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a)
n Al = 10,8/27 = 0,4(mol)
2Al + 6HCl → 2AlCl3 + 3H2
n H2 = \(\dfrac{3}{2}\)n Al = 0,6(mol)
=> V H2 = 0,6.22,4 = 13,44(lít)
b) n AlCl3 = n Al = 0,4(mol)
=> m AlCl3 = 0,4.133,5 = 53,4(gam)
c) n CuO = 16/80 = 0,2(mol)
CuO + H2 \(\xrightarrow{t^o}\) Cu + H2O
n CuO = 0,2 < n H2 = 0,6 => H2 dư
n H2 pư = n Cu = n CuO = 0,2 mol
Suy ra:
m H2 dư = (0,6 -0,2).2 = 0,8(gam)
m Cu = 0,2.64 = 12,8(gam)
a) nAl=0,4(mol)
PTHH: 2Al + 6HCl -> 2AlCl3 + 3H2
nH2= 3/2 . nAl=3/2 . 0,4=0,6(mol)
=>V(H2,đktc)=0,6 x 22,4= 13,44(l)
b) nAlCl3= nAl=0,4(mol)
=>mAlCl3=133,5 x 0,4= 53,4(g)
c) nCuO=0,2(mol)
PTHH: CuO + H2 -to-> Cu + H2O
Ta có: 0,2/1 < 0,6/1
=> H2 dư, CuO hết, tính theo nCuO
=> nH2(p.ứ)=nCu=nCuO=0,2(mol)
=>nH2(dư)=0,6 - 0,2=0,4(mol)
=> mH2(dư)=0,4. 2=0,8(g)
mCu=0,2.64=12,4(g)
\(n_{Al} = \dfrac{2,7}{27} = 0,1(mol)\\ 2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2\\ n_{H_2} = \dfrac{3}{2}n_{Al} = 0,15(mol)\\ \Rightarrow V_{H_2} = 0,15.22,4 = 3,36(lít)\\ n_{HCl} = \dfrac{8,1}{36,5} = \dfrac{81}{365}(mol)\\ 2Al + 6HCl \to 2AlCl_3 + 3H_2\\ \dfrac{n_{Al}}{2} = 0,05 > \dfrac{n_{HCl}}{6} = \dfrac{27}{730} \to Al\ dư\\ n_{Al\ pư} = \dfrac{1}{3}n_{HCl} = \dfrac{27}{365}(mol)\\ \)
\(m_{Al\ dư} = 2,7 - \dfrac{27}{265}.27 = 0,703(gam)\)
a) PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
Ta có: \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\) \(\Rightarrow n_{HCl}=0,8\left(mol\right)\) \(\Rightarrow V_{HCl}=\dfrac{0,8}{2}=0,4\left(l\right)\)
b) PTHH: \(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{H_2}=0,4\left(mol\right)\\n_{CuO}=\dfrac{24}{80}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Hidro còn dư, CuO p/ứ hết
\(\Rightarrow n_{Cu}=0,3\left(mol\right)\) \(\Rightarrow m_{Cu}=0,3\cdot64=19,2\left(g\right)\)
a)\(n_{Mg}=\dfrac{35,6}{24}=1,483\left(mol\right)\)
\(V_{O2\left(đktc\right)}=\dfrac{21,504}{22,4}=0,96\left(mol\right)\)
pt: 2Mg + O2 → 2MgO (1)
mol: 2 1 2
mol:1,483 0,96
Tỉ lệ: \(\dfrac{1,483}{2}=0,7415< \dfrac{0,96}{1}=0,96\)
Mg tác dụng hết. O2 dư
theo PTHH có
\(n_{O2p\intư}=\dfrac{1,843x1}{2}=0,7415\left(mol\right)\)
nO2 dư=1,843-0,7415=1,1015 (mol)
mO2dư= 1,1015 x 32 = 35,48 (g)
b)theo PTHH có
\(n_{MgO}=\dfrac{1,843x2}{2}=1,843\left(mol\right)\)
nMgO = 1,843 X 40 = 73,72 (g)
