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\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
tl1..........1................1.............1(mol)
br x.......x................x.............x(mol)
\(Cu+H_2SO_4\rightarrow CuSO_4+H_2\)
tl1............1...............1...........1(mol)
Br y...........y...............y...........y(mol)
\(n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
Taco hệ pt
\(\left\{{}\begin{matrix}x+y=0,05\\24x+64y=5\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,045\\y=0,095\end{matrix}\right.\)
\(\Rightarrow\%m_{Mg}=0,045.24:5.100\%=21,6\%\)
\(\Rightarrow\%m_{Cu}=100\%-21,6\%=78,4\%\)
\(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\\ Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ 0,3.........0,3.........0,3.......0,3\left(mol\right)\\ m_{ddsau}=16,8+100=116,8\left(g\right)\\ m_{FeSO_4}=152.0,3=45,6\left(g\right)\\ C\%_{ddFeSO_4}=\dfrac{45,6}{116,8}.100\approx39,041\%\)
Ta có: \(n_{Fe}=\dfrac{0,56}{56}=0,01\left(mol\right)\)
\(PTHH:H_2SO_4+Fe--->FeSO_4+H_2\)
a. Theo PT: \(n_{H_2SO_4}=n_{FeSO_4}=n_{H_2}=n_{Fe}=0,01\left(mol\right)\)
\(\Rightarrow m_{FeSO_4}=0,01.152=1,52\left(g\right)\)
\(V_{H_2}=0,01.22,4=0,224\left(lít\right)\)
b. Ta có: \(m_{H_2SO_4}=0,01.98=0,98\left(g\right)\)
Ta lại có: \(C_{\%_{H_2SO_4}}=\dfrac{0,98}{m_{dd_{H_2SO_4}}}.100\%=19,6\%\)
\(\Rightarrow m_{dd_{H_2SO_4}}=5\left(g\right)\)
\(n_{H_2}=\dfrac{1,568}{22,4}=0,07\left(mol\right)\)
Gọi số mol Al, Fe là a, b
=> 27a + 56b = 2,78
2Al + 6HCl --> 2AlCl3 + 3H2
a------------------------->1,5a
Fe + 2HCl --> FeCl2 + H2
b--------------->b----->b
=> 1,5a + b = 0,07
=> a = 0,02; b = 0,04
=> mFeCl2 = 0,04.127 = 5,08 (g)
=> C
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2(mol)\\ Fe+H_2SO_4\to FeSO_4+H_2\\ \Rightarrow n_{Fe}=n_{H_2SO_4}=n_{Fe(OH)_2}=0,2(mol)\\ a,m_{Fe}=0,2.56=11,2(g)\\ b,C_{M_{H_2SO_4}}=\dfrac{0,2}{0,2}=1M\)
\(c,Ba(OH)_2+FeSO_4\to BaSO_4\downarrow+Fe(OH)_2\downarrow\\ n_{Ba(OH)_2}=\dfrac{250.17,1}{100.171}=0,25(mol)\\ LTL:\dfrac{0,2}{1}<\dfrac{0,25}{1}\Rightarrow Ba(OH)_2\text{ dư}\\ \Rightarrow n_{BaSO_4}=0,2(mol)\\ \Rightarrow m_{BaSO_4}=233.0,2=46,6(g)\)
Câu 1:
Gọi số mol Al, Fe là a,b (mol)
=> 27a + 56b = 41,5
\(n_{H_2}=\dfrac{28}{22,4}=1,25\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
______a-------------------------->1,5a_______(mol)
Fe + 2HCl --> FeCl2 + H2
b---------------------------->b_______________(mol)
=> 1,5a + b = 1,25
=> \(\left\{{}\begin{matrix}a=0,5\\b=0,5\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{56.0,5}{41,5}.100\%=67,47\%\\\%m_{Al}=\dfrac{27.0,5}{41,5}.100\%=32,53\%\end{matrix}\right.\)
Câu 1:
Đặt \(n_{Al}=x(mol);n_{Fe}=y(mol)\Rightarrow 27x+56y=41,5(1)\)
\(n_{H_2}=\dfrac{28}{22,4}=1,25(mol)\\ PTHH:2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ Fe+H_2SO_4\to FeSO_4+H_2\\ \Rightarrow 1,5x+y=1,25(2)\\ (1)(2)\Rightarrow x=y=0,5(mol)\\ \Rightarrow \%_{Fe}=\dfrac{0,5.56}{41,5}.100\%\approx 67,5\%\\ \Rightarrow \%_{Al}=100\%-67,5\%=32,5\%\)
Chọn D
\(n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
PTHH: Fe + H2SO4 --> FeSO4 + H2
_____0,05<--------------------0,05
=> mFe = 0,05.56 = 2,8 (g)
=> mCu = 6-2,8 = 3,2 (g)
=> A
Fe+H2SO4->FeSO4+H2
0,05------------------------0,05 mol
n H2=\(\dfrac{1,12}{22,4}\)=0,05 mol
=>m Fe=0,05.56=2,8g