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a) \(n_{O_2}=\dfrac{2,8}{22,4}=0,125\left(mol\right)\)
PTHH: 2H2 + O2 --to--> 2H2O
____0,25<-0,125
=> mH2 = 0,25.2 = 0,5 (g)
=> mN2 = 4,7 - 0,5 = 4,2 (g)
b)
\(n_{N_2}=\dfrac{4,2}{28}=0,15\left(mol\right)\)
=> \(\overline{M}=\dfrac{4,7}{0,15+0,25}=11,75\left(g/mol\right)\)
=> \(d_{hh/He}=\dfrac{11,75}{4}=2,9375\)
\(m_{Cu}=\dfrac{29,6-4}{2}=12,8(g)\\ \Rightarrow m_{Fe}=12,8+4=16,8(g)\\ PTHH:CuO+H_2\xrightarrow{t^o}Cu+H_2O\\ Fe_3O_4+4H_2\xrightarrow{t^o}3Fe+4H_2O\\ \Rightarrow \Sigma n_{H_2}=n_{Cu}+3n_{Fe}=\dfrac{12,8}{64}+\dfrac{3}{4}.\dfrac{16,8}{56}=0,6(mol)\\ \Rightarrow V_{H_2}=0,6.22,4=13,44(l)\)
Ta có: \(\left\{{}\begin{matrix}m_{Fe}=\dfrac{59,2+8}{2}=33,6\left(g\right)\\m_{Cu}=59,2-33,6=25,6\left(g\right)\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}n_{Fe}=\dfrac{33,6}{56}=0,6\left(mol\right)\\n_{Cu}=\dfrac{25,6}{64}=0,4\left(mol\right)\end{matrix}\right.\)
PTHH:
\(Fe_3O_4+4H_2\xrightarrow[]{t^o}3Fe+4H_2O\)
0,8<----0,3
\(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)
0,4<---0,4
`=> V_{H_2} = (0,4 + 0,8).22,4 = 26,88 (l)`
\(n_{Mg}=\dfrac{4,8}{24}=0,2mol\)
\(2Mg+O_2\rightarrow\left(t^o\right)2MgO\)
0,2 0,1 ( mol )
\(V_{kk}=V_{O_2}.5=0,1.22,4.5=11,2l\)
\(m_{Cu}=12g\Rightarrow n_{Cu}=\dfrac{12}{64}=0,1875mol\)
\(\Rightarrow m_{Fe}=m_{kl}-m_{Cu}=24-12=12g\Rightarrow n_{Fe}=\dfrac{3}{14}mol\)
\(CuO+H_2\rightarrow Cu+H_2O\)
\(\dfrac{12}{64}\) \(\dfrac{12}{64}\)
\(Fe_2O_3+3H_2\rightarrow2Fe+3H_2O\)
\(\dfrac{9}{28}\) \(\dfrac{3}{14}\)
\(\Rightarrow\Sigma n_{H_2}=\dfrac{12}{64}+\dfrac{9}{28}=\dfrac{57}{112}mol\)
\(\Rightarrow V_{H_2}=\dfrac{57}{112}\cdot22,4=11,4l\)
\(M_{hỗn\ hợp} = 4,5.2 = 9\\ Gọi : n_{CH_4} = a(mol) ; n_{H_2} = b(mol)\\ \Rightarrow 16a + 2b =9(a + b)\ (1) n_{O_2} = \dfrac{56}{5.22,4} = 0,5(mol)\\ CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ 2H_2 + O_2 \xrightarrow{t^o} 2H_2O\\ n_{O_2} = 2a + 0,5b = 0,5(2)\\ (1)(2) \Rightarrow a = 0,2 ; b = 0,2\\ \Rightarrow V = (0,2 + 0,2).22,4 = 8,96(lít)\)