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Ta có: \(C_{\%_{Ba\left(OH\right)_2}}=\dfrac{m_{Ba\left(OH\right)_2}}{250}.100\%=34,2\%\)
=> \(m_{Ba\left(OH\right)_2}=85,5\left(g\right)\)
=> \(n_{Ba\left(OH\right)_2}=\dfrac{85,5}{171}=0,5\left(mol\right)\)
Ta lại có: \(C_{\%_{H_2SO_4}}=\dfrac{m_{H_2SO_4}}{150}.100\%=4,9\%\)
=> \(m_{H_2SO_4}=7,35\left(g\right)\)
=> \(n_{H_2SO_4}=\dfrac{7,35}{98}=0,075\left(mol\right)\)
a. PTHH; Ba(OH)2 + H2SO4 ---> BaSO4↓ + 2H2O
Ta thấy: \(\dfrac{0,5}{1}>\dfrac{0,075}{1}\)
Vậy Ba(OH)2 dư.
Theo PT: \(n_{BaSO_4}=n_{H_2SO_4}=0,075\left(mol\right)\)
=> \(m_{BaSO_4}=0,075.233=17,475\left(g\right)\)
b. Ta có: \(m_{dd_{BaSO_4}}=250+7,35=257,35\left(g\right)\)
=> \(C_{\%_{BaSO_4}}=\dfrac{17,475}{257,35}.100\%=6,79\%\)
PTHH: \(KOH+HNO_3\rightarrow KNO_3+H_2O\)
\(Ba\left(OH\right)_2+2HNO_3\rightarrow Ba\left(NO_3\right)_2+2H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{KOH}=\dfrac{112}{56}=2\left(mol\right)\\n_{HNO_3}=\dfrac{189}{63}=3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) HNO3 dư 1 mol
\(\Rightarrow n_{Ba\left(OH\right)_2}=0,5\left(mol\right)\) \(\Rightarrow m_{ddBa\left(OH\right)_2}=\dfrac{0,5\cdot171}{25\%}=342\left(g\right)\)
Ba(OH)2+Na2CO3−−>BaCO3+2NaOH
...0.001......................................0.001...............mol
NaOH+HCl−−>NaCl+H2O
Ba(OH)2+2HCl−−>BaCl2+2H2O
....0.001............0.002................................mol
nHCl=0.1∗0.06=0.006mol
=> nNaOH=0.006−0.002=0.004mol
=> CM từng chất =......
a, \(n_{CO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PTHH: CO2 + Ca(OH)2 → CaCO3 ↓ + H2O
Mol: 0,25 0,25 0,25
\(C_{M_{ddCa\left(OH\right)_2}}=\dfrac{0,25}{0,1}=2,5M\)
b, \(m_{CaCO_3}=0,25.100=25\left(g\right)\)
c,
PTHH: Ca(OH)2 + 2HCl → CaCl2 + 2H2O
Mol: 0,25 0,5
\(m_{ddHCl}=\dfrac{0,5.36,5.100}{20}=91,25\left(g\right)\)
B2/
nH2SO4= 196/98=2 mol
nNaOH = 60/40=1.5 mol
2NaOH + H2SO4 --> Na2SO4 + H2O
Bđ: 1.5________2
Pư: 1.5________0.75
Kt: 0__________1.25
2KOH + H2SO4 --> K2SO4 + H2O
2.5_______1.25
mKOH = 2.5*56=140g
mdd KOH = 140*100/40=350g
a)
NaOH + H2SO4 ---> Na2SO4 + H2O
KOH + H2SO4 ---> K2SO4 + H2O
b) nKOH = \(n_{H_2SO_4}\) - nNaOH = 2 -1,5 = 0,5( mol)
➞ mKOH = 28 g
➞ mddKOH = 70g
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
a, \(n_{H_2}=n_{Mg}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.24,79=4,958\left(l\right)\)
b, \(n_{HCl}=2n_{Mg}=0,4\left(mol\right)\Rightarrow m_{ddHCl}=\dfrac{0,4.36,5}{20\%}==73\left(g\right)\)
c, \(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)
Theo PT: \(n_{Ba\left(OH\right)_2}=\dfrac{1}{2}n_{HCl}=0,2\left(mol\right)\)
\(\Rightarrow V_{Ba\left(OH\right)_2}=\dfrac{0,2}{2,5}=0,08\left(l\right)\)
\(n_{Mg}=\dfrac{3,6}{24}=0,15\left(mol\right)\)
PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
a, \(n_{H_2}=n_{Mg}=0,15\left(mol\right)\Rightarrow V_{H_2}=0,15.24,79=3,7185\left(l\right)\)
b, \(n_{HCl}=2n_{Mg}=0,3\left(mol\right)\Rightarrow m_{ddHCl}=\dfrac{0,3.36,5}{25\%}=43,8\left(g\right)\)
c, PT: \(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)
Theo PT: \(n_{Ba\left(OH\right)_2}=\dfrac{1}{2}n_{HCl}=0,15\left(mol\right)\)
\(\Rightarrow V_{Ba\left(OH\right)_2}=\dfrac{0,15}{2,5}=0,06\left(l\right)\)
nH2SO4 = 2
nNaOH = 1.5
2NaOH + H2SO4 = Na2SO4 + 2H2O
1.5--------0.75
2KOH + H2SO4 = K2SO4 + 2H2O
2.5-------1.25
mKOH = 140 => m dd KOH = 350g