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4Al+3O2-to>2Al2O3
0,4----0,3-----0,2
n Al=0,4 mol
=>m Al2O3=0,2.102=20,4g
=>VO2=0,3.22,4=6,72l
2KClO3-to>2KCl+3O2
0,2----------------------0,3
=>m KClO3=0,2.122,5=24,5g
nAl = 10,8 : 27 = 0,4 (mol)
pthh : 4Al + 3O2 -t--> 2Al2O3
0,4-->0,3-------> 0,2 (mol)
mAl2O3 = 0,2 . 102 = 20,4 (g)
VH2 = 0,3 . 22,4 = 6,72 (L)
pthh: 2KClO3 -t--> 2KCl + 3O2
0,2<----------------------0,3 (mol)
=> mKClO3 = 0,2 . 122,5 = 24,5 (g)
nP = 12,4/31 = 0,4 (mol)
PTHH: 4P + 5O2 -> (t°) 2P2O5
Mol: 0,4 ---> 0,5 ---> 0,2
mP2O5 = 0,2 . 142 = 28,4 (g)
VO2 = 0,5 . 22,4 = 11,2 (l)
PTHH: 2KMnO4 -> (t°) K2MnO4 + MnO2 + O2
nKMnO4 = 0,5 . 2 = 1 (mol)
mKMnO4 = 1 . 158 = 158 (g)
a, PT: \(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
b, Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{3}{4}n_{Al}=0,15\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,15.22,4=3,36\left(l\right)\)
c, Theo PT: \(n_{Al_2O_3}=\dfrac{1}{2}n_{Al}=0,1\left(mol\right)\)
\(\Rightarrow m_{Al_2O_3}=0,1.102=10,2\left(g\right)\)
nAl = 2,7/27 = 0,1 (mol)
PTHH: 4Al + 3O2 -> (t°) 2Al2O3
Mol: 0,1 ---> 0,075 ---> 0,05
mAl2O3 = 0,05 . 102 = 5,1 (g)
VO2 = 0,075 . 22,4 = 1,68 (l)
Vkk = 1,68 . 5 = 8,4 (l)
\(n_{Al}=\dfrac{m_{Al}}{M_{Al}}=\dfrac{2,7}{27}=0,1mol\)
\(4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\)
0,1 0,075 0,05 ( mol )
\(m_{Al_2O_3}=n_{Al_2O_3}.M_{Al_2O_3}=0,05.102=5,1g\)
\(V_{kk}=V_{O_2}.5=\left(0,075.22,4\right).5=8,4l\)
a, Ta có: \(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\)
PT: \(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
Theo PT: \(n_{Al_2O_3}=\dfrac{1}{2}n_{Al}=0,05\left(mol\right)\Rightarrow m_{Al_2O_3}=0,05.102=5,1\left(g\right)\)
b, Theo PT: \(n_{O_2}=\dfrac{3}{4}n_{Al}=0,075\left(mol\right)\Rightarrow V_{O_2}=0,075.22,4=1,68\left(l\right)\)
c, Có lẽ đề cho 0,112 chứ không phải 0,1121 bạn nhỉ?
Ta có: \(n_{O_2}=\dfrac{0,112}{22,4}=0,005\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,1}{4}>\dfrac{0,005}{3}\), ta được Al dư.
Theo PT: \(n_{Al_2O_3}=\dfrac{2}{3}n_{O_2}=\dfrac{1}{300}\left(mol\right)\Rightarrow m_{Al_2O_3}=\dfrac{1}{300}.102=0,34\left(g\right)\)
\(n_{Al}=\dfrac{8,1}{27}=0,3mol\)
\(4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\)
0,3 0,225 0,15 ( mol )
\(V_{O_2}=0,225.22,4=5,04l\)
\(m_{Al_2O_3}=0,15.102=15,3g\)
a, \(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
b, \(n_{Al_2O_3}=\dfrac{20,4}{102}=0,2\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{3}{2}n_{Al_2O_3}=0,3\left(mol\right)\Rightarrow V_{O_2}=0,3.22,4=6,72\left(l\right)\)
c, \(V_{kk}=\dfrac{V_{O_2}}{20\%}=33,6\left(l\right)\)
nAl=16,2/27= 0,6(mol)
a) PTHH: 4 Al +3 O2 -to-> 2 Al2O3
nO2= 3/4 . nAl=3/4 . 0,6= 0,45(mol)
=> V(O2,đktc)=0,45 x 22,4=10,08(l)
b) nAl2O3= nAl/2=0,6/2=0,3(mol)
=>mAl2O3=102. 0,3= 30,6(g)
c) 2KMnO4 -to-> K2MnO4 + MnO2 + O2
nKMnO4= 2.nO2=2. 0,45=0,9(mol)
=>mKMnO4= 158 x 0,9= 142,2(g)
4Al+3O2-to>2Al2O3
0,2----0,15-------0,1
nAl=\(\dfrac{5,4}{27}\)=0,2 mol
m Al2O3=0,1.102=10,2g
=>VO2=0,15.22,4=3,36l
2KClO3-to>2KCl+3O2
0,1----------------------0,15
=>m KClO3=0,1.122,5=12,25g