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\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ n_O=\dfrac{11,6-0,15}{16}=0,2\left(mol\right)\)
CTHH: FexOy
\(\rightarrow x:y=n_{Fe}:n_O=0,15:0,2=3:4\)
CTHH: Fe3O4
PTHH: Fe3O4 + 4H2 --to--> 3Fe + 4H2O
0,2 0,15
=> VH2 = 0,2.22,4 = 4,48 (l)
\(n_{Fe}=\dfrac{8,4}{56}=0,15mol\)
\(n_{Fe_xO_y}=\dfrac{11,6}{56x+16y}\) mol
\(Fe_xO_y+yH_2\rightarrow\left(t^p\right)xFe+yH_2O\)
\(\dfrac{11,6}{56x+16y}\) \(\dfrac{11,6x}{56x+16y}\) ( mol )
\(\Rightarrow\dfrac{11,6x}{56x+16y}=0,15\)
\(\Leftrightarrow11,6x=8,4x+2,4y\)
\(\Leftrightarrow3,2x=2,4y\)
\(\Leftrightarrow4x=3y\)
\(\Leftrightarrow x=3;y=4\)
\(\Rightarrow CTHH:Fe_3O_4\)
\(\Rightarrow n_{H_2}=0,15.4:3=0,2mol\)
\(V_{H_2}=0,2.22,4=4,48l\)
a) \(n_O=\dfrac{34,8-25,2}{16}=0,6\left(mol\right)\)
=> \(n_{H_2O}=0,6\left(mol\right)\) (bảo toàn O)
=> \(n_{H_2}=0,6\left(mol\right)\) (bảo toàn H)
=> \(V_{H_2}=0,6.22,4=13,44\left(l\right)\)
b) \(n_{Fe}=\dfrac{25,2}{56}=0,45\left(mol\right)\)
nFe : nO = 0,45 : 0,6 = 3 : 4
=> CTHH: Fe3O4
c) \(m_{H_2O}=0,6.18=10,8\left(g\right)\)
Mà \(d_{H_2O}=1\left(g/ml\right)\)
=> \(V_{H_2O}=10,8\left(ml\right)\)
CTHH: FexOy
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: FexOy + yH2 --to--> xFe + yH2O
\(\dfrac{0,2}{x}\)<---------------0,2
Fe + 2HCl --> FeCl2 + H2
0,2<-------------------0,2
=> \(M_{Fe_xO_y}=56x+16y=\dfrac{16}{\dfrac{0,2}{x}}=80x\)
=> \(\dfrac{x}{y}=\dfrac{2}{3}\) => CTHH: Fe2O3
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
PTHH: Fe2O3 + 3H2 --to--> 2Fe + 3H2O
0,1 0,3 0,2
\(V_{H_2}=0,3.22,4=6,72\left(l\right)\)
\(n_{O_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH: 3Fe + 2O2 --to--> Fe3O4
LTL: \(\dfrac{0,2}{3}>\dfrac{0,1}{2}\rightarrow\) Fe dư
Theo pthh: \(n_{Fe\left(pư\right)}=\dfrac{3}{2}n_{O_2}=\dfrac{3}{2}.0,1=0,15\left(mol\right)\)
\(\rightarrow m_{Fe\left(dư\right)}=\left(0,2-0,15\right).56=2,8\left(g\right)\)
a.\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1mol\)
\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
0,1 0,3 0,2 ( mol )
\(V_{H_2}=0,3.22,4=6,72l\)
b.\(n_{O_2}=\dfrac{2,24}{22,4}=0,1mol\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
\(\dfrac{0,2}{3}\) > \(\dfrac{0,1}{2}\) ( mol )
0,15 0,1 ( mol )
Chất dư là Fe
\(m_{Fe\left(dư\right)}=\left(0,2-0,15\right).56=2,8g\)
\(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right);n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\\ a,PTHH:3H_2+Fe_2O_3\rightarrow\left(t^o\right)2Fe+3H_2O\\ b,Vì:\dfrac{0,4}{3}>\dfrac{0,1}{1}\Rightarrow H_2dư\\ n_{H_2\left(dư\right)}=0,4-3.0,1=0,1\left(mol\right)\\ c,Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\\ n_{FeCl_3}=2.0,1=0,2\left(mol\right)\\ m=m_{FeCl_3}=0,2.162,5=32,5\left(g\right)\)
mgiảm = mO(oxit) = 4.8 (g)
nO = 4.8/16 = 0.3 (mol)
nFexOy = 0.3/y (mol)
MFexOy = 16/0.3/y = 160y/3 (g/mol)
=> 56x + 16y = 160y/3
=> 56x = 112y/3
=> x / y = 2 / 3
CT : Fe2O3
nFe = 16,8 : 56 = 0,3 (mol)
pthh :3 Fe + 2O2 -t--> Fe3O4
0,3--------------> 0,1 (mol)
=> mFe3O4 =0,1 . 232 = 23,2(G)
nH2 = 44,8 : 22,4 = 2 (g)
pthh : Fe3O4 + H2 -t--> Fe + H2O
LTL : 0,1 / 1 < 2 /1
=> H2 du
nH2 (pu) = nFe3O4 = 0,1 (mol)
=> nH2 (d) = 2-0,1 = 1,9 (mol)
mH2 (d) = 1,9 . 2 = 3,8 (g)
\(CT:Fe_xO_y\)
\(Fe_xO_y+yH_2\underrightarrow{^{t^o}}xFe+yH_2O\left(1\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\left(2\right)\)
\(n_{Fe}=n_{H_2\left(2\right)}=\dfrac{4.032}{22.4}=0.18\left(mol\right)\)
\(n_{H_2\left(1\right)}=\dfrac{y}{x}\cdot n_{Fe}=\dfrac{5.376}{22.4}=0.24\left(mol\right)\)
\(\Leftrightarrow\dfrac{y}{x}\cdot0.18=0.24\)
\(\Leftrightarrow\dfrac{x}{y}=\dfrac{3}{4}\)
\(CT:Fe_3O_4\)
\(m_{Fe_3O_4}=\dfrac{0.18}{3}\cdot232=13.92\left(g\right)\)
Ta có: \(n_{H_2}=\dfrac{7,392}{22,4}=0,33\left(mol\right)\)
Gọi: nH2 (pư) = a (mol) ⇒ nH2 (dư) = 10%a (mol)
⇒ a + 10%a = 0,33
⇒ a = 0,3 (mol)
Có: \(H_2+O_{\left(trongoxit\right)}\rightarrow H_2O\)
⇒ nO (trong oxit) = 0,3 (mol)
\(\Rightarrow n_{Fe}=\dfrac{16-m_{O\left(trongoxit\right)}}{56}=0,2\left(mol\right)\)
\(\Rightarrow\dfrac{x}{y}=\dfrac{0,2}{0,3}=\dfrac{2}{3}\)
Vậy: CTHH cần tìm là Fe2O3.