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Theo gt ta có: $n_{O_2}=0,6(mol);n_{hh}=0,25(mol)$
a, $CH_4+2O_2\rightarrow CO_2+2H_2O$
$C_2H_4+3O_2\rightarrow 2CO_2+2H_2O$
Gọi số mol CH4 và C2H4 lần lượt là a;b(mol)
Ta có: $a+b=0,25;2a+3b=0,6\Rightarrow a=0,15;b=0,1$
b, Suy ra $\%V_{CH_4}=60\%;\%V_{C_2H_4}=40\%$
c, Ta có: $n_{CaCO_3}=n_{CO_2}=0,15+0,1.2=0,35(mol)\Rightarrow m_{CaCO_3}=35(g)$
\(a)\\ CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_4 + 3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O\\ b)\ V_{CH_4} = a(lít) ; V_{C_2H_4} = b(lít)\\ \Rightarrow a + b = 5,6(1)\\ V_{O_2} = 2a + 3b = 13,44(2)\\ (1)(2)\Rightarrow a = 3,36 ; b = 2,24\\ \%V_{CH_4} = \dfrac{3,36}{5,6}.100\% = 60\%\\ \%V_{C_2H_4} = 40\%\\ c) V_{CO_2} = a + 2b = 7,84(lít)\\\)
\(CO_2 + Ca(OH)_2 \to CaCO_3 + H_2O\\ n_{CaCO_3} = n_{CO_2} = \dfrac{7,84}{22,4} = 0,35(mol)\\ \Rightarrow m_{CaCO_3} = 0,35.100 = 35(gam)\)
Sửa : 29,25 \(\to\) 29,55
\(C_2H_4 + Br_2 \to C_2H_4Br_2\\ n_{C_2H_4} = n_{Br_2} = \dfrac{8}{160} = 0,05(mol)\\ \Rightarrow m_{C_2H_4} = 0,05.28 = 1,4(gam)\\ CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_4 +3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O\\ CO_2 + Ba(OH)_2 \to BaCO_3 + H_2O\\ n_{CO_2} = n_{CH_4} + 2n_{C_2H_4} = n_{CH_4} + 0,05.2 = n_{BaCO_3} = \dfrac{29,55}{197}=0,15(mol) \\ \Rightarrow n_{CH_4} = 0,05(mol)\\ \Rightarrow m_{CH_4} = 0,05.16 = 0,8(gam)\)
Đầu tiên, không có nước Br chỉ có nước Br2 em nhé!
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nBr2= 8/160=0,05(mol)
PTHH: C2H4 + Br2 -> C2H4Br2
nC2H4=nBr2=0,05(mol) => mC2H4=0,05.28=1,4(g)
- Khí bay ra là khí CH4.
CH4 + 2 O2 -to-> CO2 + 2 H2O
CO2 + Ba(OH)2 -> BaCO3 + H2O
nBaCO3=29,25/197= 117/ 788 (mol ) (Số xấu quá em ơi)
=> nCH4=nCO2=nBaCO3= 117/788(mol)
=> mCH4=16. 117/788= 468/197(g)
a) Khí còn lại là CH4
\(n_{CH_4} = \dfrac{3,36}{22,4} = 0,15(mol)\\ n_{C_2H_4} = \dfrac{8-0,15.16}{28} = 0,2(mol)\)
Vậy :
\(\%m_{CH_4} = \dfrac{0,15.16}{8}.100\% = 30\%\\ \%m_{C_2H_4} = 100\% - 30\% = 70\%\)
b)
\(CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_4 + 2O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O\\ CO_2 + Ca(OH)_2 \to CaCO_3 + H_2O\\ n_{CaCO_3} = n_{CO_2} = n_{CH_4} + 2n_{C_2H_4} =0,55(mol)\\ m_{CaCO_3} =0,55.100 = 55(gam) \)
a)
Khí thoát ra: CH4
\(\%V_{CH_4} = \dfrac{6,72}{16,8}.100\% = 40\%\\ \%V_{C_2H_4} = 100\% - 40\% = 60\%\)
b)
\(n_{C_2H_4} = \dfrac{16,8-6,72}{22,4} = 0,45(mol)\\ C_2H_4 + Br_2 \to C_2H_4Br_2\\ n_{Br_2} = n_{C_2H_4} = 0,45(mol)\\ \Rightarrow C_{M_{Br_2}} = \dfrac{0,45}{2} = 0,225M\\ c) n_{C_2H_4Br_2} = n_{C_2H_4} = 0,45(mol)\\ \Rightarrow n_{C_2H_4Br_2} = 0,45.188 = 84,6(gam)\)
Bài 4:
a) n(hỗn hợp khí)= 16,8/22,4=0,75(mol)
- Khí thoát ra là khí CH4.
=> nCH4=6,72/22,4=0,3(mol)
nC2H4=0,75-0,3=0,45(mol)
- Số mol tỉ lệ thuận với thể tích.
