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a, Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Theo PT: \(n_{FeSO_4}=n_{Fe}=0,1\left(mol\right)\Rightarrow m_{FeSO_4}=0,1.152=15,2\left(g\right)\)
b, \(n_{H_2}=n_{Fe}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
c, Sửa đề: 500 ml → 500 (g)
Theo PT: \(n_{H_2SO_4}=n_{Fe}=0,1\left(mol\right)\Rightarrow C\%_{H_2SO_4}=\dfrac{0,1.98}{500}.100\%=1,96\%\)
\(n_{Na}=\dfrac{4.6}{23}=0.2\left(mol\right)\)
\(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\)
\(0.2......................0.2.......0.1\)
\(V_{H_2}=0.1\cdot22.4=2.24\left(l\right)\)
Dung dịch X : NaOH
\(m_{dd_X}=4.6+200-0.1\cdot2=204.4\left(g\right)\)
\(C\%_{NaOH}=\dfrac{0.2\cdot40}{204.4}\cdot100\%=3.9\%\%\)
Câu 3:
c, Từ phần trên, có nH2 = nFe = 0,1 (mol)
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,1}{3}\), ta được Fe2O3 dư.
Theo PT: \(n_{Fe}=\dfrac{2}{3}n_{H_2}=\dfrac{1}{15}\left(mol\right)\Rightarrow m_{Fe}=\dfrac{1}{15}.56=\dfrac{56}{15}\left(g\right)\)
a) \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: `Fe + 2HCl -> FeCl_2 + H_2`
0,1-->0,2----->0,1------>0,1
`=> m_{FeCl_2} = 0,1.127 = 12,7 (g)`
b) `V_{H_2} = 0,1.22,4 = 2,24 (l)`
c) `n_{Fe_2O_3} = (16)/(160) = 0,1 (mol)`
PTHH: \(Fe_2O_3+3H_2\xrightarrow[]{t^o}2Fe+3H_2O\)
Xét tỉ lệ: \(0,1>\dfrac{0,1}{3}\Rightarrow\) Fe2O3
Theo PT: \(n_{Fe}=\dfrac{2}{3}.n_{H_2}=\dfrac{1}{15}\left(mol\right)\)
\(\Rightarrow m_{Fe}=\dfrac{1}{15}.56=\dfrac{56}{15}\left(g\right)\)
a) \(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
0,4-->0,6---------->0,2------->0,6
=> \(C_{M\left(dd.H_2SO_4\right)}=\dfrac{0,6}{0,15}=4M\)
b) VH2 = 0,6.22,4 = 13,44 (l)
c) \(C_{M\left(Al_2\left(SO_4\right)_3\right)}=\dfrac{0,2}{0,15}=\dfrac{4}{3}M\)
\(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\\
pthh:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,4 0,6 0,2 0,6
\(C_M_{H_2SO_4}=\dfrac{0,6}{0,15}=4M\\ V_{H_2}=0,622,4=13,44L\)
\(C_M=\dfrac{0,2}{0,15}=1,3M\)
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right);n_{HCl}=0,2.2,5=0,5\left(mol\right)\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ Vì:\dfrac{0,2}{1}< \dfrac{0,5}{2}\Rightarrow HCl.dư\\ n_{H_2}=n_{FeCl_2}=n_{Fe}=0,2\left(mol\right);n_{HCl\left(dư\right)}=0,5-0,2.2=0,1\left(mol\right)\\ a,V_{H_2\left(đktc\right)}=0,2.22,4=4,48\left(l\right)\\ b,V_{ddsau}=V_{ddHCl}=0,2\left(l\right)\\ C_{MddFeCl_2}=\dfrac{0,2}{0,2}=1\left(M\right);C_{MddHCl\left(dư\right)}=\dfrac{0,1}{0,2}=0,5\left(M\right)\)
\(m_{NaOH}=200.10\%=20\left(g\right)\Rightarrow n_{NaOH}=\dfrac{20}{40}=0,5\left(mol\right)\)
PTHH: 2Na + 2H2O → 2NaOH + H2
Mol: 0,5 0,5 0,5
\(m_{Na}=0,5.23=11,5\left(g\right)\)
\(V_{H_2}=0,25.22,4=5,6\left(l\right)\)
a.b.\(n_{Zn}=\dfrac{1,95}{65}=0,03mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,03 0,06 0,03 0,03 ( mol )
\(V_{H_2}=0,03.22,4=0,672l\)
\(m_{ddHCl}=\dfrac{0,06.36,5}{7,3\%}=30g\)
c.Tên muối: Kẽm clorua
\(m_{ZnCl_2}=0,03.136=4,08g\)
\(m_{ddspứ}=30+1,95-0,03.2=31,89g\)
\(C\%_{ZnCl_2}=\dfrac{4,08}{31,89}.100\%=12,79\%\)
1. \(m_{KOH}=500.3\%=15g\)
Vì KOH không bị điện phân nên nước tham gia điện phân
Ở Anot thu được khí Oxi
\(n_{O_2}=\frac{67,2}{22,4}=3mol\)
\(2H_2O\rightarrow2H_2+O_2\)
\(\rightarrow n_{H_2}=2n_{O_2}=6mol\)
\(\rightarrow V_{\text{khí}}=22,4.\left(6+3\right)=201,6l\)
2. \(m_{ddsaupu}=500-6.2-3.32=392g\)
\(\rightarrow C\%_{KOH}=\frac{15.100}{392}=3,82\%\)