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1)
2Mg + O2 \(\rightarrow\) 2MgO
4Al + 3O2 \(\rightarrow\)2Al2O3
Ta có: nO2=\(\frac{33,6}{22,4}\)=1,5 mol; nAl=\(\frac{2,7}{27}\)=0,1 mol
Ta có: nO2=\(\frac{1}{2}\)nMg +\(\frac{3}{4}\)nAl\(\rightarrow\) nMg=2,85 mol
\(\rightarrow\) mMg=68,4 gam
\(\rightarrow\) %Al=\(\frac{2,7}{\text{2,7+68,4}}\)=3,8%\(\rightarrow\) %Mg=96,2%
1,a,Gọi \(n_{Al}=a\left(mol\right)\rightarrow n_{Mg}=0,5a\left(mol\right)\)
\(\rightarrow27a+24.0,5b=7,8\\ \Leftrightarrow a=0,2\left(mol\right)\\ \rightarrow\left\{{}\begin{matrix}n_{Al}=0,2\left(mol\right)\\n_{Mg}=0,1\left(mol\right)\end{matrix}\right.\)
b, \(\rightarrow\left\{{}\begin{matrix}m_{Al}=0,2.27=5,4\left(g\right)\\m_{Mg}=0,1.24=2,4\left(g\right)\end{matrix}\right.\)
2, \(n_{O_2}=\dfrac{0,16}{32}=0,005\left(mol\right)\)
PTHH: 2HgO --to--> 2Hg + O2
0,01<- 0,05
\(\rightarrow m_{Hg}=0,01.201=2,01\left(g\right)\)
a) \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(n_{O_2}=\dfrac{16,8}{22,4}=0,75\left(mol\right)\)
PTHH:
4Al + 3O2 --to--> 2Al2O3
0,2-->0,15
2Mg + O2 --to--> 2MgO
1,2<--0,6
b) \(m_{Mg}=1,2.24=28,8\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{28,8}{28,8+5,4}.100\%=84,21\%\\\%m_{Al}=100\%-84,21\%=15,79\%\end{matrix}\right.\)
\(m_{tăng}=m_{O_2}=7.2\left(g\right)\)
\(n_{O_2}=\dfrac{7.2}{32}=0.225\left(mol\right)\)
\(V_{kk}=5V_{O_2}=5\cdot0.225\cdot22.4=25.2\left(l\right)\)
\(Đặt:n_{Mg}a\left(mol\right),n_{Cu}=b\left(mol\right),n_{Al}=c\left(mol\right)\)
\(Mg+\dfrac{1}{2}O_2\underrightarrow{t^0}MgO\)
\(Cu+\dfrac{1}{2}O_2\underrightarrow{t^0}CuO\)
\(4Al+3O_2\underrightarrow{t^0}2Al_2O_3\)
\(TC:n_{O_2}=0.5a=0.5b=0.75c=\dfrac{0.225}{3}=0.075\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}a=0.15\\b=0.15\\c=0.1\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Mg}=0.15\cdot24=3.6\left(g\right)\\m_{Cu}=0.15\cdot64=9.6\left(g\right)\\m_{Al}=0.1\cdot27=2.7\left(g\right)\end{matrix}\right.\)
PTHH: \(2Mg+O_2\underrightarrow{t^o}2MgO\) (1)
\(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\) (2)
Ta có: \(\left\{{}\begin{matrix}\Sigma n_{O_2}=\dfrac{33,6}{22,4}=1,5\left(mol\right)\\n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\Rightarrow n_{O_2\left(2\right)}=0,075\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{O_2\left(1\right)}=1,425\left(mol\right)\) \(\Rightarrow n_{Mg}=2,85\left(mol\right)\)
\(\Rightarrow\%m_{Mg}=\dfrac{2,85\cdot24}{2,85\cdot24+2,7}\cdot100\%\approx96,2\%\)
\(\Rightarrow\%m_{Al}=3,8\%\)
\(n_{O_2} =\dfrac{33,6}{22,4} = 1,5(mol)\\ n_{Al} = \dfrac{2,7}{27} = 0,1(mol)\\ 2Mg + O_2 \xrightarrow{t^o} 2MgO\\ 4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3\\ n_{O_2} = \dfrac{1}{2}n_{Mg} + \dfrac{3}{4}n_{Al}\\ \Rightarrow n_{Mg} = 2,85(mol)\)
Vậy :
\(\%m_{Mg} = \dfrac{2,85.24}{2,85.24 + 2,7}.100\% = 96,2\%\\ \%m_{Al} = 100\% - 96,2\% = 3,8\%\)
`4Al + 3O_2` $\xrightarrow{t^o}$ `2Al_2 O_3`
`0,2` `0,15` `(mol)`
`2Mg + O_2` $\xrightarrow{t^o}$ `2MgO`
`1,5` `0,75` `(mol)`
`n_[Al]=[5,4]/27=0,2(mol)`
`n_[O_2]=[16,8]/[22,4]=0,75(mol)`
`=>m_[hh]=0,2.27+1,5.24=41,4(g)`
`=>%m_[Al]=[5,4]/[41,4].100~~13,04%`
`=>%m_[Mg]~~100-13,04~~86,96%`
Ta có:
\(m_C=1.90\%=0,9kg=900g\)
\(\Rightarrow n_C=\dfrac{900}{12}=75\left(mol\right)\)
Theo gt ta có PTHH: \(C+O_2-t^o->CO_2\) (*)
Theo (*) và gt có: 75mol...75mol...75mol
\(\Rightarrow\left\{{}\begin{matrix}m_{CO_2}=75.44=3300\left(g\right)\\m_{O_2}=75.32=2400\left(g\right)\\V_{O_2}=75.22,4=1680\left(l\right)\end{matrix}\right.\)
Vì \(V_{kk}=5V_{O_2}\) nên \(V_{kk}=5.1680=8400\left(l\right)\)
Vậy................
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