%V(CH4)=%nCH4= (0,3/0,75).100=40%
=> %V(C2H4)=100% - 40%=60%
b) PTHH: C2H4 + Br2 -> C2H4Br2
nC2H4Br2= nBr2=nC2H4=0,45(mol)
=>VddBr2= 0,45/2=0,225(l)
c) mC2H4Br2=0,45. 188= 84,6(g)
a) PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
Ta có: \(n_{C_2H_4}=\dfrac{5,6}{28}=0,2\left(mol\right)=n_{C_2H_4Br_2}\) \(\Rightarrow m_{C_2H_4Br_2}=0,2\cdot188=37,6\left(g\right)\)
b) Ta có: \(n_{CH_4}=\dfrac{11,2}{22,4}-0,2=0,3\left(mol\right)\)
Bảo toàn nguyên tố: \(n_{CO_2}=n_{CH_4}+2n_{C_2H_4}=0,7\left(mol\right)\)
\(\Rightarrow V_{CO_2}=0,7\cdot22,4=15,68\left(l\right)\)
\(n_{hh}=\dfrac{V_{hh}}{22,4}=\dfrac{1,68}{22,4}=0,075mol\)
Gọi \(\left\{{}\begin{matrix}n_{CH_4}=x\\n_{C_2H_4}=y\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{CO_2\left(CH_4\right)}=x\\n_{CO_2\left(C_2H_4\right)}=2y\end{matrix}\right.\)
\(n_{CaCO_3}=\dfrac{m_{CaCO_3}}{M_{CaCO_3}}=\dfrac{10}{100}=0,1mol\)
\(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\)
x+2y x+2y ( mol )
Ta có:
\(\left\{{}\begin{matrix}22,4x+22,4y=1,68\\x+2y=0,1\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,05\\y=0,025\end{matrix}\right.\)
\(\%CH_4=\dfrac{0,05}{0,075}.100=66,66\%\)
\(\%C_2H_4=100\%-66,66\%=33,34\%\)
\(m_{CH_4}=0,05.16=0,8g\)
\(m_{C_2H_4}=0,025.28=0,7g\)
\(n_{C_2H_4}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ PTHH:C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\\ n_{O_2}=3.0,4=1,2\left(mol\right);n_{CO_2}=0,4.2=0,8\left(mol\right)\\ a,V_{O_2\left(đktc\right)}=22,4.1,2=26,88\left(l\right)\\ b,V_{kk\left(đktc\right)}=\dfrac{100}{20}.26,88=134,4\left(l\right)\\ c,CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3\downarrow\left(trắng\right)+H_2O\\ n_{CaCO_3}=n_{CO_2}=0,8\left(mol\right)\\ m_{kết.tủa}=m_{CaCO_3}=100.0,8=80\left(g\right)\)
a.\(n_{hh}=\dfrac{6,72}{22,4}=0,3mol\)
Gọi \(\left\{{}\begin{matrix}n_{CH_4}=x\\n_{C_2H_4}=y\end{matrix}\right.\)
\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)
x x ( mol )
\(C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\)
y 2y ( mol )
\(n_{CaCO_3}=\dfrac{40}{100}=0,4mol\)
\(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\)
0,4 0,4 ( mol )
Ta có:
\(\left\{{}\begin{matrix}x+y=0,3\\x+2y=0,4\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)
\(\%V_{CH_4}=\dfrac{0,2}{0,3}.100=66,67\%\)
\(\%V_{C_2H_4}=100\%-66,67\%=33,33\%\)
b.\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,1 0,1 ( mol )
\(m_{Br_2}=0,1.160:10\%=160g\)
g) Đặt x=nC2H4, y=mCH4
nCO2 = 22.4/22,4 =1mol
nhh = 13.44/22.4=0.6mol
=> x + y =0.6(1)
C2H4 + 6O2 -> 2CO2 + 2H2O
x 2x
CH4 + 2O2 -> CO2 + 2H2O
y y
ta có 2x + y = 1(2)
Giải PT (1) và (2)
x=0.4
y= 0.2
%vC2H4 = %nC2H4 = 0.4/0.6*100% =66.67%
%vCH4 = %nCH4 = 0.2/0.6*100% = 33.33%
b)nCa(OH)2 =1.0,5 = 0.5mol
nCO2/nCa(OH)2 = 1/0.5 = 2 => xảy ra muối Ca(HCO3)2
2CO2 + Ca(OH)2 -> Ca(HCO3)2
1 0.5
mCa(HCO3)2 = 0.5*162= 81g
c)nBa(OH)2 = 0.2*2=0.4mol
nCO2/mBa(OH)2 = 1/0.4=2.5=> xảy ra muối Ba(HCO3)2
2CO2 + Ba(OH)2 -> Ba(HCO3)2
0.4 0.4
mBa(HCO3)2 = 0.4*259=103.6g