Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
Theo đề gọi \(\left\{{}\begin{matrix}n_{Fe_2O_3}=3x\left(mol\right)\\n_{CuO}=2x\left(mol\right)\end{matrix}\right.\)
Có: \(m_{hh}=m_{Fe_2O_3}+m_{CuO}=160.3x+80.2x=32\)
\(\Rightarrow x=0,05\\ \Rightarrow\left\{{}\begin{matrix}n_{Fe_2O_3}=0,05.3=0,15\left(mol\right)\\n_{CuO}=0,05.2=0,1\left(mol\right)\end{matrix}\right.\)
\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
0,15 ---->0,45-->0,3
\(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
0,1 --->0,1-->0,1
a. \(m_{kim.loại}=m_{Fe}+m_{Cu}=0,3.56+0,1.64=23,2\left(g\right)\)
b. \(V_{H_2}=\left(0,45+0,1\right).22,4=12,32\left(l\right)\)
\(\left\{{}\begin{matrix}CuO:a\\Fe2O3:2a\end{matrix}\right.\)
a.\(80a+320a=24\Leftrightarrow a=0.06\)
\(\Rightarrow\left\{{}\begin{matrix}CuO=0.06\\Fe2O3=0.12\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}CuO=4.8g\\Fe2O3=19.2g\end{matrix}\right.\)
b.\(CuO+H2\rightarrow Cu+H2O\)
a a a
\(Fe2O3+3H2\rightarrow2Fe+3H2O\)
2a 6a 4a
\(\Rightarrow V_{H2}=\left(a+6a\right)\times22.4=9.408l\)
c.nHCl = 0.2 mol
\(Fe+2HCl\rightarrow FeCl2+H2\)
0.1 0.2
m chất rắn còn lại = mCu + m Fe ban đầu - m Fe bị hòa tan
= \(a\times64+4a\times56-0.1\times56=11.68g\)
a.b.
\(\left\{{}\begin{matrix}n_{Fe_2O_3}=40.80\%=32g\\m_{CuO}=40-32=8g\end{matrix}\right.\)
\(\left\{{}\begin{matrix}n_{Fe_2O_3}=\dfrac{32}{160}=0,2mol\\n_{CuO}=\dfrac{8}{80}=0,1mol\end{matrix}\right.\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,1 0,1 0,1 ( mol )
\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
0,2 0,6 0,4 ( mol )
\(V_{H_2}=\left(0,1+0,6\right).22,4=15,68l\)
\(\left\{{}\begin{matrix}m_{Cu}=0,1.64=6,4g\\m_{Fe}=0,4.56=22,4g\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}\%m_{Cu}=\dfrac{6,4}{6,4+22,4}.100=22,22\%\\\%m_{Fe}=100\%-22,22\%=77,78\%\end{matrix}\right.\)
c.
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\) ( Cu không phản ứng với H2SO4 loãng )
0,4 0,4 ( mol )
\(V_{H_2}=0,4.22,4=8,96l\)
\(n_{CuO}=2a\left(mol\right)\Rightarrow n_{Fe_2O_3}=a\left(mol\right)\)
\(m_X=80\cdot2a+160a=80\left(g\right)\)
\(\Rightarrow a=0.25\left(mol\right)\)
\(CuO+H_2\underrightarrow{^{^{t^0}}}Cu+H_2O\)
\(Fe_2O_3+3H_2\underrightarrow{^{^{t^0}}}2Fe+3H_2O\)
\(n_{H_2}=0.5+0.25\cdot3=1.25\left(mol\right)\)
\(V_{H_2}=1.25\cdot22.4=28\left(l\right)\)
\(m_{cr}=0.5\cdot64+0.5\cdot56=60\left(g\right)\)
Đổi 2,016 dm3 = 2,016 l
nH2 = 2,016/22,4 = 0,09 (mol)
Gọi nFe2O3 = a (mol); nCuO = b (mol)
160a + 80b = 5,6 (g) (1)
PTHH:
Fe2O3 + 3H2 -> (t°) 2Fe + 3H2O
Mol: a ---> 3a ---> 2a ---> 3a
CuO + H2 -> (t°) Cu + H2O
Mol: b ---> b ---> b ---> b
3a + b = 0,09 (mol) (2)
Từ (1) và (2) => a = 0,02 (mol); b = 0,03 (mol)
mFe2O3 = 0,02 . 160 = 3,2 (g)
mCuO = 0,03 . 80 = 2,4 (g)
mH2O = (0,02 . 3 + 0,03) . 18 = 1,62 (g)
mFe = 2 . 0,02 . 56 = 2,24 (g)
mCu = 0,03 . 64 = 1,92 (g)
