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Đặt \(\hept{\begin{cases}a\left(mol\right)=n_{H_2}=n_{O_2\left(A\right)}\\2b\left(mol\right)=n_{Cl_2}\\3b\left(mol\right)=n_{O_2\left(B\right)}\end{cases}}\)
\(\overline{M_A}=\frac{2a+16.2a}{a+a}=\frac{34a}{2a}=17g/mol\)
\(\overline{M_B}=\frac{2b.71+3b.16.2}{2b+3b}=\frac{238b}{5b}=47,6g/mol\)
\(\rightarrow d_{A/B}=\frac{17}{47,6}=\frac{5}{14}\approx0,36\)
\(Coi: n_{Cl_2} = 1(mol) \to n_{O_2} = 2(mol)\\ \%V_{Cl_2} = \dfrac{1}{1+2}.100\% = 33,33\%\\ \%V_{O_2} = 100\% -33,33\% = 66,67\%\\ M_A = \dfrac{1.71+2.32}{1+2}=45(g/mol)\\ d_{A/H_2} = \dfrac{45}{2} = 22,5\)
\(\text{Trong 6,72 lít khí A : }m_A = 45.\dfrac{6,72}{22,4}=13,5(gam)\)
a) \(M_X=19.2=38\left(g/mol\right)\)
`=>` \(d_{X/kk}=\dfrac{38}{29}=1,310345\)
b) \(m_X=0,4.38=15,2\left(g\right)\)
Gọi \(\left\{{}\begin{matrix}n_{O_2}=x\left(mol\right)\\n_{CO_2}=y\left(mol\right)\end{matrix}\right.\)
`=>` \(\left\{{}\begin{matrix}32x+44y=15,2\\x+y=0,4\end{matrix}\right.\Leftrightarrow x=y=0,2\)
\(m_Y=0,1.28+15,2=18\left(g\right)\)
`=>` \(\left\{{}\begin{matrix}\%m_{N_2}=\dfrac{0,1.28}{18}.100\%=15,56\%\\\%m_{O_2}=\dfrac{0,2.32}{18}.100\%=35,56\%\\\%m_{CO_2}=100\%-15,56\%-35,56\%=48,88\%\end{matrix}\right.\)
b) \(M_{hh}=4.10=40\left(g/mol\right)\)
Gọi \(n_{NO_2}=a\left(mol\right)\)
`=>` \(\left\{{}\begin{matrix}m_{hh}=18+46a\left(g\right)\\n_{hh}=0,5+0,1+a=0,6+a\left(mol\right)\end{matrix}\right.\)
`=>` \(M_{hh}=\dfrac{m_{hh}}{n_{hh}}=\dfrac{18+46a}{0,6+a}=40\)
`=> a = 1`
`=> V_{NO_2(đktc)} = 1.22,4 = 22,4 (l)`
Bài 2:
a) Vì khối lượng mol của N2 và CO đều bằng 28 và lớn hơn khối lượng mol của khí metan CH4 (28>16)
=> \(d_{\dfrac{hhX}{CH_4}}=\dfrac{28}{16}=1,75\)
Hỗn hợp X nhẹ hơn không khí (28<29)
b)
\(M_{C_2H_4}=M_{N_2}=M_{CO}=28\left(\dfrac{g}{mol}\right)\\ \rightarrow M_{hhY}=28\left(\dfrac{g}{mol}\right)\\ d_{\dfrac{Y}{H_2}}=\dfrac{28}{2}=14\)
c) \(\%V_{NO}=100\%-\left(30\%+30\%\right)=40\%\\ \rightarrow\%n_{CH_4}=40\%\\ Vì:\%m_{CH_4}=22,377\%\\ Nên:\dfrac{30\%.16}{40\%.30+30\%.16+30\%.\left(x.14+16\right)}=22,377\%\\ \Leftrightarrow x=-0,03\)
Sao lại âm ta, để xíu anh xem lại như nào nhé.
Bài 1:
\(a.\\ d_{\dfrac{SO_2}{O_2}}=\dfrac{64}{32}=2\\ d_{\dfrac{SO_2}{N_2}}=\dfrac{64}{28}=\dfrac{16}{7}\\ d_{\dfrac{SO_2}{SO_3}}=\dfrac{64}{80}=0,8\\ d_{\dfrac{SO_2}{CO}}=\dfrac{64}{28}=\dfrac{16}{7}\\ d_{\dfrac{SO_2}{N_2O}}=\dfrac{64}{44}=\dfrac{16}{11}\\ d_{\dfrac{SO_2}{NO_2}}=\dfrac{64}{46}=\dfrac{32}{23}\\ b.M_{hhA}=\dfrac{1.64+1.32}{1+1}=48\left(\dfrac{g}{mol}\right)\\ d_{\dfrac{hhA}{O_2}}=\dfrac{48}{32}=1,5\)
Giả sử có 1 mol khí Cl2, 2 mol khí O2
a) \(\left\{{}\begin{matrix}\%V_{Cl_2}=\dfrac{1}{1+2}.100\%=33,33\%\\\%V_{O_2}=\dfrac{2}{1+2}.100\%=66,67\%\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%m_{Cl_2}=\dfrac{1.71}{1.71+2.32}.100\%=52,59\%\\\%m_{O_2}=\dfrac{2.32}{1.71+2.32}.100\%=47,41\%\end{matrix}\right.\)
b) \(\overline{M}=\dfrac{1.71+2.32}{1+2}=45\left(g/mol\right)\)
=> \(d_{A/H_2}=\dfrac{45}{2}=22,5\)
c) \(n_A=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
=> mA = 0,3.45 = 13,5 (g)
\(\left\{{}\begin{matrix}n_{Cl_2}+n_{O_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\\dfrac{n_{Cl_2}}{n_{O_2}}=\dfrac{1}{3}\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}n_{Cl_2}=0,1\left(mol\right)\\n_{O_2}=0,3\left(mol\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}m_{Cl_2}=0,1.71=7,1\left(g\right)\\m_{O_2}=0,3.32=9,6\left(g\right)\end{matrix}\right.\)
=> mhh = 7,1 + 9,6 = 16,7(g)
Đặt $n_{Cl_2}=x(mol)\Rightarrow n_{O_2}=3x(mol)$
Mà $n_{hh}=n_{Cl_2}+n_{O_2}=\dfrac{8,96}{22,4}=0,4$
$\Rightarrow x+3x=0,4\Rightarrow x=0,1$
$\Rightarrow m_{Cl_2}=0,1.71=7,1(g);m_{O_2}=3.0,1.32=9,6(g)$
$\Rightarrow m_{hh}=7,1+9,6=16,7(g)$
a)
$n_{Cl_2} : n_{O_2} = 1 : 2$
Suy ra :
$\%V_{Cl_2} = \dfrac{1}{1 + 2}.100\% = 33,33\%$
$\%V_{O_2} = \dfrac{2}{1 + 2}.100\% = 66,67\%$
b)
Coi $n_{Cl_2} = 1 (mol) \Rightarrow n_{O_2} = 2(mol)$
$\%m_{Cl_2} = \dfrac{1.71}{1.71 + 2.32}.100\% = 52,59\%$
$\%m_{O_2} = 100\% -52,59\% = 47,41\%$
c)
$M_A = \dfrac{71.1 + 32.2}{1 + 2} = 45(g/mol)$
$d_{A/B} = \dfrac{45}{28} = 1,607$
\(d_{A/B}=\dfrac{2+32}{71\cdot2+32\cdot3}\approx0,143\)