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\(a)\\ n_{O_2} = \dfrac{6,72}{22,4} = 0,3(mol)\\ 4P + 5O_2 \xrightarrow{t^o} 2P_2O_5\\ \dfrac{n_P}{4} = 0,05 < \dfrac{n_{O_2}}{5} = 0,06\)
Do đó, Oxi dư.
\(n_{O_2\ pư} = \dfrac{5}{4}n_P = 0,25(mol)\\ \Rightarrow m_{O_2\ dư} = (0,3 - 0,25).32 = 1,6(gam)\\ b)\\ n_{P_2O_5} = \dfrac{n_P}{2} = 0,1(mol)\\ \Rightarrow m_{P_2O_5} = 0,1.142 = 14,2(gam)\)
\(n_{Al}=\dfrac{m}{M}=\dfrac{10,8}{27}=0,4\left(mol\right)\\ a.PTHH:4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
4 3 2
0,4 0,3 0,2
\(m_{Al_2O_3}=n.M=0,2.\left(27.2+16.3\right)=20,4\left(g\right)\\ c.V_{O_2}=n.24,79=0,3.24,79=7,437\left(l\right)\)
\(d.n_{O_2}=\dfrac{m}{M}=\dfrac{12,8}{\left(16.2\right)}=0,4\left(mol\right)\\ PTHH:4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
4 3 2
0,53 0,4 0,27
Tỉ lệ: \(\dfrac{0,53}{4}< \dfrac{0,4}{3}< \dfrac{0,27}{2}\Rightarrow Al_2O_3\) dư và dư \(m_{Al_2O_3}=n.M=0,27.\left(27.2+16.3\right)=27,54\left(g\right).\)
a, \(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
b, \(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)
Theo PT: \(n_{Al_2O_3}=\dfrac{1}{2}n_{Al}=0,2\left(mol\right)\Rightarrow m_{Al_2O_3}=0,2.102=20,4\left(g\right)\)
c, \(n_{O_2}=\dfrac{3}{4}n_{Al}=0,3\left(mol\right)\Rightarrow V_{O_2}=0,3.22,4=6,72\left(l\right)\)
d, \(n_{O_2}=\dfrac{12,8}{32}=0,4\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,4}{4}< \dfrac{0,4}{3}\), ta được O2 dư.
\(\Rightarrow n_{O_2\left(dư\right)}=0,4-0,3=0,1\left(mol\right)\Rightarrow m_{O_2\left(dư\right)}=0,1.32=3,2\left(g\right)\)
a) \(n_{Na}=\dfrac{9,2}{23}=0,4\left(mol\right);n_{O_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
PTHH: 4Na + O2 --to--> 2Na2O
Xét tỉ lệ: \(\dfrac{0,4}{4}>\dfrac{0,05}{1}\) => Na dư, O2 hết
PTHH: 4Na + O2 --to--> 2Na2O
0,2<-0,05------>0,1
=> \(m_{Na\left(dư\right)}=\left(0,4-0,2\right).23=4,6\left(g\right)\)
b) \(\left\{{}\begin{matrix}\%m_{Na\left(dư\right)}=\dfrac{4,6}{9,2+0,05.32}.100\%=42,6\%\\\%m_{Na_2O}=\dfrac{0,1.62}{9,2+0,05.32}.100\%=57,4\%\end{matrix}\right.\)
a: \(n_{Na}=\dfrac{9.2}{23}=0.4\left(mol\right)\)
\(n_{O_2}=\dfrac{1.12}{22.4}=0.05\left(mol\right)\)
=>Na dư 0,35 mol
b: \(4Na+O_2\rightarrow2Na_2O\)
nFe = 2.8/56 = 0.05 (mol)
nO2 = 22.4 / 22.4 = 1 (mol)
3Fe + 2O2 -to-> Fe3O4
0.05__1/30______1/60
mO2 (dư) = ( 1 - 1/30) * 32 = 30.93 (g)
mFe3O4 = 1/60 * 232 = 3.867 (g)
a/ \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b/ Ta có: \(n_{Fe}=\dfrac{2.8}{56}=0.05\left(mol\right)\)
\(n_{O_2}=\dfrac{22.4}{22.4}=1\left(mol\right)\)
Ta có: \(\dfrac{n_{Fe\left(bra\right)}}{n_{Fe\left(pt\right)}}=\dfrac{0.05}{3}=0.016< \dfrac{n_{O_2\left(bra\right)}}{n_{O_2\left(pt\right)}}=\dfrac{1}{2}=0.5\)
=> Oxi phản ứng dư
mO2 dư = (1 - 1/30) . 32 = 30.93 (g)
mFe3O4 = 1/60 . 232 = 3.867 (g)
4P + 5O2 -----to---> 2P2O5
0,4---0,5-----------> 0,2 (mol)
+ n P = 12,4 / 31 = 0,4 (mol)
+nO2 = 13,44 / 22,4 = 0,6 (mol)
Vì nP/4 = 0,1 < n O2 /5 = 0,12
=> Oxi còn thừa sau phản ứng .
mO2 dư = (0,6 - 0,5 ) . 32 = 3,2 (g)
b. chất tạo thành : P2O5
mP2O5 = 0,2 . ( 2.31 + 16 . 5 ) = 28,4 (g)
\(n_P=\dfrac{12,4}{31}=0,4\left(mol\right)\\
n_{O_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\\
pthh:4P+5O_2\underrightarrow{t^o}2P_2O_5\\
LTL:\dfrac{0,4}{4}< \dfrac{0,6}{5}\)
=> Oxi dư
\(n_{O_2\left(p\text{ư}\right)}=\dfrac{5}{4}n_P=0,5\left(mol\right)\\
m_{O_2\left(d\right)}=\left(0,6-0,5\right).32=3,2\left(g\right)\\
n_{P_2O_5}=\dfrac{1}{2}n_P=0,2\left(mol\right)\\
m_{P_2O_5}=0,2.142=28,4\left(g\right)\)
nAl=\(\dfrac{5,4}{27}\)=0,2mol
nO2=\(\dfrac{4,48}{22,4}\)=0,2mol
PTHH:
4Al + 3O2--to->2Al2O3
Tỉ lệ \(\dfrac{0,2}{4}\) <\(\dfrac{0,2}{3}\)->Al hết O2 dưtính theo Al
=>m O2=\(\dfrac{1}{60}\).32=\(\dfrac{8}{15}\)g
2KMnO4-to>K2MnO4+MnO2+O2
0,4--------------------------------------0,2
m KMnO4=0,4.158=63,2g
.
Sửa đề: 2,47 (l) → 2,479 (l)
a, \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
b, Ta có: \(n_P=\dfrac{12,4}{31}=0,4\left(mol\right)\)
\(n_{O_2}=\dfrac{2,479}{24,79}=0,1\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,4}{1}>\dfrac{0,1}{5}\), ta được P dư.
Theo PT: \(n_{P\left(pư\right)}=\dfrac{4}{5}n_{O_2}=0,08\left(mol\right)\)
\(\Rightarrow n_{P\left(dư\right)}=0,4-0,08=0,32\left(mol\right)\)
\(\Rightarrow m_{P\left(dư\right)}=0,32.31=9,92\left(g\right)\)