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PTHH: \(CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_2\downarrow\)
\(Cu\left(OH\right)_2\xrightarrow[]{t^o}CuO+H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{CuCl_2}=0,2\cdot2=0,4\left(mol\right)\\n_{NaOH}=0,2\cdot2=0,4\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,4}{1}>\dfrac{0,4}{2}\) \(\Rightarrow\) CuCl2 còn dư
\(\Rightarrow\left\{{}\begin{matrix}n_{NaCl}=0,4\left(mol\right)\\n_{Cu\left(OH\right)_2}=0,2\left(mol\right)=n_{CuO}=n_{CuCl_2\left(dư\right)}\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CuO}=0,2\cdot80=16\left(g\right)\\C_{M_{NaCl}}=\dfrac{0,4}{0,2+0,2}=1\left(M\right)\\C_{M_{CuCl_2}}=\dfrac{0,2}{0,4}=0,5\left(M\right)\\\end{matrix}\right.\)
Ba(OH)2+Na2CO3−−>BaCO3+2NaOH
...0.001......................................0.001...............mol
NaOH+HCl−−>NaCl+H2O
Ba(OH)2+2HCl−−>BaCl2+2H2O
....0.001............0.002................................mol
nHCl=0.1∗0.06=0.006mol
=> nNaOH=0.006−0.002=0.004mol
=> CM từng chất =......
nAgNO3= (100.17%)/170=0,1(mol)
nHCl= (300.3,65%)/36,5=0,3(mol)
a) PTHH: AgNO3 + HCl -> AgCl + HNO3
Ta có: 0,1/1 < 0,3/1
=> AgNO3 hết, HCl dư, tính theo nAgNO3
Ta có: nAgCl= nHNO3= nHCl(p.ứ)= nAgNO3= 0,1(mol)
=>m(kt)=mAgCl= 143,5.0,1= 14,35(g)
b) mHCl(dư)= (0,3- 0,1).36,5=7,3(g)
mHNO3= 63.0,1= 6,3(g)
mddsau= mddAgNO3 + mddHCl - mAgCl= 100+300- 14,35= 385,65(g)
=>C%ddHCl(dư)= (7,3/385,65).100= 1,893%
C%ddHNO3= (6,3/385,65).100=1,634%
a.CuCl2 + 2NaOH -> Cu(OH)2 + 2NaCl
0.15 0.3 0.15 0.3
Cu(OH)2 -> CuO + H2O
0.15 0.15
nNaOH = 0.3 mol
\(CM_{CuCl2}=\dfrac{0.15}{2}=0.075M\)
b.Vdd sau phản ứng = 0.2 + 0.15 = 0.35l
\(CM_{NaCl}=\dfrac{0.3}{0.35}=0.86M\)
c.mCuO = \(0.15\times80=12g\)
mHCl=(7,3*300)/100=21,9 g =>nHCl=0,6 mol
mH2SO4=(100*19,6)/100=19,6g =>nH2SO4=0,2 mol
PT HCl+NaOH-> NaCl+ H2O
mol 0,6 0,6 0,6
2NaOH+ H2SO4->Na2SO4+ H2O
mol 0,4 0,2 0,2
m NaOH=(0,4+0,6)*40=40g =>mdd NaOH=(40*100)/5=800g
C%NaCl=(0,6*58,5*100%)/(300+800+100)=2,925%
C%Na2SO4=(0,2*142*100%)/(300+800+100)=2,367%
a, \(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\)
\(n_{HCl}=0,2.2=0,4\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Xét tỉ lệ: \(\dfrac{0,15}{1}< \dfrac{0,4}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Fe}=0,15\left(mol\right)\Rightarrow V_{H_2}=0,15.22,4=3,36\left(l\right)=3360\left(ml\right)\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{FeCl_2}=n_{Fe}=0,15\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Fe}=0,3\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl\left(dư\right)}=0,4-0,3=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C_{M_{FeCl_2}}=\dfrac{0,15}{0,2}=0,75\left(M\right)\\C_{M_{HCl\left(dư\right)}}=\dfrac{0,1}{0,2}=0,5\left(M\right)\end{matrix}\right.\)
c, Ta có: \(m_{ddHCl}=1,25.200=250\left(g\right)\)
⇒ m dd sau pư = 8,4 + 250 - 0,15.2 = 258,1 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{FeCl_2}=\dfrac{0,15.127}{258,1}.100\%\approx7,38\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,1.36,5}{258.1}.100\%\approx1,41\%\end{matrix}\right.\)
\(a)n_{MnO_2}=\dfrac{69,6}{87}=0,8mol\\ MnO_2+4HCl\xrightarrow[nhẹ]{đun}MnCl_2+Cl_2+H_2O\)
0,8 3,2 0,8 0,8 0,8
\(V_A=V_{Cl_2}=0,8.22,4=17,92l\\ b)Cl_2+2NaOH\rightarrow NaCl+NaClO+H_2O\)
0,8 1,6 0,8 0,8
\(V_{ddNaOH}=\dfrac{1,6}{1}=1,6l\\ C_{M_{NaCl}}=\dfrac{0,8}{1,6}=0,5M\\ C_{M_{NaClO}}=\dfrac{0,8}{1,6}=0,5M\)
Đáp án:
CMdd NaOH=2 (M)
CMdd NaAlO2=1(M)
Giải thích các bước giải:
PTHH: NaOH+ HCl--->NaCl+H2O (1)
0,4<--(0,6-0,2) mol
NaAlO2+HCl+H2O---> Al(OH)3+ NaCl (2)
0,2<-- 0,2 <-- 0,2 mol
Ta có: mHCl=300.7,31007,3100 =21,9(g)
=>nHCl=21,936,521,936,5 =0,6(mol)
nAl(OH)3=15,67815,678 =0,2(mol)
CMdd NaOH=0,40,20,40,2 =2 (M)
CMdd NaAlO2=0,20,20,20,2 =1(M)