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Ta có:
n H2 = 0,05 ( mol )
1.PTHH
Fe + H2SO4 ====> FeSO4 + H2
FeO + H2SO4 ====> FeSO4 + H2O
theo pthh: n Fe = n H2 = 0,05 ( mol )
=> m Fe = 2,8 ( g )
=> m FeO = 7,2 ( g ) => n FeO = 0,1 ( mol )
2.
theo pthh: n H2SO4 = 0,05 + 0,1 = 0,15
=> m H2SO4 = 14,7 ( g )
=> m dd H2SO4 9,8% = 150 ( g )
\(n_{H2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
Pt : \(Fe+H_2SO_4\rightarrow FeSO_4+H_2|\)
1 1 1 1
0,05 0,05 0,05 0,05
\(FeO+H_2SO_4\rightarrow FeSO_4+H_2O|\)
1 1 1 1
0,1 0,1 0,1
1) \(n_{Fe}=\dfrac{0,05.1}{1}=0,05\left(mol\right)\)
\(m_{Fe}=0,05.56=2,8\left(g\right)\)
\(m_{FeO}=10-2,8=7,2\left(g\right)\)
2) Có : \(m_{FeO}=7,2\left(g\right)\)
\(n_{FeO}=\dfrac{7,2}{72}=0,1\left(mol\right)\)
\(n_{H2SO4\left(tổng\right)}=0,05+0,1=0,15\left(mol\right)\)
\(m_{H2SO4}=0,15.98=14,7\left(g\right)\)
\(m_{ddH2SO4}=\dfrac{14,7.100}{9,8}=150\left(g\right)\)
3) \(n_{FeSO4\left(tổng\right)}=0,05+0,1=0,15\left(mol\right)\)
⇒ \(m_{FeSO4}=0,15.152=22,8\left(g\right)\)
\(m_{ddspu}=10+150-\left(0,05.2\right)=159,9\left(g\right)\)
\(C_{FeSO4}=\dfrac{22,8.100}{159,9}=14,26\)0/0
Chúc bạn học tốt
a, \(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{FeCl_2}=n_{H_2}=0,3\left(mol\right)\Rightarrow m_{Fe}=0,3.56=16,8\left(g\right)\)
b, \(n_{HCl}=2n_{H_2}=0,6\left(mol\right)\Rightarrow C_{M_{HCl}}=\dfrac{0,6}{0,15}=4\left(M\right)\)
c, \(FeCl_2+2NaOH\rightarrow2NaCl+Fe\left(OH\right)_2\)
Theo PT: \(n_{NaOH}=2n_{FeCl_2}=0,6\left(mol\right)\)
\(\Rightarrow V_{NaOH}=\dfrac{0,6}{1}=0,6\left(l\right)=600\left(ml\right)\)
\(a.Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe,pư}=n_{FeCl_2}=n_{H_2}=\dfrac{6,72}{22,4}=0,3mol\\ m_{Fe,pư}=0,3.56=16,8g\\ b.n_{HCl}=0,3.2=0,6mol\\ C_{M_{HCl}}=\dfrac{0,6}{0,15}=4M\\ c.2NaOH+FeCl_2\rightarrow Fe\left(OH\right)_2+2NaCl\\ n_{NaOH}=0,3.2=0,6mol\\ V_{ddNaOH}=\dfrac{0,6}{1}=0,6l=600ml\)
a, Ta có: 27nAl + 56nFe = 0,83 (1)
PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}+n_{Fe}=\dfrac{0,56}{22,4}=0,025\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow n_{Al}=n_{Fe}=0,01\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,01.27}{0,83}.100\%\approx32,53\%\\\%m_{Fe}\approx67,47\%\end{matrix}\right.\)
b, nH2SO4 = nH2 = 0,025 (mol)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,025.98}{20\%}=12,25\left(g\right)\)
Bài 7:
a) PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
b) Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)=n_{Zn\left(pư\right)}\)
\(\Rightarrow m_{Zn\left(pư\right)}=0,2\cdot65=13\left(g\right)\)
c) Theo PTHH: \(n_{HCl}=2n_{H_2}=0,4mol\) \(\Rightarrow C_{M_{HCl}}=\dfrac{0,4}{0,2}=2\left(M\right)\)
(Coi như thể tích dd thay đổi không đáng kể)
PTHH: \(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3\downarrow+H_2O\)
Gộp cả phần a và b
Ta có: \(n_{CO_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)=n_{Ca\left(OH\right)_2}=n_{CaCO_3}\)
\(\Rightarrow\left\{{}\begin{matrix}C_{M_{Ca\left(OH\right)_2}}=\dfrac{0,05}{0,1}=0,5\left(M\right)\\m_{CaCO_3}=0,05\cdot100=5\left(g\right)\end{matrix}\right.\)
Tóm tắt
\(V_{H_2\left(đktc\right)}=8,96l\\ C_{\%H_2SO_4}=19,6\%\\ a)m_{Zn}=?\\ m_{ddH_2SO_4}=?\\ b)C_{\%ZnSO_4}=?\)
\(a)n_{H_2}=\dfrac{8,96}{22,4}=0,4mol\\ Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
0,4 0,4 0,4 0,4
\(m_{Zn}=0,4.65=26g\\ m_{ddH_2SO_4}=\dfrac{0,4.98}{19,6}\cdot100=200g\\ b)C_{\%ZnSO_4}=\dfrac{0,4.161}{26+200-0,4.2}\cdot100=28,6\%\)
Ta có: \(n_{Fe}=\dfrac{0,56}{56}=0,01\left(mol\right)\)
\(PTHH:H_2SO_4+Fe--->FeSO_4+H_2\)
a. Theo PT: \(n_{H_2SO_4}=n_{FeSO_4}=n_{H_2}=n_{Fe}=0,01\left(mol\right)\)
\(\Rightarrow m_{FeSO_4}=0,01.152=1,52\left(g\right)\)
\(V_{H_2}=0,01.22,4=0,224\left(lít\right)\)
b. Ta có: \(m_{H_2SO_4}=0,01.98=0,98\left(g\right)\)
Ta lại có: \(C_{\%_{H_2SO_4}}=\dfrac{0,98}{m_{dd_{H_2SO_4}}}.100\%=19,6\%\)
\(\Rightarrow m_{dd_{H_2SO_4}}=5\left(g\right)\)
\(a,n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(PTHH:Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ ..........0,15.......0,15.......0,15.......0,15\left(mol\right)\)
\(m_{Zn}=65\cdot0,15=9,75\left(g\right)\)
\(b,m_{H_2SO_4}=98\cdot0,15=14,7\left(mol\right)\\ c,m_{dd_{H_2SO_4}}=\dfrac{14,7\cdot100}{20}=\dfrac{147}{2}\left(g\right)\\ d,C\%_{dd_{ZnSO_4}}=\dfrac{0,15\cdot161}{\dfrac{147}{2}}\cdot100\approx32,86\%\)
nFe = 11.2/56 = 0.2 (mol)
Fe + H2SO4 => FeSO4 + H2
0.2____0.2_______0.2___0.2
mH2SO4 = 0.2*98 = 19.6 (g)
mdd H2SO4 = 19.6*100/10 = 196 (g)
m dd sau phản ứng = 11.2 + 196 - 0.4 = 206.8 (g)
mFeSO4 = 0.2*152 = 30.4 (g)
C% FeSO4 = 30.4/206.8 * 100% = 14.7%
Vdd H2SO4 = mdd H2SO4 / D = 196 / 1.14 = 171.9 (ml)
CM FeSO4 = 0.2 / 0.1719 = 1.16 M