.22,4=17,92\left(l\right)\)
2)
PTHH: CaCO3 --to--> CaO + CO2
0,8<---------0,8<---0,8
=> \(m_{CaCO_3\left(pư\right)}=0,8.100=80\left(g\right)\)
3)
\(m_{CaCO_3\left(bd\right)}=\dfrac{100.90}{100}=90\left(g\right)\)
=> Rắn sau pư chứa CaCO3, CaO, tạp chất
\(m_{tạp.chất}=100-90=10\left(g\right)\)
\(m_{CaCO_3\left(saupư\right)}=90-80=10\left(g\right)\)
\(m_{CaO}=0,8.56=44,8\left(g\right)\)
\(1,n_{CaCO_3}=\dfrac{90\%.100}{100}=0,9\left(mol\right)\\ PTHH:CaCO_3\rightarrow\left(t^o\right)CaO+CO_2\\ Đặt:n_{CaCO_3\left(p.ứ\right)}=a\left(mol\right)\left(a>0\right)\\ Ta.có:m_{rắn}=64,8\left(g\right)\\ \Leftrightarrow10+\left(90-100a\right)+56a=64,8\\ \Leftrightarrow a=0,8\left(mol\right)\\ n_{CO_2}=n_{CaO}=n_{CaCO_3\left(p.ứ\right)}=0,8\left(mol\right)\\ V_{CO_2\left(đktc\right)}=0,8.22,4=17,92\left(l\right)\\ 2,m_{CaCO_3\left(p.ứ\right)}=0,8.100=80\left(g\right)\\ 3,Rắn.sau.nung:m_{tạp.chất}=10\%.100=10\left(g\right)\\ m_{CaO}=0,8.56=44,8\left(g\right)\\ m_{CaCO_3\left(dư\right)}=\left(0,9-0,8\right).100=10\left(g\right)\)
Câu 7 :
1) \(n_{Fe3O4}=\dfrac{34,8}{232}=0,15\left(mol\right)\)
Pt : \(Fe_3O_4+4H_2\underrightarrow{t^o}3Fe+4H_2O|\)
1 4 3 4
0,15 0,45
\(n_{Fe}=\dfrac{0,15.3}{1}=0,45\left(mol\right)\)
\(m_{Fe\left(Lt\right)}=0,45.56=25,2\left(g\right)\)
⇒ \(m_{Fe\left(tt\right)}=25,2.90\%=22,68\left(g\right)\)
Chúc bạn học tốt
\(n_{Fe_3O_4}=\dfrac{34,8}{232}=0,15\left(mol\right)\)
\(pthh:Fe_3O_4+H_2\underrightarrow{t^o}Fe+H_2O\)
0,15 0,15
=> \(m_{Fe}=\dfrac{90.0,15}{100}.56=7,56\left(g\right)\)
1) câu 1. nCO2=0,75 , n H2O=1
a) gọi công thức CxHyOz gọi MCxHyOz=a
2CxHyOz + (2x+0,5y-z)O2--> 2xCO2 + yH2O
..0,75/x......................................0,75..........1
có 0,75/2x=1/y==>x/y=3/8
có a=23/0,75/x=92/3.x
có m/a=0,3478.m/o2==>a=92=92/3x==>x=3==>y=8===>z=3
=>CTHH: C3H8O3
Nguon: Hocmai nha ban
Bảo toàn khối lượng :
$m_{CO_2} = 12 - 7,6 = 4,4(gam)$
$n_{CaO} = n_{CaCO_3\ pư} = n_{CO_2} = \dfrac{4,4}{44} = 0,1(mol)$
$H = \dfrac{0,1.100}{12}.100\% = 83,33\%$
$\%m_{CaO} = \dfrac{0,1.56}{7,6}.100\% = 73,68\%$
$\%m_{CaCO_3} = 100\% -73,68\% = 26,32\%$
\(n_{CaCO_3}=\dfrac{12}{100}=0,12\left(mol\right)\\ PTHH:CaCO_3\underrightarrow{to}CaO+CO_2\\ x.........x........x\left(mol\right)\\ m_{rắn}=m_{CaCO_3\left(còn\right)}+m_{CaO}=\left(12-100x+56x\right)=7,6\\ \Leftrightarrow x=0,1\left(mol\right)\\ H=\dfrac{0,1}{0,12}.100\approx83,333\%\)
2KClO3 -to-> 2KCl + 3O2 (1)
NaCl --đpnc--> Na +Cl2 (2)
mNaCl=25/100 .a=0,25a(g)
=>nNaCl=0,25a/58,5=0,0042a(mol)
mKClO3=a - 2,5a=0,75a(g)
=> nKClO3=0,75a/122,5=0,0061a(mol)
mchất rắn thu được=90,4/100 .a=0,904a(g)
theo (1): nKCl=nKClO3=0,0061a(mol)
=>mKCl=0,0061a.74,5=0,455a(g)
theo (2) : nNa=nNaCl=0,0042a(mol)
=>mNa=0,0042.23=0,096a(mol)
=>%mKCl =0,455a/0,904a .100=50,33(%)
%mNa=0,0966a/0,904a .100=10,68(%)