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\(a,PTHH:4Al+3O_2\underrightarrow{t^o}2Al_2O_3\\ n_{Al}=\dfrac{m}{M}=\dfrac{10,8}{27}=0,4\left(mol\right)\\ Theo.PTHH:n_{Al_2O_3}=\dfrac{1}{2}.n_{Al}=\dfrac{1}{2}.0,4=0,2\left(mol\right)\\ m_{Al_2O_3}=n.M=0,2.102=20,4\left(g\right)\)
\(b,n_{O_2}=\dfrac{V_{\left(đktc\right)}}{22,4}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ Lập.tỉ.lệ:\dfrac{n_{Al}}{4}>\dfrac{n_{O_2}}{3}\Rightarrow Al.dư\\ Theo.PTHH:n_{Al\left(pư\right)}=\dfrac{4}{3}.n_{O_2}=\dfrac{4}{3}.0,2\left(mol\right)\\ n_{Al\left(dư\right)}=n_{Al\left(bđ\right)}-n_{Al\left(pư\right)}=0,4-0,2=0,2\left(mol\right)\\ Theo.PTHH:n_{Al_2O_3}=\dfrac{1}{2}.n_{Al}=\dfrac{1}{2}.0,2=0,1\left(mol\right)\\ m_{Al_2O_3}=n.M=0,1=102=10,2\left(g\right)\)
\(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\\ n_{O_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ PTHH:4P+5O_2\underrightarrow{t^o}2P_2O_5\\ LTL:\dfrac{0,2}{4}< \dfrac{0,4}{5}\Rightarrow O_2dư\)
\(n_{O_2\left(pư\right)}=\dfrac{5}{4}n_P=\dfrac{5}{4}.0,2=0,25\left(mol\right)\\ n_{O_2\left(dư\right)}=0,4-0,25=0,15\left(mol\right)\)
\(n_{P_2O_5\left(lt\right)}=\dfrac{1}{2}n_P=\dfrac{1}{2}.0,2=0,1\left(mol\right)\\ m_{P_2O_5\left(lt\right)}=0,1.142=14,2\left(g\right)\\ m_{P_2O_5\left(tt\right)}=0,1.142.80\%=11,36\left(g\right)\)
\(n_{H_2}=\dfrac{33,6}{22,4}=1,5\left(mol\right)\\ n_{O_2}=\dfrac{33,6}{22,4}=1,5\left(mol\right)\)
PTHH: 2H2 + O2 --to--> 2H2O
LTL: \(\dfrac{1,5}{2}< 1,5\rightarrow O_2\) dư
Theo pt: \(\left\{{}\begin{matrix}n_{O_2\left(pư\right)}=\dfrac{1}{2}n_{H_2}=\dfrac{1}{2}.1,5=0,75\left(mol\right)\\n_{H_2O}=n_{H_2}=1,5\left(mol\right)\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}m_{O_2\left(dư\right)}=\left(1,5-0,75\right).32=24\left(g\right)\\V_{O_2}\left(1,5-0,75\right).22,4=16,8\left(l\right)\\m_{H_2O}=1,5.18=27\left(g\right)\end{matrix}\right.\)
\(n_{H_2}=n_{O_2}=\dfrac{33,6}{22,4}=1,5\left(MOL\right)\)
pthh: \(2H_2+O_2\underrightarrow{t^O}2H_2O\)
LTL : \(\dfrac{1,5}{2}< \dfrac{1,5}{1}\)
=> O2 dư , H2 hết
theo pthh: nH2O = nH2 = 1,5 (mol)
=> \(m_{H_2O}=1,5.18=27\left(g\right)\)
\(n_{Zn}=\dfrac{13}{65}=0.2\left(mol\right)\)
\(n_{O_2}=\dfrac{8.96}{22.4}=0.4\left(mol\right)\)
\(2Zn+O_2\underrightarrow{^{^{t^0}}}2ZnO\)
LTL : \(\dfrac{0.2}{2}< \dfrac{0.4}{1}\Rightarrow O_2dư\)
\(m_{O_2\left(dư\right)}=\left(0.4-0.1\right)\cdot32=9.6\left(g\right)\)
\(m_{ZnO}=0.2\cdot81=16.2\left(g\right)\)
$a) CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O$
b) $n_{CH_4} = \dfrac{3,92}{22,4} = 0,175(mol)$
$n_{O_2} = \dfrac{3,84}{32} = 0,12(mol)$
Ta thấy : $n_{CH_4} : 1 > n_{O_2} : 2$ nên $CH_4$ dư
$n_{CH_4\ pư} = \dfrac{1}{2}n_{O_2} = 0,06(mol)$
$\Rightarrow m_{CH_4\ dư} = (0,175 - 0,06).16 = 1,84(gam)$
c) $2NaOH + CO_2 \to Na_2CO_3 + H_2O$
Theo PTHH :
$n_{Na_2CO_3} = n_{CO_2} = \dfrac{1}{2}n_{CH_4} = 0,06(mol)$
$m_{Na_2CO_3} = 0,06.106 = 6,36(gam)$
a) 2H2 + O2 --to--> 2H2O
b) \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH: 2H2 + O2 --to--> 2H2O
0,1-->0,05------>0,1
=> mH2O = 0,1.18 = 1,8 (g)
c) \(n_{O_2\left(bđ\right)}=\dfrac{1,344}{22,4}=0,06\left(mol\right)>n_{O_2\left(pư\right)}=0,05\left(mol\right)\)
=> O2 dư
nO2(dư) = 0,06 - 0,05 = 0,01 (mol)
VO2(dư) = 0,01.22,4 = 0,224 (l)
a)
\(n_{Mg} = \dfrac{4,8}{24} = 0,2(mol)\\ n_{O_2} = \dfrac{3,36}{22,4}= 0,15(mol)\\ 2Mg + O_2 \xrightarrow{t^o} 2MgO\)
Ta thấy :
\( \dfrac{n_{Mg}}{2} = 0,1 < n_{O_2} = 0,15 \) nên O2 dư.
\(n_{O_2\ pư} = \dfrac{n_{Mg}}{2} = 0,1(mol)\\ m_{O_2\ dư} = (0,15-0,1).32 = 1,6(gam)\\ V_{O_2\ dư} = (0,15-0,1).22,4 = 1,12(lít)\)
b)
\(n_{MgO} = n_{Mg} = 0,2\ mol\\ \Rightarrow m_{MgO} = 0,2.40 = 8\ gam\)