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PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\) (1)
\(2Fe+6H_2SO_{4\left(đ\right)}\underrightarrow{t^o}Fe_2\left(SO_4\right)_3+3SO_2+6H_2O\) (2)
\(5SO_2+2KMnO_4+2H_2O\rightarrow2MnSO_4+K_2SO_4+2H_2SO_4\) (3)
Ta có: \(n_{H_2}=0,2\left(mol\right)\)
Theo PT (1): \(n_{Fe}=n_{H_2}=0,2\left(mol\right)\)
Theo PT (2): \(n_{SO_2}=\dfrac{3}{2}n_{Fe}=0,3\left(mol\right)\)
\(\Rightarrow V_{SO_2}=0,3.22,4=6,72\left(l\right)\)
Theo PT (3): \(n_{KMnO_4}=\dfrac{2}{5}n_{SO_2}=0,12\left(mol\right)\)
\(\Rightarrow V_{KMnO_4}=\dfrac{0,12}{2}=0,06\left(l\right)\)
Bạn tham khảo nhé!
a, \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(n_{Fe}=n_{H_2}=0,15\left(mol\right)\Rightarrow m_{Fe}=0,15.56=8,4\left(g\right)\)
b, \(n_{Na_2O}=\dfrac{6,2}{62}=0,1\left(mol\right)\)
\(Na_2O+H_2O\rightarrow2NaOH\)
\(n_{NaOH}=2n_{Na_2O}=0,2\left(mol\right)\Rightarrow C_{M_{NaOH}}=\dfrac{0,2}{0,5}=0,4\left(M\right)\)
\(a,n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH:
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
0,15 0,3 0,15 0,15
\(m_{Fe}=0,15.56=8,4\left(g\right)\)
\(a,n_{Na_2O}=\dfrac{6,2}{62}=0,1\left(mol\right)\)
PTHH :
\(Na_2O+H_2O\rightarrow2NaOH\)
0,1 0,1 0,2
\(C_{M\left(A\right)}=\dfrac{0,2}{0,5}=0,4\left(M\right)\)
$CO + O_{oxit} \to CO_2$
$CO_2 + Ca(OH)_2 \to CaCO_3 + H_2O$
$n_{O(oxit)} = n_{CaCO_3} = \dfrac{8}{100} = 0,08(mol)$
$Fe + H_2SO_4 \to FeSO_4 + H_2$
$n_{Fe} = n_{H_2} = \dfrac{1,344}{22,4} = 0,06(mol)$
Ta có :
$n_{Fe} : n_O = 0,06 : 0,08 = 3 : 4$
Vậy oxit là $Fe_3O_4$
Công thức oxit sắt có dạng: \(Fe_xO_y\)
\(Fe_xO_y+yCO\rightarrow xFe+yCO_2\uparrow\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
\(\Rightarrow n_{Fe}=n_{H_2}=\dfrac{1,344}{22,4}=0,06\left(mol\right)\)
\(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3\downarrow+H_2O\)
\(\Rightarrow n_{CO}=n_{CO_2}=n_{CaCO_3}=0,08\left(mol\right)\)
\(\Rightarrow n_{O\left(Fe_xO_y\right)}=n_{O\left(CO_2\right)}-n_{O\left(CO\right)}=2n_{CO_2}-n_{CO}=0,08\left(mol\right)\)
\(\Rightarrow n_{Fe}:n_O=0,06:0,08=3:4\)
\(\Rightarrow Fe_3O_4\)
a) mCu = 3,2 (g)
=> mFe = 6 - 3,2 = 2,8 (g)
\(n_{Fe}=\dfrac{2,8}{56}=0,05\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
0,05->0,1--->0,05--->0,05
=> V1 = 0,05.22,4 = 1,12 (l)
\(n_{Cu}=\dfrac{3,2}{64}=0,05\left(mol\right)\)
PTHH: 2Fe + 6H2SO4(đ/n) --> Fe2(SO4)3 + 3SO2 + 6H2O
0,05--------------------------------->0,075
Cu + 2H2SO4 --> CuSO4 + SO2 + 2H2O
0,05------------------------>0,05
=> V2 = (0,075 + 0,05).22,4 = 2,8 (l)
b)
nHCl(dư) = 0,5.2 - 0,1 = 0,9 (mol)
=> \(\left\{{}\begin{matrix}C_{M\left(HCl.dư\right)}=\dfrac{0,9}{0,5}=1,8M\\C_{M\left(FeCl_2\right)}=\dfrac{0,05}{0,5}=0,1M\end{matrix}\right.\)
\(n_{H_2}=\dfrac{1,568}{22,4}=0,07\left(mol\right)\)
Gọi số mol Al, Fe là a, b
=> 27a + 56b = 2,78
2Al + 6HCl --> 2AlCl3 + 3H2
a------------------------->1,5a
Fe + 2HCl --> FeCl2 + H2
b--------------->b----->b
=> 1,5a + b = 0,07
=> a = 0,02; b = 0,04
=> mFeCl2 = 0,04.127 = 5,08 (g)
=> C
Giả sử có u (mol) Fe
TN1:
PTHH: Fe + 2HCl --> FeCl2 + H2
u--------------------->u
=> \(n_{H_2}=u\left(mol\right)\)
TN2:
PTHH: 2Fe + 6H2SO4 --> Fe2(SO4)3 + 3SO2 + 6H2O
u------------------------------>1,5u
=> \(n_{SO_2}=1,5u\left(mol\right)\)
Có: \(\dfrac{V_{SO_2}}{V_{H_2}}=\dfrac{n_{SO_2}}{n_{H_2}}=\dfrac{1,5u}{u}=1,5\Rightarrow V_{SO_2}=1,5.3,36=5,04\left(l\right)\)
TN3:
PTHH: Fe + 4HNO3 --> Fe(NO3)3 + NO + 2H2O
u-------------------------->u
=> \(n_{NO}=u\left(mol\right)\)
Có: \(\dfrac{V_{NO}}{V_{H_2}}=\dfrac{n_{NO}}{n_{H_2}}=\dfrac{u}{u}=1\Rightarrow V_{NO}=3,36\left(l\right)\)