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PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
\(FeO+2HCl\rightarrow FeCl_2+H_2O\)
Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)=n_{Fe}\) \(\Rightarrow n_{FeO}=\dfrac{12,8-0,1\cdot56}{72}=0,1\left(mol\right)\)
Theo các PTHH: \(\Sigma n_{HCl}=2n_{Fe}+2n_{FeO}=0,4\left(mol\right)\)
\(\Rightarrow V_{HCl}=\dfrac{0,4}{0,1}=4\left(l\right)\)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1mol\)
Fe + 2HCl => FeCl2 + H2
0,1 0,2 0,1
=> FeO = \(\dfrac{12,8-0,1.56}{72}=0,1\left(mol\right)\)
FeO + 2HCl => FeCl2 + H2O
0,1 0,2
VHCl = 0,2 . 22,4 = 4,48 lít
nH2 = 2.24/22.4 = 0.1 (mol)
Fe + 2HCl => FeCl2 + H2
0.1___0.2_____0.1___0.1
mFeO = 12.8 - 0.1*56 = 7.2 (g)
nFeO = 7.2/72 = 0.1 (mol)
FeO + 2HCl => FeCl2 + H2O
0.1____0.2______0.1
%Fe = 5.6/12.8 * 100% = 43.75%
%FeO = 56.25%
nHCl = 0.2 + 0.2 = 0.4 (mol)
Vdd HCl = 0.4/0.1 = 4(l)
nFeCl2 = 0.1 + 0.1 = 0.2 (mol)
CM FeCl2 = 0.2/4 = 0.05 (M)
nCl2 = 3.36/22.4 = 0.15 (mol)
MnO2 + 4HCl => MnCl2 + Cl2 + 2H2O
0.15____0.6____________0.15
mMnO2 = 0.15*87 = 13.05 (g)
Vdd HCl = 0.6 / 3 = 0.2 (l)
a) MnO2 + 4 HCl(đ) -to-> MnCl2 + Cl2 + 2 H2O
nCl2=0,15(mol)
=> nMnO2=nCl2=0,15(mol)
=> mMnO2=0,15.87=13,05(g)
b) nHCl=0,15.4=0,6(mol)
=>VddHCl=0,6/3=0,2(l)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe}=n_{H_2}=0,1\left(mol\right)\\ m_{Fe_3O_4}=11,4-0,1.56=5,8\left(g\right)\\ n_{Fe_3O_4}=\dfrac{5,8}{232}=0,025\left(mol\right)\\ Fe_3O_4+8HCl\rightarrow2FeCl_3+FeCl_2+4H_2O\\ n_{HCl\left(tổng\right)}=2.n_{Fe}+8.n_{Fe_3O_4}=2.0,1+8.0,025=0,4\left(mol\right)\\ V_{ddHCl}=\dfrac{0,4}{1,25}=0,32\left(l\right)\)
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\(Đặt:n_{Al}=a\left(mol\right),n_{Fe}=b\left(mol\right)\)
\(m_{hh}=27a+56b=8.3\left(g\right)\left(1\right)\)
\(n_{H_2}=\dfrac{5.6}{22.4}=0.25\left(mol\right)\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(Tathấy:\)
\(n_{HCl}=2n_{H_2}=2\cdot0.25=0.5\left(mol\right)\)
\(V_{ddHCl}=\dfrac{0.5}{0.2}=2.5\left(l\right)\)
\(n_{H_2}=1.5a+b=0.25\left(mol\right)\left(2\right)\)
\(\left(1\right),\left(2\right):a=b=0.1\)
\(C_{M_{AlCl_3}}=\dfrac{0.1}{2.5}=0.04\left(M\right)\)
\(C_{M_{FeCl_2}}=\dfrac{0.1}{2.5}=0.04\left(M\right)\)
Chúc em học tốt !!!
a, Ta có: \(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
BTNT H, có: \(n_{HCl}=2n_{H_2}=0,5\left(mol\right)\)
\(\Rightarrow V_{HCl}=\dfrac{0,5}{0,2}=2,5\left(l\right)\)
b, Giả sử: \(\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\)
⇒ 27x + 56y = 8,3 (1)
Các quá trình:
\(Al^0\rightarrow Al^{+3}+3e\)
x___________ 3x (mol)
\(Fe^0\rightarrow Fe^{+2}+2e\)
y____________2y (mol)
\(2H^++2e\rightarrow H_2^0\)
______0,5__0,25 (mol)
Theo ĐLBT mol e, có: 3x + 2y = 0,5 (2)
Từ (1) và (2) ⇒ x = y = 0,1 (mol)
BTNT Al và Fe, có: \(\left\{{}\begin{matrix}n_{AlCl_3}=n_{Al}=0,1\left(mol\right)\\n_{FeCl_3}=n_{Fe}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow C_{M_{AlCl_3}}=C_{M_{FeCl_3}}=\dfrac{0,1}{2,5}=0,04M\)
Bạn tham khảo nhé!
