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\(CT:Fe_xO_y\)
\(Fe_xO_y+yH_2\underrightarrow{^{t^o}}xFe+yH_2O\left(1\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\left(2\right)\)
\(n_{Fe}=n_{H_2\left(2\right)}=\dfrac{4.032}{22.4}=0.18\left(mol\right)\)
\(n_{H_2\left(1\right)}=\dfrac{y}{x}\cdot n_{Fe}=\dfrac{5.376}{22.4}=0.24\left(mol\right)\)
\(\Leftrightarrow\dfrac{y}{x}\cdot0.18=0.24\)
\(\Leftrightarrow\dfrac{x}{y}=\dfrac{3}{4}\)
\(CT:Fe_3O_4\)
\(m_{Fe_3O_4}=\dfrac{0.18}{3}\cdot232=13.92\left(g\right)\)
PTHH: \(Fe_xO_y+yH_2\underrightarrow{t^o}xFe+yH_2O\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
Đặt \(\left\{{}\begin{matrix}n_{Fe\left(oxit\right)}=a\left(mol\right)=n_{H_2}\\n_{O\left(oxit\right)}=b\left(mol\right)\end{matrix}\right.\)
Ta có: \(m_{tăng}=m_{Fe}-m_{H_2}\) \(\Rightarrow56a-2a=3,24\) \(\Rightarrow a=n_{Fe}=0,06\left(mol\right)\)
Hỗn hợp D gồm \(\left\{{}\begin{matrix}n_{CO_2\left(dư\right)}=c\left(mol\right)\\n_{H_2O}=n_{O\left(oxit\right)}=b\left(mol\right)\end{matrix}\right.\)
Ta có hệ phương trình: \(\left\{{}\begin{matrix}c+b=0,1\\18b+2c=7,4\cdot2\cdot\left(b+c\right)\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}b=0,08\\c=0,02\end{matrix}\right.\)
\(\Rightarrow x:y=a:b=0,06:0,08=3:4\)
\(\Rightarrow\) Công thức cần tìm là Fe3O4
Gọi CT oxit sắt là FexOy
Gọi nCu=a(mol)
nH2=\(\dfrac{6,72}{22,4}\)=0,3(mol)
FexOy+yH2to→xFe+yH2O(1)
Fe+2HCl→FeCl2+H2(2)
Theo pthh(2)
nFe=nH2=0,3(mol)
Theo pthh(1)
nFexOy=\(\dfrac{0,3}{x}\)(mol)
Ta có: 64a+56.0,3=29,6
⇒a=0,2(mol)
⇒mCu=0,2.64=12,8(g)
⇒mFexOy=36−12,8=23,2(g)
=>MFexOy= \(\dfrac{\dfrac{23,2}{0,3}}{x}\)=\(\dfrac{232x}{3}\)
=>56x+16y=\(\dfrac{232x}{3}\)
=>\(\dfrac{64x}{3}=16y\)
->\(\dfrac{x}{y}=\dfrac{3}{4}\)
⇒CTHH:Fe3O4
Ta có :
%m Cu=\(\dfrac{12,8}{36}100\)=35,56%
=>%m Fe3O4=100%-35,56%=64,44%
a) \(n_{Fe}=\dfrac{m_{Fe}}{M_{Fe}}=\dfrac{28}{56}=0,5\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,5-------1---------0,5------0,5
b) \(V_{H_2}=n_{H_2}.22,4=0,5.22,4=11,2\left(l\right)\)
c) \(H_2+CuO\rightarrow Cu+H_2O\)
0,5-----0,5------0,5----0,5
Khối lượng đồng tạo thành: \(m_{Cu}=n_{Cu}.64=0,5.64=32\left(g\right)\)
a) \(n_{Fe}=\dfrac{28}{56}=0,5\left(mol\right)\)
PTHH: `Fe + 2HCl -> FeCl_2 + H_2`
0,5-------------------------->0,5`
b) `V_{H_2} = 0,5.22,4 = 11,2 (l)`
c) PTHH: \(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)
0,5---->0,5
`=> m_{Cu} = 0,5.64 = 32 (g)`
\(Fe+2HCl\underrightarrow{t^o}FeCl_2+H_2\)
\(1mol\) \(1mol\)
\(0,5mol\) \(0,5mol\)
\(n_{Fe}=\dfrac{m}{M}=\dfrac{28}{56}=0,5\left(mol\right)\)
\(V_{H_2}=n.22,4=0,5.22,4=11,2\left(l\right)\)
\(H_2+CuO\underrightarrow{t^o}Cu+H_2O\)
\(1mol\) \(1mol\)
\(0,5mol\) \(0,5mol\)
\(m_{Cu}=n.M=0,5.64=32\left(g\right)\)
\(n_{H_2}=\dfrac{8.96}{22.4}=0.4\left(mol\right)\)
\(BTKL:\)
\(m+0.4\cdot2=28.4+7.2\)
\(\Rightarrow m=34.8\left(g\right)\)
\(b.\)
\(m_{Fe}=0.59155\cdot28.4=16.8\left(g\right)\)
\(n_{Fe}=\dfrac{16.8}{56}=0.3\left(mol\right)\)
\(PTHH:\)
\(\dfrac{x}{y}=\dfrac{n_{Fe}}{n_{H_2}}=\dfrac{0.3}{0.4}=\dfrac{3}{4}\)
\(CT:Fe_3O_4\)
- Cho phản ứng xảy ra hoàn toàn (2 chất trong A có sắt và oxit khác oxit sắt ban đầu)
\(yH_2+Fe_xO_y\rightarrow\left(t^o\right)xFe+yH_2O\left(1\right)\\ Fe+2HCl\rightarrow FeCl_2+H_2\left(2\right)\\ n_{H_2\left(2\right)}=n_{Fe\left(2\right)}=n_{Fe\left(1\right)}=0,3\left(mol\right)\\ n_{O\left(trong.oxit\right)}=n_{H_2O}=n_{H_2}=0,4\left(mol\right)\\ BTKL:m_{H_2}+m_{oxit}=m_A+m_{H_2O}\\ \Leftrightarrow0,4.2+m=28,4+18.0,4\\ \Leftrightarrow m=34,8\left(g\right)\\ b,x:y=0,3:0,4=3:4\Rightarrow x=3;y=4\\ \Rightarrow CTHH:Fe_3O_4\)
\(Fe_xO_y\)
\(n_{Fe_2O_n}=\dfrac{34,8}{56x+16n}\)
\(Fe_xO_y+yH_2\rightarrow\left(t^o\right)xFe+yH_2O\)
\(\dfrac{34,8}{56x+16y}\) -----> \(\dfrac{34,8x}{56x+16y}\) ( mol )
\(n_{H_2}=\dfrac{10,08}{22,4}=0,45mol\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,45 0,45 ( mol )
Ta có:
\(\dfrac{34,8x}{56x+16y}=0,45\)
\(\Leftrightarrow34,8x=25,2x+7,2y\)
\(\Leftrightarrow x=0,75y\)
\(\Leftrightarrow4x=3y\)
\(\Leftrightarrow x=3;y=4\)
\(\Rightarrow CTHH:Fe_3O_4\)