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\(n_{H_2S}=\dfrac{0.448}{22.4}=0.02\left(mol\right)\)
\(n_{NaOH}=0.1\cdot0.5=0.05\left(mol\right)\)
\(T=\dfrac{0.05}{0.02}=2.5>2\)
\(2NaOH+H_2S\rightarrow Na_2S+H_2O\)
\(0.04........0.02..............0.02\)
\(n_{Na_2S}=0.02\left(mol\right)\)
\(n_{NaOH\left(dư\right)}=0.05-0.04=0.01\left(mol\right)\)
\(n_{NaOH}=0.24\cdot0.1=0.024\left(mol\right)\)
\(T=\dfrac{0.024}{0.02}=1.2\)
=> Tạo 2 muối
\(n_{Na_2S}=a\left(mol\right),n_{NaHS}=b\left(mol\right)\)
\(\left\{{}\begin{matrix}2a+b=0.024\\a+b=0.02\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}a=0.004\\b=0.016\end{matrix}\right.\)
\(n_{H_2S}=0,08\left(mol\right),n_{OH^-}=0,1.0,05+0,1.0,08=0,013\left(mol\right)\)
T=\(\dfrac{0,013}{0,08}=0,1625\)=> Tạo 1 muối HS- , H2S dư
Muối gồm KHS và NaHS
=> \(m_{muối}=0,1.0,05.56+0,1.0,08.72=0,856\left(g\right)\)
\(n_{Na_2S}=n_{NaHS}=a\left(mol\right)\)
\(n_{NaOH}=2a+a=3a=0.03\left(mol\right)\)
\(\Rightarrow a=0.01\)
\(V=\left(0.01+0.01\right)\cdot22.4=0.448\left(l\right)\)
$n_{H_2} = \dfrac{2,24}{22,4} = 0,1(mol)$
$2M + 2H_2O \to 2MOH + H_2$
Theo PTHH :
$n_M = 2n_{H_2} = 0,1.2 = 0,2(mol)$
$\Rightarrow M_M = \dfrac{4,6}{0,2} = 23(Natri)$
Ta có :
$m_{H_2O} = D.V = 1.200 = 200(gam)$
Sau phản ứng :
$m_{dung\ dịch} = m_M + m_{H_2O} - m_{H_2} = 4,6 + 200 - 0,1.2 = 204,4(gam)$
$C\%_{NaOH} = \dfrac{0,2.40}{204,4}.100\% = 3,91\%$
Đáp án B
`1)`
`n_{Al}={2,7}/{27}=0,1(mol)`
`2Al+3H_2SO_4->Al_2(SO_4)_3+3H_2`
`0,1->0,15->0,05->0,15(mol)`
`V_{dd\ H_2SO_4}={0,15}/1=0,15(l)=150(ml)`
`->V=150`
`V'=V_{H_2}=0,15.22,4=3,36(l)`
`C_{M\ X}=C_{M\ Al_2(SO_4)_3}={0,05}/{0,15}=1/3M`
`2)`
`n_{Fe}={2,8}/{56}=0,05(mol)`
`Fe+2HCl->FeCl_2+H_2`
`0,05->0,1->0,05->0,05(mol)`
`V_{dd\ HCl}={0,1}/1=0,1(l)=100(ml)`
`->V=100`
`V_{H_2}=0,05.22,4=1,12(l)`
`C_{M\ FeCl_2}={0,05}/{0,1}=0,5M`
Giải thích các bước giải:
nH2S = 3,36/22,4= 0,15 mol
- Giả sử muối sinh ra là Na2S
2NaOH + H2S → Na2S + 2H2O
0,15 0,15 (mol)
Theo PT ⇒ nNa2S = nH2S = 0,15 mol
⇒ m muối = 0,15.78 = 11,7 gam
\(n_{NaOH}=0,25.1=0,25\left(mol\right)\\ n_{H_2S}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(T=\dfrac{0,25}{0,15}=\dfrac{5}{3}\rightarrow\) Tạo cả 2 muối
Gọi \(\left\{{}\begin{matrix}n_{NaOH\left(\text{tạo muối trung hoà}\right)}=a\left(mol\right)\\n_{NaOH\left(\text{tạo muối axit}\right)}=b\left(mol\right)\end{matrix}\right.\)
PTHH:
2NaOH + H2S ---> Na2S + 2H2O
a \(\dfrac{a}{2}\) \(\dfrac{a}{2}\)
NaOH + H2S ---> NaHS + H2O
b b b
Hệ pt \(\left\{{}\begin{matrix}a+b=0,25\\\dfrac{a}{2}+b=0,15\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\left(mol\right)\\b=0,05\left(mol\right)\end{matrix}\right.\)
\(\rightarrow m_{muối}=\dfrac{0,2}{2}.78+0,05.56=10,6\left(g\right)\)
