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thôi thì mình làm cho bn vậy, câu a ko làm dc đâu, làm câu b thôi, làm sao biết dc chất nào dư khi chỉ có số mol 1 chất?
nK2SO3=0.1367(mol)
mddH2SO4=Vdd.D=200.1,04=208(g)
K2SO3+H2SO4-->K2SO4+H2O+SO2
0.1367----0.1367----0.1367---------0.1367 (mol)
mddspu=100+208-0,1367.64=299.2512(g) ; mK2SO4=0,1367.174=23.7858(g)
==>C%=23.7858.100/299.512=7.94%
2)pt bn tự ghi nhé
ta có hệ pt: 56a+27b=11 và a+3b/2=8.96/22.4==>a=0.1, b=0.2
==>%Fe=0.1x56x100/11=50.9%
%Al=100%-50.9%=49.1%
b)nH2SO4= 0.7(mol)==>VddH2SO4=0.7/2=0.35(L)
\(a)2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ b)n_{H_2}=\dfrac{5,6}{22,4}=0,25mol\\ n_{Al}=a;n_{Fe}=b\\ \left\{{}\begin{matrix}3a+b=0,25\\27a+56b=8,3\end{matrix}\right.\\ a=\dfrac{19}{470};b=\dfrac{121}{940}\\ \%m_{Al}=\dfrac{\dfrac{19}{470}\cdot27}{8,3}\cdot100=13,15\%\\ \%m_{Fe}=100-13,15=86,85\%\\ c)n_{HCl}=3\cdot\dfrac{19}{470}+2\cdot\dfrac{121}{940}=\dfrac{89}{235}mol\\ m_{ddHCl=}=\dfrac{\dfrac{89}{235}\cdot36,5}{7,3}\cdot100=189g\\ d)n_{AlCl_3}=n_{Al}=\dfrac{19}{470}mol\\ n_{Fe}=n_{FeCl_2}=\dfrac{121}{940}mol\)
\(m_{dd}=8,3+189-0,25.2=196,8g\\ C_{\%AlCl_3}=\dfrac{\dfrac{19}{470}\cdot133,8}{196,8}\cdot100=2,8\%\\ C_{\%FeCl_2}=\dfrac{\dfrac{121}{940}127}{196,8}\cdot100=8,3\%\)
a, \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
b, Ta có: \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=\dfrac{4}{15}\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{\dfrac{4}{15}.27}{10}.100\%=72\%\\\%m_{Cu}=28\%\end{matrix}\right.\)
c, Theo PT: \(n_{H_2SO_4}=n_{H_2}=0,4\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=0,4.98=39,2\left(g\right)\)
\(\Rightarrow C\%_{H_2SO_4}=\dfrac{39,2}{300}.100\%\approx13,067\%\)
\(n_{H_2}=\dfrac{3,36}{22,4}0,15(mol)\\ a,PTHH:Fe+H_2SO_4\to FeSO_4+H_2\\ b,n_{Fe}=n_{H_2}=0,15(mol)\\ \Rightarrow \%_{Fe}=\dfrac{0,15.56}{14,8}.100\%=56,76\%\\ \Rightarrow \%_{Cu}=100\%-56,76\%=43,24\%\\ c,n_{H_2SO_4}=0,15(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,15.98}{20\%}=73,5(g)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{73,5}{1,4}=52,5(l)\)
a)
Gọi $n_{Fe} = a(mol) ; n_{Al} =b (mol) \Rightarrow 56a + 27b = 11(1)$
$Fe + 2HCl \to FeCl_2 + H_2$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
Theo PTHH : $n_{H_2} = a + 1,5b = \dfrac{8,96}{22,4} = 0,4(2)$
Từ (1)(2) suy ra : a = 0,1 ; b = 0,2
$\%m_{Fe} = \dfrac{0,1.56}{11}.100\% = 50,9\%$
$\%m_{Al} = 100\% - 50,9\% = 49,1\%$
b) $n_{HCl} = 2n_{H_2} = 0,8(mol)$
$\Rightarrow C_{M_{HCl}} = \dfrac{0,8}{0,4} = 2M$
c)
$C_{M_{FeCl_2}} = \dfrac{0,1}{0,4} = 0,25M$
$C_{M_{AlCl_3}} =\dfrac{0,2}{0,4} = 0,5M$
\(Đặt:n_{Fe}=a\left(mol\right);n_{Al}=b\left(mol\right)\left(a,b>0\right)\\ Kim.loại.còn.lại.sau.p.ứ:Cu\\ n_{Cu}=\dfrac{25,4}{64}=0,4\left(mol\right)\\ a,PTHH:Fe+CuSO_4\rightarrow FeSO_4+Cu\\ 2Al+3CuSO_4\rightarrow Al_2\left(SO_4\right)_3+3Cu\\ \Rightarrow\left\{{}\begin{matrix}56a+27b=11\\a+1,5b=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,2\end{matrix}\right.\\b, \%m_{Fe}=\dfrac{0,1.56}{11}.100\approx50,909\%\\ \%m_{Cu}\approx100\%-50,909\%\approx49,091\%\\ c,V_{ddsau}=V_{ddCuSO_4}=0,2\left(l\right)\\ C_{MddFeSO_4}=\dfrac{0,1}{0,2}=0,5\left(M\right);C_{MddAl_2\left(SO_4\right)_3}=\dfrac{0,2:2}{0,2}=0,5\left(M\right)\\ d,C_{MddCuSO_4}=\dfrac{a+1,5b}{0,2}=2\left(M\right)\)