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a)\(n_{Fe_2O_3}=0,2\left(mol\right)\)
PT:\(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)
\(0,2\) \(1,2\) \(0,4\)
\(\Rightarrow n_{FeCl_3}=0,4\left(mol\right)\)
\(\Rightarrow m_{FeCl_3}=65\left(g\right)\)
b) \(n_{HCl}=\dfrac{218.30\%}{35,5+1}=\dfrac{654}{365}\left(mol\right)\)
Từ PT \(\Rightarrow\)\(n_{HClpư}=1,2\left(mol\right)\)
\(\Rightarrow n_{HCldư}=\dfrac{654}{365}-1,2=\dfrac{216}{365}\left(mol\right)\)
\(\Rightarrow m_{HCldư}=21,6\left(g\right)\)
\(m_{dd}=32+218=250\left(g\right)\)
\(C\%_{FeCl_3}=\dfrac{65}{250}.100\%=26\left(\%\right)\)
\(C\%_{HCldu}=\dfrac{21,6}{250}.100\%=8,64\%\)
PTHH: \(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)
\(2FeCl_3+Cu\rightarrow CuCl_2+2FeCl_2\)
Ta có: \(\left\{{}\begin{matrix}n_{FeCl_3}=2n_{Fe_2O_3}=2\cdot\dfrac{16}{160}=0,2\left(mol\right)\\n_{Cu}=\dfrac{32}{64}=0,5\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,5}{1}\) \(\Rightarrow\) Cu còn dư
\(\Rightarrow\left\{{}\begin{matrix}n_{CuCl_2}=0,1\left(mol\right)\\n_{FeCl_2}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CuCl_2}=0,1\cdot135=13,5\left(g\right)\\m_{FeCl_2}=0,2\cdot127=25,4\left(g\right)\end{matrix}\right.\)
\(n_{CuO}=\dfrac{32}{80}=0,4(mol)\\ CuO+2HCl\to CuCl_2+H_2\\ \Rightarrow n_{HCl}=0,8(mol);n_{CuCl_2}=n_{H_2}=0,4(mol)\\ a,m_{dd_{HCl}}=\dfrac{0,8.36,5}{20\%}=146(g)\\ b,m_{CuCl_2}=0,4.135=54(g)\\ c,C\%_{CuCl_2}=\dfrac{54}{32+146-0,4.2}.100\%=30,47\%\)
\(CuO + 2HCl \rightarrow CuCl_2 + H_2O\)
\(n_{CuO}= \dfrac{32}{80}= 0,4 mol\)
Theo PTHH:
\(n_{HCl}= 2n_{CuO}= 0,8 mol\)
\(\Rightarrow m_{HCl}= 0,8 . 36,5=29,2 g\)
\(\rightarrow m_{dd HCl}= \dfrac{29,2 . 100%}{20%}= 146 g\)
b) Muối tạo thành là CuCl2
Theo PTHH:
\(n_{CuCl_2}= n_{CuO}= 0,4 mol\)
\(\Rightarrow m_{CuCl_2}= 0,4 . 135= 54g\)
c)
\(m_{dd sau pư}= m_{CuO} + m_{dd HCl}= 32 + 146=178 g\)
C%= \(\dfrac{54}{178} . 100\)%= 30,337 %
PTHH: MgO + 2HCl --> MgCl2 + H2O (1)
Fe2O3 + 6HCl --> 2FeCl3 + 3H2O (2)
Gọi số mol MgO, Fe2O3 là a,b
=> 40a + 160b = 32
\(n_{HCl}=\dfrac{325.14,6}{100.36,5}=1,3\left(mol\right)\)
(1)(2) => 2a + 6b = 1,3
=> a = 0,2 , b = 0,15
\(\left\{{}\begin{matrix}\%MgO=\dfrac{0,2.40}{32}.100\%=25\%\\\%Fe_2O_3=\dfrac{0,15.160}{32}.100\%=75\%\end{matrix}\right.\)
nMgCl2 = a = 0,2 (mol)
=> mMgCl2 = 0,2.95 = 19(g)
nFeCl3 = 2b = 0,3 (mol)
=> mFeCl3 = 0,3.162,5 = 48,75(g)
a) \(m_{HCl}=200.7,3\%=14,6\left(g\right)\Rightarrow n_{HCl}=\dfrac{14,6}{36,5}=0,4\left(mol\right)\)
PTHH: CuO + 2HCl → CuCl2 + H2O
Mol: 0,2 0,4 0,2
b,\(m_{CuO}=0,2.80=16\left(g\right)\)
c, mdd sau pứ = 16+200 = 216 (g)
\(C\%_{ddCuCl_2}=\dfrac{0,2.135.100\%}{216}=12,5\%\)
\(n_{HCl}=\dfrac{14,6\%.450}{36,5}=1,8\left(mol\right)\\ n_{Fe_2O_3}=\dfrac{32}{160}=0,2\left(mol\right)\\ Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\\ Vì:\dfrac{1,8}{6}>\dfrac{0,2}{1}\\ \Rightarrow HCldư\\ a.n_{FeCl_3}=0,2.2=0,4\left(mol\right)\\ m_{FeCl_3}=162,5.0,4=65\left(g\right)\\ b.n_{HCl\left(dư\right)}=1,8-6.0,2=0,6\left(mol\right)\\ m_{HCl\left(dư\right)}=0,6.36,5=21,9\left(g\right)\\ c.m_{ddsau}=32+450=482\left(g\right)\\ C\%_{ddHCl\left(dư\right)}=\dfrac{21,9}{482}.100\approx4,544\%\\ C\%_{ddFeCl_3}=\dfrac{65}{482}.100\approx13,485\%\)
\(n_{Fe2O3}=\dfrac{32}{160}=0,2\left(mol\right)\)
\(m_{ct}=\dfrac{14,6.450}{100}=65,7\left(g\right)\)
\(n_{HCl}=\dfrac{65,7}{36,5}=1,8\left(mol\right)\)
Pt : \(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O|\)
1 6 2 3
0,2 1,8 0,4
a) Lập tỉ số so sánh : \(\dfrac{0,2}{1}< \dfrac{1,8}{6}\)
⇒ Fe2O3 phản ứng hết , HCl dư
⇒ Tính toán dựa vào số mol của Fe2O3
\(n_{FeCl3}=\dfrac{0,2.2}{1}=0,4\left(mol\right)\)
⇒ \(m_{FeCl3}=0,4.162,5=65\left(g\right)\)
b) \(n_{HCl\left(dư\right)}=1,8-\left(0,2.6\right)=0,6\left(mol\right)\)
⇒ \(m_{HCl\left(dư\right)}=0,6.36,5=21,9\left(g\right)\)
c) \(m_{ddspu}=32+450=482\left(g\right)\)
\(C_{FeCl3}=\dfrac{65.100}{482}=13,48\)0/0
\(C_{HCl\left(dư\right)}=\dfrac{21,9.100}{482}=4,54\)0/0
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