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a, PT: \(Na_2SO_3+2HCl\rightarrow2NaCl+SO_2+H_2O\)
Ta có: \(n_{Na_2SO_3}=\dfrac{12,6}{126}=0,1\left(mol\right)\)
Theo PT: \(n_{SO_2}=n_{Na_2SO_3}=0,1\left(mol\right)\)
\(\Rightarrow V_{SO_2}=0,1.22,4=2,24\left(l\right)\)
b, Theo PT: \(n_{NaCl}=n_{HCl}=2n_{Na_2SO_3}=0,2\left(mol\right)\)
\(\Rightarrow m_{NaCl}=0,2.58,5=11,7\left(g\right)\)
c, \(m_{HCl}=0,2.36,5=7,3\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{7,3}{10\%}=73\left(g\right)\)
d, Ta có: m dd sau pư = 12,6 + 73 - 0,1.64 = 79,2 (g)
\(\Rightarrow C\%_{NaCl}=\dfrac{11,7}{79,2}.100\%\approx14,77\%\)
\(n_{C_2H_4}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\\ C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\\ a,n_{O_2}=3.0,5=1,5\left(mol\right)\\ V_{O_2\left(đktc\right)}=1,5.22,4=33,6\left(l\right)\\ V_{kk\left(đktc\right)}=33,6.5=168\left(l\right)\\ b,n_{CO_2}=n_{H_2O}=2.0,5=1\left(mol\right)\\ m_{CO_2}=44.1=44\left(g\right);m_{H_2O}=18.1=18\left(g\right)\\ c,CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\\ n_{Ca\left(OH\right)_2}=n_{CO_2}=1\left(mol\right)\\ m_{Ca\left(OH\right)_2}=1.74=74\left(g\right)\\ m_{ddCa\left(OH\right)_2}=\dfrac{74.100}{10}=740\left(g\right)\)
Ta có nNa2SO3 = 12,6/126=0,1 (mol)
PTHH : Na2SO3 + H2SO4 \(\rightarrow\)Na2SO4 + H2O + SO2
Ta có nNa2SO3 =nSO2 = 0,1 mol
Nếu a ≤ 1 : Tạo ra muối: CaSO3↓
pt: SO2 + Ca(OH)2 --> CaSO3↓ + H2O
Ta có nSO2=nCaSO3 = 0,1 mol
=> mCaSO3= 0,1. 120=12(g)
a, \(Na_2SO_3+H_2SO_4\rightarrow Na_2SO_4+SO_2+H_2O\)
\(K_2SO_3+H_2SO_4\rightarrow K_2SO_4+SO_2+H_2O\)
Ta có: \(n_{SO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{SO_2}=0,3\left(mol\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,3.98}{20\%}=147\left(g\right)\)
b, Ta có: 126nNa2SO3 + 158nK2SO3 = 44,2 (1)
Theo PT: \(n_{SO_2}=n_{Na_2SO_3}+n_{K_2SO_3}=0,3\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Na_2SO_3}=0,1\left(mol\right)\\n_{K_2SO_3}=0,2\left(mol\right)\end{matrix}\right.\)
Có: m dd sau pư = 44,2 + 147 - 0,3.64 = 172 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{Na_2SO_3}=\dfrac{0,1.126}{172}.100\%\approx7,33\%\\C\%_{K_2SO_3}=\dfrac{0,2.158}{172}.100\%\approx18,37\%\end{matrix}\right.\)
c, \(n_{Ba\left(OH\right)_2}=0,5.1=0,5\left(mol\right)\)
\(\Rightarrow\dfrac{n_{SO_2}}{n_{Ba\left(OH\right)_2}}=0,6< 1\) → Pư tạo BaSO3.
PT: \(SO_2+Ba\left(OH\right)_2\rightarrow BaSO_3+H_2O\)
\(n_{BaSO_3}=n_{SO_2}=0,3\left(mol\right)\Rightarrow m_{BaSO_3}=0,3.217=65,1\left(g\right)\)
\(n_{Ca\left(OH\right)_2}=0,3.1=0,3\left(mol\right)\\ n_{HCl}=0,2.0,2=0,04\left(mol\right)\)
a
\(Ca\left(OH\right)_2+2HCl\rightarrow CaCl_2+2H_2O\)
0,02<------0,04----->0,02
Xét \(\dfrac{0,3}{1}>\dfrac{0,04}{2}\Rightarrow Ca\left(OH\right)_2.dư\)
\(m_{CaCl_2}=0,02.111=2,22\left(g\right)\)
b
Muốn pứ xảy ra hoàn toàn phải thêm dung dịch HCl 0,2 M
\(n_{HCl.cần}=2n_{Ca\left(OH\right)_2}=0,3.2=0,6\left(mol\right)\\ n_{HCl.cần.thêm}=0,6-0,04=0,56\left(mol\right)\)
\(V_{cần.\left(HCl\right)}=\dfrac{0,56}{0,2}=2,8\left(l\right)=280\left(ml\right)\\ V_{cần.thêm\left(HCl\right)}=280-200=80\left(ml\right)\)
c
\(CM_{CaCl_2}=\dfrac{0,02}{0,3+0,28}=\dfrac{1}{29}M\)
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
a) PTHH : \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Theo Pt : \(n_{Fe}=n_{H2SO4}=n_{FeSO4}=n_{H2}=0,2\left(mol\right)\)
b) \(V_{H2\left(dktc\right)}=0,2.22,4=4,48\left(l\right)\)
c) \(C_{MddH2SO4}=\dfrac{0,2}{0,2}=1\left(M\right)\)
d) \(m_{muối}=m_{FeSO4}=0,2.152=30,4\left(g\right)\)
Ta có nNa2SO3 = \(\dfrac{12,6}{126}\)=0,1 (mol)
PTHH : Na2SO3 + H2SO4 →Na2SO4 + H2O + SO2
Ta có nNa2SO3 =nSO2 = 0,1 mol
nCa(OH)2 = 1,5.0,1 = 0,15 mol
Xét T = \(\dfrac{n_{SO2}}{n_{Ca\left(OH\right)2}}\) = \(\dfrac{0,1}{0,15}\)< 1 : Tạo ra muối: CaSO3↓
pt: SO2 + Ca(OH)2 --> CaSO3↓ + H2O
Ta có nSO2= nCaSO3 = 0,1 mol
=> mCaSO3= 0,1. 120=12(g)
Mếch cô thảo