c)
nMg PT(1)=nMgPT(2)=1,843 (mol)
pt: Mg + H2SO4 ➝ MgSO4 + H2 (2)
mol: 1 1 1 1
mol: 1,843
Theo PTHH có
\(n_{H2}=\dfrac{1,843x1}{1}=1,843\) (mol)
mH2=1,843 x 2 = 3,686 (g)
\(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\\
pthh:Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
0,1 0,1 0,1
\(m_{MgSO_4}=120.0,1=12\left(g\right)\\
n_{CuO}=\dfrac{48}{80}=0,6\left(mol\right)\\
pthh:CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
\(LTL:\dfrac{0,6}{1}>\dfrac{0,1}{1}\)
=> CuO dư
\(n_{CuO\left(P\text{Ư}\right)}=n_{H_2}=0,1\left(mol\right)\\
m_{CuO\left(d\right)}=\left(0,6-0,1\right).80=40\left(g\right)\)
nMg=2,424=0,1(mol)pthh:Mg+H2SO4→MgSO4+H2nMg=2,424=0,1(mol)pthh:Mg+H2SO4→MgSO4+H2
0,1 0,1 0,1
mMgSO4=120.0,1=12(g)nCuO=4880=0,6(mol)pthh:CuO+H2to→Cu+H2OmMgSO4=120.0,1=12(g)nCuO=4880=0,6(mol)pthh:CuO+H2to→Cu+H2O
a) mHCl = 14,6% . 200 = 29,2 ( g )
⇒ nHCl = \(\dfrac{m}{M}\) = \(\dfrac{29,2}{36,5}\) = 0,8 ( mol )
PTHH : Zn + 2HCl → ZnCl2 + H2
0,4 0,8 0,4 0,2 ( mol )
Theo pt : nH2 = 0,4 mol
⇒ VH2(đktc) = nH2 . 22.4 = 0,4 . 22,4 = 8,96 ( l )
b) Theo pt : mZn = n.M = 0,4 . 65 = 26 ( g )
c) mH2 = n.M = 0,4 . 2 = 0,8 ( g )
Theo pt : mZnCl2 = n.M = 0,4 . 136 = 54,4 ( g )
⇒ mdd(sau) = 200 + 26 - 0,8 = 225,2 ( g )
⇒ C%ZnCl2 = \(\dfrac{54,4}{225,2}\) . 100% ≃ 24,16%
\(a) Zn + H_2SO_4 \to ZnSO_4 + H_2\\ n_{Zn} = \dfrac{13}{65} = 0,2 < n_{H_2SO_4} = \dfrac{200.24,5\%}{98} = 0,5 \to H_2SO_4\ dư\\ n_{H_2SO_4\ pư} =n_{Zn} = 0,2(mol)\\ \Rightarrow m_{H_2SO_4\ dư} = (0,5 - 0,2).98 = 29,4(gam)\\ c) n_{FeSO_4} = n_{H_2} = n_{Zn} = 0,2(mol)\\ m_{FeSO_4} = 0,2.152 = 30,4(gam)\\ V_{H_2} = 0,2.22,4 = 4,48(lít)\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\\ n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\\ n_{H_2}=n_{MgCl_2}=n_{Mg}=0,1\left(mol\right)\\ a,V_{H_2\left(đktc\right)}=0,1.22,4=2,24\left(l\right)\\ b,m_{MgCl_2}=95.0,1=9,5\left(g\right)\\ c,m_{ddMgCl_2}=m_{Mg}+m_{ddHCl}-m_{H_2}=2,4+200-0,1.2=202,2\left(g\right)\\ C\%_{ddMgCl_2}=\dfrac{9,5}{202,2}.100\approx4,698\%\\ d,n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\\ PTHH:H_2+CuO\rightarrow\left(t^o\right)Cu+H_2O\\ Vì:\dfrac{0,2}{1}>\dfrac{0,1}{1}\Rightarrow CuOdư\\ n_{CuO\left(dư\right)}=0,2-0,1.1=0,1\left(mol\right)\\ m_{CuO\left(dư\right)}=0,1.80=8\left(g\right)\)