\(a)Gọi : n_{CuO} = x(mol) \Rightarrow n_{Fe_2O_3} = \dfrac{80a.2}{160}=x(mol)\\ CuO + H_2 \xrightarrow{t^o} Cu + H_2O\\ Fe_2O_3 + 3H_2 \xrightarrow{t^o} 2Fe + H_2O\\ n_{H_2} = x + x = \dfrac{8,96}{22,4} = 0,4(mol)\Rightarrow x = 0,2\\ a = 0,2.80 + 0,2.160 = 48(gam)\\ b)\\ n_{Fe} = 2n_{Fe_2O_3} = 0,4(mol) \Rightarrow m_{Fe} = 0,4.56 = 22,4(gam)\\ n_{Cu} = n_{CuO} = 0,2(mol) \Rightarrow m_{Cu} = 0,2.64 = 12,8(gam)\)
\(n_{H_2}=\dfrac{5,04}{22,4}=0,225\left(mol\right)\)
PTHH: CuO + H2 → Cu + H2O
Mol: x x x
PTHH: Fe2O3 + 3H2 → 2Fe + 3H2O
Mol: y 3y 2y
Ta có hpt:\(\left\{{}\begin{matrix}80x+160y=14\\x+3y=0,225\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,075\left(mol\right)\\y=0,05\left(mol\right)\end{matrix}\right.\)
\(m_{hh.kim.loại}=m_{Cu}+m_{Fe}=0,075.64+2.0,05.56=10,4\left(g\right)\)
\(n_{H_2}=\dfrac{5,04}{22,4}=0,225\left(mol\right)\)
PTHH:
\(CuO+H_2\underrightarrow{t^o}Cu+H_2O\\ Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
Theo 2 pthh trên: \(n_{H_2O}=n_{H_2}=0,225\left(mol\right)\)
\(\rightarrow m_{H_2O}=0,225.18=4,05\left(g\right)\\ \rightarrow m_{H_2}=0,225.2=0,45\left(g\right)\)
Áp dụng ĐLBTKL, ta có:
\(m_{oxit\left(CuO,Fe_2O_3\right)}+m_{H_2}=m_{\text{kim loại}\left(Cu,Fe\right)}+m_{H_2O}\\ \rightarrow m_{\text{kim loại}\left(Cu,Fe\right)}=14+0,45-4,05=10,4\left(g\right)\)
a) Gọi số mol H2 là x
=> nH2O=x(mol)
Theo ĐLBTKL: mA+mH2=mB+mH2O
=> 200 + 2x = 156 + 18x
=> x = 2,75 (mol)
=> VH2=2,75.22,4=61,6(l)
b) Gọi nCuO=a(mol)
nFe2O3=1,5a(mol)
=> 80a + 240a + 102b = 200
=> 320a + 102b = 200
PTHH: CuO + H2 --to--> Cu + H2O
a---------------->a
Fe2O3 + 3H2 --to--> 2Fe + 3H2O
1,5a------------------>3a
=> 64a + 168a + 102b = 156
=> 232a + 102b = 156
=> a = 0,5; b = \(\dfrac{20}{15}\)
%mCuO=\(\dfrac{0,5.80}{200}\).100%=20%
%mFe2O3=\(\dfrac{0,75.160}{200}\).100%=60%
%mAl2O3=\(\dfrac{\dfrac{20}{15}102}{200}\).100%=20%
c) nH2=\(\dfrac{2,75}{5}\)=0,55(mol)
nFeO(tt)=\(\dfrac{36}{72}\)=0,5(mol)
Gọi số mol FeO phản ứng là t (mol)
PTHH: FeO + H2 --to--> Fe + H2O
t--------------->t
=> 56t + (0,5-t).72 = 29,6
=> t = 0,4 (mol)
=> H%=\(\dfrac{0,4}{0,5}\).100%=80%
\(a)\)
\(Fe_2O3 + 3H_2-t^o-> 2Fe + 3H_2O\)(1)
\(CuO + H_2-t^o-> Cu + H_2O\)(2)
Theo đề: mFe2O3: mCuO = 3: 1.
Gọi \(mCuO =a \)\((g)\) \(=> mFe_2O_3 = 3a \)\((g)\)
Ta có:\(mCuO + mFe_2O_3 = 48 (g)\)
\(<=> 3a + a = 48 \)
\(=> a =12 \)
\(=>\) \(mFe_2O_3 \)\(=3a = 36 (g)\)\(=> nFe2O3 = 0,225 (mol)\)
\(mCuO= a = 12 (g)\)\(=> nCuO =0,15 (mol)\)
Vậy \(nH_2 \) đã dùng = \(nH_2 \)(1) + \(nH_2 \)(2)
\(<=>nH2 = 0,675 + 0,15 = 0,825 (mol)\)
Thể tích khí H2 là:
\(V_H2 (đktc) = 22,4.nH2 \) \(= 22,4. 0,825 = 18,48 (l)\)
\(b)\)
Theo (1) \(nFe = 2.nFe_2O_3\) = \(2.0,225 = 0,45 (mol)\)
\(=> mFe = 0,45 . 56 = 25,2 (g)\)
Theo (2) \(nCu = nCuO = 0,15 (mol)\)
\(=> mCu = 0,15.64 = 9,6 (g)\)
%mFe = \(\dfrac{mFe .100}{mFe + mCu}\) = \(\dfrac{25,2.100}{25,2+9,6}\) = 72,41%
=> %mCuO = 100% - 72,41% = 27,59%