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a) 4P + 5O2 --to--> 2P2O5
b) \(n_{P_2O_5}=\dfrac{34,08}{142}=0,24\left(mol\right)\)
4P + 5O2 --to--> 2P2O5
0,48<-0,6<------0,24
=> mO2 = 0,6.32 = 19,2 (g)
c)
C1: mP = 0,48.31 = 14,88(g)
C2:
Theo ĐLBTKL: mP + mO2 = mP2O5
=> mP = 34,08-19,2 = 14,88(g)
d)
VO2 = 0,6.22,4 = 13,44 (l)
=> Vkk = 13,44 :20% = 67,2 (l)
\(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\\ n_{O_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ PTHH:4P+5O_2\underrightarrow{t^o}2P_2O_5\\ LTL:\dfrac{0,2}{4}< \dfrac{0,4}{5}\Rightarrow O_2dư\)
\(n_{O_2\left(pư\right)}=\dfrac{5}{4}n_P=\dfrac{5}{4}.0,2=0,25\left(mol\right)\\ n_{O_2\left(dư\right)}=0,4-0,25=0,15\left(mol\right)\)
\(n_{P_2O_5\left(lt\right)}=\dfrac{1}{2}n_P=\dfrac{1}{2}.0,2=0,1\left(mol\right)\\ m_{P_2O_5\left(lt\right)}=0,1.142=14,2\left(g\right)\\ m_{P_2O_5\left(tt\right)}=0,1.142.80\%=11,36\left(g\right)\)
\(n_{O_2\left(đktc\right)}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ 4P+5O_2\underrightarrow{^{to}}2P_2O_5\\ 0,12........0,15.........0,06\left(mol\right)\\ m_P=0,12.31=3,72\left(g\right)\)
\(a.PTHH:4P+5O_2\underrightarrow{t^o}2P_2O_5\)
\(b.n_{O_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
\(\Rightarrow n_P=\dfrac{0,5}{5}.4=0,4\left(mol\right)\\ \Rightarrow m_P=0,4.31=12,4\left(g\right)\)
\(m_{O_2}=0,5.32=16\left(g\right)\\ \Rightarrow m_P+m_{O_2}=m_{P_2O_5}\\ m_{P_2O_5}=24,8+16=40,8\left(g\right)\)
a) \(PTHH:4P+5O_2\) → \(2P_2O_5\)
b) \(n_{O_2}=\dfrac{V_{O_2\left(đktc\right)}}{22,4}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
Theo PTHH:
⇒ \(n_P=\dfrac{4}{5}.n_{O_2}=\dfrac{4}{5}.0,5=0,4\left(mol\right)\)
⇒ \(m_P=n.M=0,4.31=12,4\left(g\right)\)
c) Theo định luật bảo toàn khối lượng
⇒ \(m_P+m_{O_2}=m_{P_2O_5}\)
⇒ \(m_{P_2O_5}=?\)
\(n_P=\dfrac{3.1}{31}=0.1\left(mol\right)\)
\(4P+5O_2\underrightarrow{^{^{t^0}}}2P_2O_5\)
\(0.1.......0.125.....0.05\)
\(V_{O_2}=0.125\cdot22.4=2.8\left(l\right)\)
\(m_{P_2O_5}=0.05\cdot142=7.1\left(g\right)\)
nP= 3,1 / 31 =0,1 mol
2P + 5/2O2 → P2O5
0,1 0,125 0,05 mol
VO2=0,125.22,4=2,8 l
b) mP2O5=0,05.142=7,1 g
Bài 1:
\(n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
\(4P+5O_2\rightarrow2P_2O_5\)
0,24.... 0,3 .... 0,12 (mol)
\(m_P=0,24.31=7,44\left(g\right)\)
\(m_{P_2O_5}=0,12.142=17,04\left(g\right)\)
Bài 2:
\(n_{Al}=\dfrac{21,6}{27}=0,8\left(mol\right)\)
\(4Al+3O_2\rightarrow2Al_2O_3\)
0,8 .... 0,6 ...... 0,4 (mol)
\(m_{Al_2O_3}=0,4.102=40,8\left(g\right)\)
\(V_{O_2}=0,6.22,4=13,44\left(l\right)\)
C9:
nP = 6,2/31 = 0,2 (mol)
nO2 = 6,4/32 = 0,2 (mol)
PTHH: 4P + 5O2 -> (t°) 2P2O5
LTL: 0,2/4 > 0,2/5 => P dư
nP (p/ư) = 0,2/5 . 4 = 0,16 (mol)
nP (dư) = 0,2 - 0,16 = 0,04 (mol)
nP2O5 = 0,2/5 . 2 = 0,08 (mol)
mP2O5 = 0,08 . 142 = 11,36 (g)
C10:
Áp dụng ĐLBTKL, ta có:
mR + mO2 = mRO
=> mO2 = 21,6 - 16,8 = 4,8 (g(
=> nO2 = 4,8/32 = 0,15 (mol)
PTHH: 2R + O2 -> (t°) 2RO
nR = 0,15 . 2 = 0,3 (mol)
M(R) = 16,8/0,3 = 56 (g/mol(
=> R là Fe
C
\(PTHH:4P+5O_2\overset{t^o}{--->}2P_2O_5\)