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a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
b, Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,1.65}{10}.100\%=65\%\\\%m_{ZnO}=35\%\end{matrix}\right.\)
c, \(n_{HCl}=0,1.0,5=0,05\left(mol\right)\)
\(n_{NaOH}=0,03.1=0,03\left(mol\right)\)
PT: \(HCl+NaOH\rightarrow NaCl+H_2O\)
Xét tỉ lệ: \(\dfrac{0,05}{1}>\dfrac{0,03}{1}\), ta được HCl dư.
→ Quỳ tím chuyển đỏ do acid dư.
Đặt: \(n_{Zn}=a\left(mol\right);n_{ZnO}=b\left(mol\right)\left(a,b>0\right)\)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(a.Zn+2HCl\rightarrow ZnCl_2+H_2\\ ZnO+2HCl\rightarrow ZnCl_2+H_2O\\ \Rightarrow\left\{{}\begin{matrix}65a+81b=14,6\\a=0,1\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\\ b.m_{Zn}=0,1.65=6,5\left(g\right)\\ m_{ZnO}=0,1.81=8,1\left(g\right)\\ d.m_{ddHCl}=\dfrac{\left(0,1+0,1\right).2.36,5.100}{7,3}=200\left(g\right)\)
a)\(n_{Fe}=\dfrac{14}{56}=0,25\left(mol\right)\)
PTHH: Fe + 2HCl → FeCl2 + H2
Mol: 0,25 0,5 0,25
b) \(C_{M_{ddHCl}}=\dfrac{0,5}{0,5}=1M\)
c) \(V_{H_2}=0,25.22,4=5,6\left(l\right)\)
\(a)Mg+2HCl\rightarrow MgCl_2+H_2\\ n_{Mg}=\dfrac{5,28}{24}=0,22mol\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ 0,22...0,44........0,22........0,22\\ V_{H_2\left(đkc\right)}=0,22.24,79=5,4538l\\ b)C_{\%HCl}=\dfrac{0,44.26,5}{200}\cdot100=8,03\%\\ c)C_{\%MgCl_2}=\dfrac{0,22.95}{200+5,28}\cdot100\approx10,18\%\)
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a, \(CuO+2HCl\rightarrow CuCl_2+H_2O\)
\(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)
b, Gọi: \(\left\{{}\begin{matrix}n_{CuO}=x\left(mol\right)\\n_{Fe_2O_3}=y\left(mol\right)\end{matrix}\right.\) ⇒ 80x + 160y = 32 (1)
Theo PT: \(\left\{{}\begin{matrix}n_{CuCl_2}=n_{Cu}=x\left(mol\right)\\n_{FeCl_3}=2n_{Fe_2O_3}=2y\left(mol\right)\end{matrix}\right.\) ⇒ 135x + 325y = 59,5 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,2\left(mol\right)\\y=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CuO}=0,2.80=16\left(g\right)\\m_{Fe_2O_3}=0,1.160=16\left(g\right)\end{matrix}\right.\)
c, Theo PT: \(n_{HCl}=2n_{CuO}+6n_{Fe_2O_3}=1\left(mol\right)\)
\(\Rightarrow V_{ddHCl}=\dfrac{1}{0,5}=2\left(l\right)\)
\(a.ZnO+2HCl\rightarrow ZnCl_2+H_2\\ b.n_{ZnO}=\dfrac{3,6}{81}=\dfrac{2}{45}mol\\ n_{HCl}=\dfrac{2}{45}\cdot2=\dfrac{4}{45}mol\\ V_{HCl}=\dfrac{4:45}{0,5}\approx0,18l\)
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