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Ta có nNa2SO3 = \(\dfrac{12,6}{126}\)=0,1 (mol)
PTHH : Na2SO3 + H2SO4 →Na2SO4 + H2O + SO2
Ta có nNa2SO3 =nSO2 = 0,1 mol
nCa(OH)2 = 1,5.0,1 = 0,15 mol
Xét T = \(\dfrac{n_{SO2}}{n_{Ca\left(OH\right)2}}\) = \(\dfrac{0,1}{0,15}\)< 1 : Tạo ra muối: CaSO3↓
pt: SO2 + Ca(OH)2 --> CaSO3↓ + H2O
Ta có nSO2= nCaSO3 = 0,1 mol
=> mCaSO3= 0,1. 120=12(g)
a, \(Na_2SO_3+H_2SO_4\rightarrow Na_2SO_4+SO_2+H_2O\)
\(K_2SO_3+H_2SO_4\rightarrow K_2SO_4+SO_2+H_2O\)
Ta có: \(n_{SO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{SO_2}=0,3\left(mol\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,3.98}{20\%}=147\left(g\right)\)
b, Ta có: 126nNa2SO3 + 158nK2SO3 = 44,2 (1)
Theo PT: \(n_{SO_2}=n_{Na_2SO_3}+n_{K_2SO_3}=0,3\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Na_2SO_3}=0,1\left(mol\right)\\n_{K_2SO_3}=0,2\left(mol\right)\end{matrix}\right.\)
Có: m dd sau pư = 44,2 + 147 - 0,3.64 = 172 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{Na_2SO_3}=\dfrac{0,1.126}{172}.100\%\approx7,33\%\\C\%_{K_2SO_3}=\dfrac{0,2.158}{172}.100\%\approx18,37\%\end{matrix}\right.\)
c, \(n_{Ba\left(OH\right)_2}=0,5.1=0,5\left(mol\right)\)
\(\Rightarrow\dfrac{n_{SO_2}}{n_{Ba\left(OH\right)_2}}=0,6< 1\) → Pư tạo BaSO3.
PT: \(SO_2+Ba\left(OH\right)_2\rightarrow BaSO_3+H_2O\)
\(n_{BaSO_3}=n_{SO_2}=0,3\left(mol\right)\Rightarrow m_{BaSO_3}=0,3.217=65,1\left(g\right)\)
a, PT: \(Na_2SO_3+2HCl\rightarrow2NaCl+SO_2+H_2O\)
Ta có: \(n_{Na_2SO_3}=\dfrac{12,6}{126}=0,1\left(mol\right)\)
Theo PT: \(n_{SO_2}=n_{Na_2SO_3}=0,1\left(mol\right)\)
\(\Rightarrow V_{SO_2}=0,1.22,4=2,24\left(l\right)\)
b, Theo PT: \(n_{NaCl}=n_{HCl}=2n_{Na_2SO_3}=0,2\left(mol\right)\)
\(\Rightarrow m_{NaCl}=0,2.58,5=11,7\left(g\right)\)
c, \(m_{HCl}=0,2.36,5=7,3\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{7,3}{10\%}=73\left(g\right)\)
d, Ta có: m dd sau pư = 12,6 + 73 - 0,1.64 = 79,2 (g)
\(\Rightarrow C\%_{NaCl}=\dfrac{11,7}{79,2}.100\%\approx14,77\%\)
\(n_{C_2H_4}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\\ C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\\ a,n_{O_2}=3.0,5=1,5\left(mol\right)\\ V_{O_2\left(đktc\right)}=1,5.22,4=33,6\left(l\right)\\ V_{kk\left(đktc\right)}=33,6.5=168\left(l\right)\\ b,n_{CO_2}=n_{H_2O}=2.0,5=1\left(mol\right)\\ m_{CO_2}=44.1=44\left(g\right);m_{H_2O}=18.1=18\left(g\right)\\ c,CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\\ n_{Ca\left(OH\right)_2}=n_{CO_2}=1\left(mol\right)\\ m_{Ca\left(OH\right)_2}=1.74=74\left(g\right)\\ m_{ddCa\left(OH\right)_2}=\dfrac{74.100}{10}=740\left(g\right)\)
\(a,MgCO_3\rightarrow\left(t^o\right)MgO+CO_2\\ Na_2O+H_2O\rightarrow2NaOH\\ CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\\ n_{CO_2}=n_{MgO}=n_{MgCO_3}=\dfrac{84}{84}=1\left(mol\right);n_{NaOH}=2.n_{Na_2O}=2.\dfrac{4,65}{62}=0,15\left(mol\right)\\ Vì:\dfrac{0,15}{2}>\dfrac{1}{1}\Rightarrow CO_2dư\\ n_{Na_2CO_3}=\dfrac{0,15}{2}=0,075\left(mol\right)\Rightarrow m_{Na_2CO_3}=106.0,075=7,95\left(g\right)\\ m_{CO_2\left(dư\right)}=\left(1-\dfrac{0,15}{2}\right).44=40,7\left(g\right)\\ m_{MgO}=40.1=40\left(g\right)\\ b,n_{CO_2}=0,1\left(mol\right)\\ Có:1< \dfrac{0,15}{0,1}=1,5< 2\\ \Rightarrow SP:n_{Na_2CO_3}=n_{NaHCO_3}=\dfrac{0,1}{2}=0,05\left(mol\right)\\ m_{muối}=0,05.\left(106+84\right)=9,5\left(g\right)\)
mKOH=28(g)
nKOH=0.5(mol)
PTHH:2KOH+H2SO4->K2SO4+2H2O
a)Theo pthh:nH2SO4=1/2 nKOH->nH2SO4=0.25(mol)
mH2SO4=0.25*98=24.5(g)
C%ddH2SO4=24.5/100*100=24.5%
theo pthh:nK2SO4=nH2SO4->nK2SO4=0.25(mol)
mK2SO4=0.25*(39*2+96)=43.5(g)
c)mdd sau phản ứng:200+100=300(g)
d) C% muối=43.5:300*100=14.5%
\(a,n_{Na_2SO_3}=\dfrac{12,6}{126}=0,1mol\\ Na_2SO_3+2HCl\rightarrow2NaCl+SO_2+H_2O\\ n_{SO_2}=n_{Na_2SO_4}=0,1mol\\ V_{SO_2}=0,1.22,4=2,24l\\ b,n_{HCl}=0,1.2=0,2mol\\ C_{M_{HCl}}=\dfrac{0,2}{0,15}=\dfrac{4}{3}M\\ c,n_{NaOH}=\dfrac{40.10}{100.40}=0,1mol\\ T=\dfrac{0,1}{0,1}=1\\ \Rightarrow Tạo,NaHSO_3\\ NaOH+SO_2\rightarrow NaHSO_3\\ m_{NaHSO_3}=0,1.64+0,1.40=10,4g\)
Ta có nNa2SO3 = 12,6/126=0,1 (mol)
PTHH : Na2SO3 + H2SO4 \(\rightarrow\)Na2SO4 + H2O + SO2
Ta có nNa2SO3 =nSO2 = 0,1 mol
Nếu a ≤ 1 : Tạo ra muối: CaSO3↓
pt: SO2 + Ca(OH)2 --> CaSO3↓ + H2O
Ta có nSO2=nCaSO3 = 0,1 mol
=> mCaSO3= 0,1. 120=12(g)