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2Fe(OH)3+3H2SO4(loãng)→ Fe2(SO4)3+ 6H2O
(mol) 0,15 0,225
\(n_{Fe\left(OH\right)_3}=\dfrac{m}{M}=\dfrac{16,05}{107}=0,15\left(mol\right)\)
\(->m_{H_2SO_4}=n.M=0,225.98=22,05\left(g\right)\)
Ta có:
\(C\%=\dfrac{m_{H_2SO_4}}{m_{ddH_2SO_4}}.100\%=7,35\%\)
<=> \(m_{ddH_2SO_4}=\dfrac{22,05.100}{7,35}=300\left(g\right)\)
Chọn câu: A
a)
$Fe + H_2SO_4 \to FeSO_4 + H_2$
$n_{H_2SO_4} = n_{H_2} = n_{Fe} = \dfrac{16,8}{56} = 0,3(mol)$
$V = 0,3.22,4 = 6,72(lít)$
$C_{M_{H_2SO_4}} = \dfrac{0,3}{0,25} = 1,2M$
b)
$n_{CuO} = \dfrac{16}{80} = 0,2(mol)$
$CuO + H_2 \xrightarrow{t^o} Cu + H_2O$
$n_{CuO} < n_{H_2}$ nên $H_2$ dư
$n_{Cu} = n_{CuO} = 0,2(mol)$
$m_{Cu} = 0,2.64 = 12,8(gam)$
\(n_{Fe}=\dfrac{m}{M}=\dfrac{16,8}{56}=0,3\left(mol\right)\\ PT:Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
0,3 0,3 0,3 (mol)
a) V= n. 22,4 = 0,3 . 22,4 = 6,72(l)
\(C\%=\dfrac{m_{H_2SO_4}}{m_{dd}}.100\%=\dfrac{0,3.98}{200}.100\%=11,76\%\)
b) PT: \(H_2+CuO\underrightarrow{t^o}Cu+H_2O\)
0,3 0,3
=> mCu=n.M=0,3.64=19,2(g)
PTHH: \(CaSO_3+H_2SO_4\rightarrow CaSO_4+H_2O+SO_2\uparrow\)
Ta có: \(n_{CaSO_3}=\dfrac{11,9}{120}\approx0,1\left(mol\right)=n_{CaSO_4}=n_{H_2SO_4}=n_{SO_2}\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CaSO_4}=0,1\cdot136=13,6\left(g\right)\\m_{ddH_2SO_4}=\dfrac{0,1\cdot98}{5\%}=196\left(g\right)\\V_{SO_2}=0,1\cdot22,4=2,24\left(l\right)\end{matrix}\right.\)
\(Ba+2HCl \to BaCl_2+H_2\\ n_{Ba}=\frac{13,7}{137}=0,1(mol)\\ n_{H_2}=n_{Ba}=0,1(mol)\\ V_{H_2}=0,1.22,4=2,24(l)\\ \text{Vậy chon đáp án C }\)
$n_{Al} = \dfrac{8,1}{27} = 0,3(mol)$
$2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
$FeO + H_2SO_4 \to FeSO_4 + H_2O$
$n_{H_2} = \dfrac{3}{2}n_{Al} = 0,45(mol)$
$V = 0,45.22,4 = 10,08(lít)$
\(n_{Al}=\frac{8,1}{27}=0,3mol\\ 2Al+3H_2SO_4\rightarrow Al_2(SO_4)_3 +3H_2 n_{H_2}=0,45mol\\ V=10,08l\)
PTHH: \(Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)
Ta có: \(n_{H_2SO_4}=3n_{Al_2O_3}=3\cdot\dfrac{15,3}{102}=0,45\left(mol\right)\) \(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,45}{3}=0,15\left(M\right)\)
a) Al2O3 + 3H2SO4 ->Al2(SO4)3 + 3H2O
nAl2O3 = m/M = 15.3/102 = 0.15
CM H2SO4 = n/V = 0.45/3 = 0.15
\(Mg + H_2SO_4 \rightarrow MgSO_4 + H_2\)
\(n_{Mg}= \dfrac{4,8}{24}= 0,2 mol\)
Theo PTHH:
\(n_{H_2}= n_{Mg} = 0,2 mol\)
\(\Rightarrow V_{H_2}= 0,2 . 22,4=4,48l\)
b)
Theo PTHH:
\(n_{H_2SO_4}= n_{Mg}= 0,2 mol\)
\(\Rightarrow V_{H_2SO_4}= \dfrac{0,2}{2}=0,1 l\)
\(a.\\ n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\ Mg+H_2SO_4->MgSO_4+H_2\\ =>n_{H_2}=0,2\left(mol\right)\\ =>V=0,2\cdot22,4=4,48\left(l\right)\)
b.
Thể tích dung dịch \(H_2SO_4\) đã dùng là:
\(v_{H_2SO_4}=\dfrac{0,2}{2}=0,1\left(l\right)\)
Al2O3+ 3H2SO4→ Al2(SO4)3+ 3H2O
(mol) 0,075 0,225
\(n_{Al_2O_3}=\dfrac{m}{M}=\dfrac{7,65}{102}=0,075\left(mol\right)\)
→\(V_{H_2SO_4}=\dfrac{n}{C_M}=\dfrac{0,225}{1,5}=0,15\left(lít\right)\)
Chọn câu: B